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Expounding the Meaning of Time in Evolutionary Process
, M.Sc. Thesis Sharif University of Technology ; Shafiee, Afshin (Supervisor)
Abstract
The question of the time is one of the obscure and challenging subjects which has been discussed as a mysterious problem in various civilizations. In ancient Greece, the question has been debated among the supporters of existence and eternity. We observe the words of Plato, on the existence of the absolute essence of eternity against the change and transition time instantiated as a conducted river in the Heraclitus view. Other discussions focused on the relationship between the change and displacement, or the the spatial relations to which Aristotle paid attention. With the passing of time from the ancient and medieval eras to the Renaissance period, along with the growth of the science in...
Reactive milling synthesis of nanocrystalline Al-Cu/Al2O3 nanocomposite
, Article Materials Science and Engineering A ; Volume 464, Issue 1-2 , 2007 , Pages 225-232 ; 09215093 (ISSN) ; Simchi, A ; Sharif University of Technology
2007
Abstract
Nanocrystalline Al-4 wt% Cu alloy reinforced with nanometric Al2O3 particles was synthesized by in situ reactive milling of Al and CuO powder mixture. X-ray diffraction (XRD), differential thermal analysis (DTA) and transmission electron microscopy (TEM) techniques were employed to study the mechanically induced solid state reaction between the blended powders. The mechanical milling stages were studied by scanning electron microscopy (SEM), bulk density measurement and laser particle size analyzer. It was shown that the reaction between Al and CuO occurs progressively as the mechanical milling continues, leading to formation of nanoscaled alumina particles. The grain refinement of the...
Energy and Economic Analysis of Micro CHP Systems in Buildings
, M.Sc. Thesis Sharif University of Technology ; Sattari, Sourena (Supervisor)
Abstract
In recent decades, due to economic, political and environmental issues, tend to use of the CHP systems (combined heating and power) have increased. CHP systems not only increase energy efficiency, but also decrease fuel consumption and emission levels of systems. The use of CHP technology in the industry has a long history, but the use of these systems in the commercial and residential sector, is considered, recently. As to the residential buildings, both electricity and thermal energy demands fluctuate seasonally and hourly, so it is necessary to take account of the plant’s annual operational strategies for the variations of load demands. In this paper, a nonlinear programming model is...
Study on the Behavior of Under Ground Intersection Subjected to Earthquake Loads
, M.Sc. Thesis Sharif University of Technology ; Sadaghiani, Mohammad Hossein (Supervisor)
Abstract
With the popular choice of using underground structures and tunnel in big cities and with significant damage in recent large earthquake; therefore more attention is given to the behavior of the underground structure in seismic area. The purpose of this thesis is to present the Soil-Tunnel-Structure Interaction analysis performed for different dynamic load condition. Therefore we modeled a 3D intersection part of two different tunnels in homogeneous soil by ABAQUS software. The soil and concrete structure of tunnel is modeled by three dimensional solid finite elements and the boundary of soil is modeled by three dimensional infinite elements with 8 nodes. The results demonstrate the geostatic...
Behavior of Underground Passagway and Subway Station for Earthquake Loads
, M.Sc. Thesis Sharif University of Technology ; Sadaghiani, Mohammad Hossein (Supervisor)
Abstract
A brief overview of the proposed research, its aims, engineering relevance and applications Underground space has long been exploited through the history to fulfill different human necessities. Underground facilities built in areas subject to earthquake activity must withstand both seismic and static loads. Some underground structures have experienced significant damage in recent large earthquakes. Tehran is located in seismic zone and investigation and research on the subject has significant role in design and construction of underground spaces for earthquake loads. Underground structures are complex structures which consist of different parts Such as passage way and platform space. Passage...
