Sharif Digital Repository

Nanocrystallization kinetics of amorphous Finemet alloy was studied using Vyazovkin advanced isoconversional method under non-isothermal condition. Well known Kissinger model-fitting method and four isoconversional methods of Kissinger-Akahira-Sunose (KSA), Flynn-Wall-Ozawa (FWO), Tang, and Starink were also used for the determination of activation energy. Differential scanning calorimetry (DSC) and X-ray diffraction (XRD) patterns were used for thermal and structural analyses, respectively. According to Vyazovkin and other isoconversional methods, the mean value of variable activation energy, as a function of conversion, was obtained as 350 kJ mol-1. While, according to Kissinger method,... 

The effects of the most important parameters of hot pressing, including temperature, time and pressure on densification, microstructure and infrared transparency of MgF2 ceramics are discussed. The results show that the absorption or scattering of incident radiation is strongly dependent on the amount of porosity. By increasing the temperature or the pressure, transparency at infrared wavelengths has been increased due to the rise in density. For the longer hot pressing times, a continuous increase in density and infrared transparency has been seen as well. Cold pressing before hot press has minor effects on the density and infrared transparency of MgF2. © 2008 Elsevier B.V. All rights... 

The comparative study of Active Screen Plasma Nitriding (ASPN) treatment of two Finemet-type alloys with the compositions of Fe73.5Si 13.5B9Nb3Cu1 and Fe 77Si11B9Nb2.4Cu0.6 was investigated in different temperatures ranging from 410°C to 56°C. Differential Scanning Calorimetry (DSC), X-Ray Diffractometery (XRD), Atomic Force Microscopy (AFM), Scanning Electron Microscopy (SEM), electrical resistivity, microhardness measurements and magnetic characterization by a Vibrating Sample Magnetometer (VSM) were utilized to characterize the treated samples. The comparison of the DSC data for the alloys suggested that the smaller amount of Nb as a growth inhibitor shifted the crystallization... 

The electrochemical corrosion behavior of finemet alloy at various heat treatment temperatures was investigated. Thermal behavior and structural changes were studied using differential scanning calorimetry and X-ray diffractometry, respectively. The electrochemical corrosion of amorphous and annealed samples was investigated in 0.10 M NaOH solution using electrochemical impedance spectroscopy and linear sweep voltammetery. Changes in morphology of the samples before and after corrosion were characterized using optical microscope. The results showed that structural relaxation and nanocrystallization during the heat treatment improved corrosion behavior of the alloy. The heat-treated alloy at... 

Kinetics of crystallization in an amorphous (Fe0.5Co 0.5)77Si11B9Cu0.6Nb 2.4 (at.%) alloy was investigated using differential scanning calorimetry (DSC). Transformed fraction as a function of temperature was obtained by accurate DSC measurement and the experimental data analyzed with Vyazovkin model-free kinetic method. Reconstructed form of the experimental kinetics model, g(α), clearly showed the crystallization mechanism do not belongs to a single model but almost follows the Avrami-Erofe'ev. Magnetic coercivity and hysteresis loss values of the annealed samples at 823 K were 7.5 A m-1 and 1.2 J m-3, compared to 17.1 A m-1 and 37.1 J m-3 for as spun samples. Magnetic measurements show the... 

The nanocrystallization process of amorphous Fe73.5Si13.5B9Nb3Cu 1 was investigated by active screen plasma nitriding (ASPN) treatment at temperatures ranging from 410 °C to 560 °C for 3 h in two gas mixtures of 75% N2-25% H2 and 25% N2-75% H2 at 5 mbar atmosphere. The amorphous ribbons were then annealed under vacuum at the same time and temperatures mentioned above. The structure of the samples was analyzed using various techniques such as X-ray diffraction (XRD), atomic force microscopy (AFM) and differential scanning calorimetry (DSC). Microhardness measurements, electrical resistivity and Vibrating Sample Magnetometer (VSM) were used to study mechanical, electrical and magnetic... 

A cyclic forward-backward extrusion (CFBE) process was used as a severe plastic deformation (SPD) technique to produce ultrafine-grained aluminum rods. Yield strength and tensile strength of the specimens increased by increasing the number of CFBE cycles, while elongation to break decreased due to an increase in the grain refinement and microhardness. According to transmission electron microscopy (TEM) and electron backscatter diffraction (EBSD) results, the average grain size was reduced from 120 μm to 315 nm after only 3 cycles of CFBE  

An exact thermoelasticity solution for a two-dimensional thick composite consisting of homogeneous and functionally graded layers is presented. The thermomechanical properties of functionally graded layers are assumed to vary exponentially through the thickness while the Poisson's ratio is taken to be constant. The heat transfer problem is solved under steady state condition accounting for the heat convection. Utilizing the stress function the governing equation reduces to a fourth order inhomogeneous partial differential equation which is solved exactly using Fourier series method. A comparative study is done between two sandwich structures with homogeneous and functionally graded coatings,... 

