Sharif Digital Repository

In this study a new Ni(II)-¬oxazoline complex was synthesized by reaction of Ni(CH3COO)2.4H2O and 2-(2׳-hydroxyphenyl)-2-oxazoline ligand in MeOH solvent. The resulting complex bis[2-(2׳-hydroxyphenyl)-2-oxazolinato]Ni(II), was characterized by different spectroscopic methods. X-ray diffraction showed that this complex is four coordinated with a square planner geometry. The complex was applied as an efficient homogeneous catalyst in C-C coupling Heck reaction of arylhalides with olefins such as methylacrylate. Investigation of the catalytic activity of the complex in Heck reaction between arylhalides and olefins showed high yield and selectivity. For example reaction between iodobenzene and... 

One of the most important issues that an organization faced with is resource management. The proper resource management has the great rule in organization cost reduction. One of the most efficient processes in resource allocation is auction and there is different auction with different mechanism and goals. In an auction there is a set of items and a set of bids, and the task of auctioneer is matching items with suitable bids. Each bid consist of desirable items and the bidder value of that items. In an auction process, after mechanism design of auction and auction implementation we must identify the winners of auction and this is a hard problem even in simple auction.
In this study we... 

Strongly correlated materials are kind of materials in which novel electric and magnetic properties will appear as a result of strong correlations among their electrons like “heavy fermion materials”. Kondo lattice model is a model to describe heavy fermion materials. If we are merely interested in the magnetic properties of heavy fermions we can replace the Kondo lattice Model with the simpler model called the Kondo-necklace model which consists of the interactions only among the spins of the itinerant (conduction) and localized electrons (magnetic impurities) and also the interactions between the spins of the itinerant electrons. In this thesis we investigate the properties of the one... 

In this study, electrochemical oxygen reduction reaction (ORR) was studied on Cu, Pd, Rh, Pd-Cu and Rh-Cu alloys in alkaline solution. Pd-Cu and Rh-Cu alloys were prepared by electrochemical methods. On copper electrode it is found that direct oxygen reduction is accompanied by the electrochemical reductions of copper oxides. Also, mechanism and kinetics of reaction change as the amount of copper oxides increase on the surface. For electrodeposited alloys, it is indicated that the reactivity of Pd-Cu and Rh-Cu alloys toward oxygen reduction is higher than pure Pd and pure Rh. The maximum reactivity among Pd-Cu alloys is related to the sample with 24.5% copper content while the maximum... 

Cavity Quantum Electro-Dynamics (CQED) in Weak, Strong and Ultra-Strong coupling Regimes are studied. A MATLAB m-file is written which is able to solve any arbitrary CQED configuration. This program demands input data such as number of Quantum Dots, number of energy levels of each Quantum Dot, energies of each energy level of Quantum Dots, Number of cavity modes, eign-frequency of each cavity mode, coupling constant, dipole strength of each allowed transition of Quantum Dots and initial state of system from user and begins to solve the Schrodinger equation for annihilation and atomic ladder operators. In addition, coefficients of each possible ket will be calculated. Since, any approximation... 

This study investigates the effect of titanium dioxide and magnesium oxide additives on hydroxyapatite synthesized by sol-gel and composite with the predominant phase of hydroxyapatite by in situ method to improve mechanical properties. Scaffold samples were synthesized with nanometer-sized hydroxyapatite and composite powder particles by gel casting and sintered at 1200 ° C. Then, to evaluate the synthesized powders, simultaneous thermal analysis (STA), X-ray diffraction test, FTIR test, FESEM, EDS, and MAP analysis were used. Also, to evaluate the mechanical properties of the scaffolds, a compressive test was used, and to evaluate the scaffolds' density, the Archimedes method was used.... 

Given the complex structure of electronic waste and the difficulty of recycling it by traditional methods, the focus is mainly on biohydrometallurgy method, and in particular on bioleaching. To recover metals, various microorganisms are utilized in this method. In light of previous studies, cyanogenic bacteria have been widely used for the extraction of basic and precious metals. Among the species, indigenous microorganisms have a higher ability to resist toxic environments in the bioleaching of metals due to their adaptation by rapid changes in their metabolic system over time. The main objective of this study is to isolate indigenous microorganisms from electronic waste landfill for their... 

Downhole temperature measurement is one of the key tools for monitoring and analyzing the performance of production wells, evaluating water injection, and identifying multiphase flows within wells. The development of fiber optic technology and tools such as distributed temperature sensors has enabled the recording of high-resolution and detailed temperature profiles. These data, which measure temperature over a wide range along the wellbore, allow researchers to analyze complex downhole processes and identify fluid entry from various reservoir layers. However, accurately distinguishing the contribution of each layer to the total flow rate, especially under multiphase flow conditions and... 

Due to the prominence of the evaluation of the consequences of rising temperatures, this paper examines the effects of temperature variation on mortality across different demographic groups in Iran. I use a rich weekly data set from 2009 to 2017 across different demographic groups to understand the potential health impacts of climate change in a developing country. Using several fixed effect regressions, I discover that for an additional day with a mean temperature over 25°C, mortality rate increases by 2.56% relative to the effects of an extra day in 0-5 °C, in the weekly temperature exposure horizon. I test for the harvesting effect by comparing the estimates at weekly and monthly...