Immobilized manganese porphyrin on functionalized magnetic nanoparticles via axial ligation: Efficient and recyclable nanocatalyst for oxidation reactions
, Article Journal of Coordination Chemistry ; Volume 68, Issue 13 , 2015 , Pages 2347-2360 ; 00958972 (ISSN) ; Mortazavi Manesh, A ; Sharif University of Technology
Taylor and Francis Ltd
2015
Abstract
Magnetic nanoparticles (MNPs), Fe3 O4 @SiO2 , have been prepared and functionalized by 3-(chloropropyl)trimethoxysilane and then by imidazole to synthesize Fe3 O4 @SiO2 -Im. The functionalized Fe3 O4 nanoparticles were used as a support to anchor manganese porphyrin via axial ligation. The prepared catalyst was characterized by elemental analysis, FT-IR spectroscopy, X-ray powder diffraction, UV-vis spectroscopy, and scanning electron microscopy. Application of immobilized manganese porphyrin as a heterogeneous catalyst in oxidation of alkenes and sulfides was explored. To find suitable reaction conditions,...
Nanoparticle supported, magnetically separable manganese porphyrin as an efficient retrievable nanocatalyst in hydrocarbon oxidation reactions
, Article RSC Advances ; Volume 6, Issue 47 , 2016 , Pages 41551-41560 ; 20462069 (ISSN) ; Mortazavi Manesh, A ; Sharif University of Technology
Royal Society of Chemistry
2016
Abstract
A manganese porphyrin, meso-tetrakis(pentafluorophenyl)porphyrinato manganese(iii) acetate, Mn(TPFPP)OAc, was immobilized on silica-coated magnetic Fe3O4 nanoparticles functionalized with 3-aminopropyltriethoxysilane (APTS) through the amino propyl linkage using a grafting process in toluene solvent. This enabled the covalent immobilization of Mn(iii) porphyrin via an aromatic nucleophilic substitution reaction, to afford the Fe3O4@SiO2-NH2@MnPor catalyst. The resulting nanoparticles were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), FT-IR spectroscopy, UV-Vis spectroscopy, elemental analysis (CHN), atomic absorption spectroscopy (AAS), and vibrating...
Synthesis and characterization of molybdenum (VI) complex immobilized on polymeric Schiff base-coated magnetic nanoparticles as an efficient and retrievable nanocatalyst in olefin epoxidation reactions
, Article Applied Organometallic Chemistry ; Volume 34, Issue 3 , 2020 ; Bagherzadeh, M ; Sharif University of Technology
John Wiley and Sons Ltd
2020
Abstract
In this study, a new polymeric functionalized magnetic nanocatalyst containing a molybdenum Schiff base complex was prepared using a few consecutive steps. Poly (methylacrylate)-coated magnetic nanoparticles were synthesized via radical polymerization of methyl acrylate onto modified magnetic nanoparticles followed by the amidation of the methyl ester groups with hydrazine. Polymeric functionalization efficiently provides the advantage that more catalytic units can be grafted on the surface of magnetic nanoparticles. The functionalization process was continued with salicylaldehyde which introduced Schiff base groups on to the surface of the polymeric support. In the final step, the desired...
Effect of predeformation and heat treatment conditions in the SIMA process on microstructural and mechanical properties of A319 aluminum alloy
, Article Journal of Alloys and Compounds ; Volume 468, Issue 1-2 , 2009 , Pages 130-135 ; 09258388 (ISSN) ; Khalifehzadeh, R ; Keyvan, H ; Khomamizadeh, F ; Sharif University of Technology
2009
Abstract
In this study the influences of predeformation and heat treatment conditions on stress-induced melt activating process (SIMA) of A319 aluminum alloy were investigated. At 30% of predeformation a dominant globular structure of grains was obtained. However, further increasing of the predeformation rate considerably reduced the shape factor. The holding time of 10-15 min at semi-solid temperature of 580 °C was suggested in order to prevent grain growth. Coarsening of the grains by excess time or temperature of heat treatment reduced the tensile strength of the alloy. © 2008 Elsevier B.V. All rights reserved
Microporosity control and thermal-fatigue resistance of A319 aluminum foundry alloy
, Article Materials Science and Engineering A ; Volume 472, Issue 1-2 , 2008 , Pages 107-114 ; 09215093 (ISSN) ; Khalifehzadeh, R ; Akbari, M ; Khomamizadeh, F ; Sharif University of Technology
2008
Abstract
The objective of this work was to gain a quantitative and qualitative understanding of the degree to which porosity influences thermal-fatigue performance and other mechanical properties of A319 aluminum casting alloy over ranges of commercial interest. The number of cycles to failure for each test was recorded. An increase in porosity content caused degradation in thermal-fatigue life and other mechanical properties. The fractographic examinations identified the pores and some intermetallics as the key microstructural features which promote damage and thermal-fatigue crack initiation sites in the specimens. Crack initiation and propagation is expected to occur sooner in regions of higher...