In this study, the kinetics of nanocrystallization of amorphous Fe 73.5Si13.5B9Nb3Cu1 (F1) and Fe77Si11B9Nb2.4Cu0.6 (F2) alloys is investigated. The microstructure and magnetic properties of the nanocrystalline alloys are compared. The crystallization temperature of F2 alloy is shifted towards lower temperatures with respect to F1. Thus, the crystalline volume fraction and the crystalline grain size at specific annealing temperature for the F2 alloy are higher than for the F1 alloy, accounting for the higher coercive force of F2 alloy with respect to the one of F1 alloy. According to isoconversional methods, the activation energy for crystallization is variable as a function of transformed... 

Thin films of Fe73.1Cu1Nb3.1Si14.7B8.2 alloy with 200, 500, and 800 nm thicknesses have been deposited by RF sputtering. Their magnetic properties have been characterized using Alternating Gradient Field Magnetometer (AGFM) and Vibrating Sample Magnetometer (VSM). The effects of residual stresses investigated by nanoindentation experiments were conducted on the as-deposited samples. It is observed that the coercivity of as-deposited films is inversely proportional to the thickness in relation with the residual stress induced during sputtering. © 2017 Sharif University of Technology. All rights reserved  

For risk free application of nanoparticles in life science, energy and the environment, it is essential to understand their biological fate and potential toxicity. The application of iron oxide nanoparticles for drug delivery has been one of the most promising researches in the field of nanotechnology. However, there are two major problems associated with magnetically targeted deliveries that still need close attention: • As the drug is coated on to the particle surfaces, there is the possibility of faster drug release (Burst Effect). Therefore, after reaching to the specific site, there is very low amount of drug for delivery. To overcome this problem, some researchers have used conjugation... 

This paper presents a nonlinear size-dependent Timoshenko beam model based on the modified couple stress theory, a non-classical continuum theory capable of capturing the size effects. The nonlinear behavior of the new model is due to the present of induced mid-plane stretching, a prevalent phenomenon in beams with two immovable supports. The Hamilton principle is employed to determine the governing partial differential equations as well as the boundary conditions. A hinged-hinged beam is chosen as an example to delineate the nonlinear size-dependent static and free-vibration behaviors of the derived formulation. The solution for the static bending is obtained numerically. The solution for... 

In this paper, a novel analytical approximation to the nonlinear Duffing-harmonic oscillator is presented. The variational iteration method (VIM) is used to obtain some accurate analytical results for frequency. The accuracy of the results is excellent in the whole range of oscillation amplitude variations. © 2009 Elsevier Ltd. All rights reserved  

A central problem in motor control is to understand how the many biomechanical degrees of freedom are coordinated to achieve a goal. A common assumption is that Central Nervous System (CNS) would minimize a performance index to achieve this goal which is called objective function. In this paper, two popular objective functions are utilized to design the optimal trajectory of trunk movements. A 3D computational method incorporated with 18 anatomically oriented muscles is used to simulate human trunk system. Inverse dynamics allows us to compute torque which is generated around Lumbosacral joint. This torque is divided among muscles by static stability-based optimization. Trunk movement from... 

This paper describes Machine Learning (ML)-based framework to detect leaks in pipes using transient waves. The so-called Transient-Based Leak Detection (TBLD) technology is a non-convex multi-dimensional optimization problem, usually solved by inefficient Metaheuristic Optimization algorithms (MOAs). This paper proposes an efficient ML approach to address this drawback. At the core of this methodology, an ensemble of CatBoost models was trained on >3.8 million data records for classifying the leaky sections and predicting the leak sizes. Results showed that the ML models could detect leaks with 97% accuracy and an F1-score of 0.86, implying a significant superiority compared to the MOAs.... 

In this paper, a size-dependent Timoshenko beam is developed on the basis of the couple stress theory. The couple stress theory is a non-classic continuum theory capable of capturing the small-scale size effects on the mechanical behavior of structures, while the classical continuum theory is unable to predict the mechanical behavior accurately when the characteristic size of structures is close to the material length scale parameter. The governing differential equations of motion are derived for the couple-stress Timoshenko beam using the principles of linear and angular momentum. Then, the general form of boundary conditions and generally valid closed-form analytical solutions are obtained... 

In this paper, a size-dependent formulation is presented for Timoshenko beams made of a functionally graded material (FGM). The formulation is developed on the basis of the modified couple stress theory. The modified couple stress theory is a non-classic continuum theory capable to capture the small-scale size effects in the mechanical behavior of structures. The beam properties are assumed to vary through the thickness of the beam. The governing differential equations of motion are derived for the proposed modified couple-stress FG Timoshenko beam. The generally valid closed-form analytic expressions are obtained for the static response parameters. As case studies, the static and free... 

This paper investigates the deflection and static pull-in voltage of microcantilevers based on the modified couple stress theory, a non-classic continuum theory capable to predict the size effects for structures in micron and sub-micron scales. It is shown that the couple stress theory can remove the gap between the experimental observations and the classical theory based simulations for the static pull-in voltage  

The geometrically nonlinear governing differential equations of motion and the corresponding boundary conditions are derived for the mechanical analysis of Timoshenko microbeams with large deflections, based on the strain gradient theory. The variational approach is employed to achieve the formulation. Hinged-hinged beams are considered as an important practical case, and their nonlinear static and free-vibration behaviors are investigated based on the derived formulation