Mechanical induced reaction in Al-CuO system for in-situ fabrication of Al based nanocomposites
, Article Journal of Alloys and Compounds ; Volume 465, Issue 1-2 , 2008 , Pages 151-156 ; 09258388 (ISSN) ; Simchi, A ; Seyed Reihani, S. M ; Sharif University of Technology
2008
Abstract
Gradual chemical (displacement) reaction between CuO and Al powders during high-energy attrition milling under a high purity argon atmosphere was studied. Differential thermal analysis (DTA), X-ray diffraction (XRD) and transmission electron microscopy (TEM) techniques were employed to study the solid-state reaction. It was shown that the solid-state reaction occurred during mechanical alloying (MA) and resulted in the dissolution of copper into the aluminum lattice and formation of nanometric alumina particles. The reinforcement particles were mostly distributed at the grain boundaries of Al matrix with an average crystallite size of about 50 nm. In DTA curve of the milled powders, a small...
Alumina nanopowder production from synthetic bayer liquor
, Article Journal of the American Ceramic Society ; Volume 89, Issue 12 , 2006 , Pages 3654-3657 ; 00027820 (ISSN) ; Khalifehzadeh, R ; Sadrnezhaad, Kh ; Arami, H ; Sharif University of Technology
2006
Abstract
Alkoxides are the most common precursors used for the production of alumina nanopowders. These materials are, however, expensive and corrosive. This paper introduces a new method for the production of alumina nanopowders by rapid cooling of a synthetic caustic sodium aluminate solution (Bayer liquor), followed by calcination in the presence of a surface-stabilizing agent like 1,2-dihydroxy-3,5-benzene disulfonic acid disodium salt (Tiron). The powders produced are characterized by differential thermal analysis, XRD, transmission electron microscopy, scanning electron microscope, and Brunauer-Emmet-Teller. A nanopowder of α-alumina with an average crystallite size of 27.7 nm and an average...
Workspace analysis of a cable-suspended robot with active/passive cables
, Article Proceedings of the ASME Design Engineering Technical Conference ; Volume 6 A , August , 2013 ; 9780791855935 (ISBN) ; Zohoor, H ; Sharif University of Technology
American Society of Mechanical Engineers
2013
Abstract
Cable-driven parallel robots have several outstanding characteristics that make them unique in many robotic applications. Since cables can only pull, one of the most important issues associated with these robots is obtaining their workspace. In this paper a spatial translational cable-driven robot with active/passive cables is considered and its workspace is investigated from several points of views. First the moment resisting capability of the robot is discussed and the effects of some robot's parameters on the workspace are studied. Then, both force-feasibility and moment-resisting capability of the robot are considered to find the region where the end-effector may exert the required...
Kinematic and Dynamic Analysis and Workspace Optimization of a 3DoF Cable-Based Parallel Robot
, M.Sc. Thesis Sharif University of Technology ; Zohoor, Hassan (Supervisor)
Abstract
Cable-driven robots are referred to as parallel robots actuated with cables. In fact,in such robots rigid links are replaced by cables, which may be extended to desired lengths without making mechanism much heavy. This robot possesses a number of unique properties that makes it suitable for many industrial applications. The main factor which makes cable robots analysis different from other parallel robots is the incapability of cables to push objects. Hence, obtaining the workspace of a cable robot is one of the most important subjects associated with this type of robot.The goal of this thesis is to design a spatial translational cable driven robot, which may be used for object handling. For...
Planning of Energy Storage Systems with the Main Goal of Managing the Output Power of Wind Farms
, M.Sc. Thesis Sharif University of Technology ; Ehsan , Mehdi (Supervisor)
Abstract
Uncertain fuel prices and also global climate changes are accompanied by some state initiatives such as renewable portfolio standards (RPS). This has caused a fast growth in the amount of renewable energy installed worldwide especially wind energy over last decades. However, the intrinsic characteristics of wind farms output power, i.e. intermittency and volatility of wind speed along with being non-dispatchable in output generation of wind turbine raises many new technical and financial challenges for power system operators and planners. Up to these issues, large level of wind power penetration causes a growing concern in wind energy curtailment issue which the wind farm’s operator may be...
The effect of annealing treatment on mechanical properties of aluminum clad steel sheet
, Article Materials and Design ; Volume 24, Issue 8 , 2003 , Pages 617-622 ; 02641275 (ISSN) ; Karimi Taheri, A ; Sharif University of Technology
Elsevier Ltd
2003
Abstract
In this paper, the effects of annealing temperature and time on mechanical properties and bond strength of aluminum clad steel sheet are evaluated. The results indicate that there exist an optimum annealing temperature and time for achieving a suitable formability and bonding strength between the clad layer and base metal. At this annealing time and temperature, the brittle intermetallic layer at the intimate interface of the layers is minimized. © 2003 Elsevier Ltd. All rights reserved
An investigation of deformation behavior and bonding strength of bimetal strip during rolling
, Article Mechanics of Materials ; Volume 37, Issue 5 , 2005 , Pages 531-542 ; 01676636 (ISSN) ; Taheri, A. K ; Sharif University of Technology
2005
Abstract
A mathematical model for cold rolling of two-layer strip is proposed using the upper bound theorem to investigate the plastic deformation behavior of the strip at the roll gap. The effects of total thickness reduction on the rolling power, rolling force, thickness reductions of each layer, and bonding strength of bimetal strip are discussed. Furthermore, experiments on two-layer strip rolling are conducted by employing aluminum-tin alloy and mild steel as the layers of the two-layer strips. It is found that all of theoretical predictions are in good agreement with the experimental measurements. Through the study, it becomes clear that the proposed analytical model is applicable for...
Theoretical and experimental investigation of cold rolling of tri-layer strip
, Article Journal of Materials Processing Technology ; Volume 166, Issue 2 , 2005 , Pages 163-172 ; 09240136 (ISSN) ; Taheri, A. K ; Sharif University of Technology
2005
Abstract
A mathematical model for cold rolling of symmetrical sandwich strip is proposed using the upper bound theorem to investigate the plastic deformation behavior of the strip at the roll gap. The velocity fields derived from the proposed upper bound model can satisfy automatically the volume constancy and the velocity boundary conditions within the roll gap. Effects of various rolling conditions such as the initial thickness and flow stress of each layer in the strip, total thickness reduction and the frictional condition between the strip and roll on the rolling power, rolling force, and thickness reduction of each layer are discussed. Furthermore, experiments on sandwich strip rolling are...
Bond strength and formability of an aluminum-clad steel sheet
, Article Journal of Alloys and Compounds ; Volume 361, Issue 1-2 , 2003 , Pages 138-143 ; 09258388 (ISSN) ; Karimi Taheri, A ; Sharif University of Technology
2003
Abstract
The production of an aluminum-clad steel sheet by the cold rolling process is a more efficient and economical approach compared with the other types of processes utilized for the production of such sheets. In this process, high plastic deformation of two metals, aluminum and steel, is necessary to create the cold bonding between the intermediate surfaces. Therefore, the work-hardened sheet must be annealed in order to obtain a high formability. Heat treatment of the sheet is, however, difficult due to the formation of a brittle intermetallic compound of aluminum and iron at the interface between the layers during heat treatment. In this investigation, the formability of these sheets was...
Study of mechanisms of cold roll welding of aluminium alloy to steel strip
, Article Materials Science and Technology ; Volume 20, Issue 8 , 2004 , Pages 1064-1068 ; 02670836 (ISSN) ; Taheri, A. K ; Sharif University of Technology
Maney Publishing
2004
Abstract
The mechanisms of cold roll welding of aluminium alloy to steel strip has been assessed based on a study of interfacial behaviour at deformations of up to 60% together with the surface characteristics of peeled Al clad steel strip. The proposed mechanisms are applicable where the contact surfaces are degreased and then scratch brushed before the rolling deformation. According to this mechanisms the scratch-brushed layers are fractured shortly after entering the roll gap at a reduction of approximately 10%, which is about the threshold deformation for the roll bonding of aluminium to steel. The transfer cracks formed then become wider so that the distance between each coherent block increases...