Sharif Digital Repository

Nanocrystallization kinetics of amorphous Finemet alloy was studied using Vyazovkin advanced isoconversional method under non-isothermal condition. Well known Kissinger model-fitting method and four isoconversional methods of Kissinger-Akahira-Sunose (KSA), Flynn-Wall-Ozawa (FWO), Tang, and Starink were also used for the determination of activation energy. Differential scanning calorimetry (DSC) and X-ray diffraction (XRD) patterns were used for thermal and structural analyses, respectively. According to Vyazovkin and other isoconversional methods, the mean value of variable activation energy, as a function of conversion, was obtained as 350 kJ mol-1. While, according to Kissinger method,... 

The effects of the most important parameters of hot pressing, including temperature, time and pressure on densification, microstructure and infrared transparency of MgF2 ceramics are discussed. The results show that the absorption or scattering of incident radiation is strongly dependent on the amount of porosity. By increasing the temperature or the pressure, transparency at infrared wavelengths has been increased due to the rise in density. For the longer hot pressing times, a continuous increase in density and infrared transparency has been seen as well. Cold pressing before hot press has minor effects on the density and infrared transparency of MgF2. © 2008 Elsevier B.V. All rights... 

The comparative study of Active Screen Plasma Nitriding (ASPN) treatment of two Finemet-type alloys with the compositions of Fe73.5Si 13.5B9Nb3Cu1 and Fe 77Si11B9Nb2.4Cu0.6 was investigated in different temperatures ranging from 410°C to 56°C. Differential Scanning Calorimetry (DSC), X-Ray Diffractometery (XRD), Atomic Force Microscopy (AFM), Scanning Electron Microscopy (SEM), electrical resistivity, microhardness measurements and magnetic characterization by a Vibrating Sample Magnetometer (VSM) were utilized to characterize the treated samples. The comparison of the DSC data for the alloys suggested that the smaller amount of Nb as a growth inhibitor shifted the crystallization... 

The electrochemical corrosion behavior of finemet alloy at various heat treatment temperatures was investigated. Thermal behavior and structural changes were studied using differential scanning calorimetry and X-ray diffractometry, respectively. The electrochemical corrosion of amorphous and annealed samples was investigated in 0.10 M NaOH solution using electrochemical impedance spectroscopy and linear sweep voltammetery. Changes in morphology of the samples before and after corrosion were characterized using optical microscope. The results showed that structural relaxation and nanocrystallization during the heat treatment improved corrosion behavior of the alloy. The heat-treated alloy at... 

A cyclic forward-backward extrusion (CFBE) process was used as a severe plastic deformation (SPD) technique to produce ultrafine-grained aluminum rods. Yield strength and tensile strength of the specimens increased by increasing the number of CFBE cycles, while elongation to break decreased due to an increase in the grain refinement and microhardness. According to transmission electron microscopy (TEM) and electron backscatter diffraction (EBSD) results, the average grain size was reduced from 120 μm to 315 nm after only 3 cycles of CFBE  

The couple stress theory is a non-classical continuum theory which is capable to capture size effects in small-scale structures. This property makes it appropriate for modeling the structures in micron and sub-micron scales. The purpose of this paper is the derivation of the governing motion equations and boundary conditions for the geometrically nonlinear micro-plates with arbitrary shapes based on the modified version of the couple stress theory. The consistent boundary conditions are provided at smooth parts of the plate periphery and also at the sharp corners of the periphery using variational approach  

In this paper, some basis-free expressions for the material time derivative of Lagrangian stress tensors are presented which are generally valid in all cases of coalescent principal stretches. The material is assumed to be elastic and isotropic  

Kinetics of crystallization in an amorphous (Fe0.5Co 0.5)77Si11B9Cu0.6Nb 2.4 (at.%) alloy was investigated using differential scanning calorimetry (DSC). Transformed fraction as a function of temperature was obtained by accurate DSC measurement and the experimental data analyzed with Vyazovkin model-free kinetic method. Reconstructed form of the experimental kinetics model, g(α), clearly showed the crystallization mechanism do not belongs to a single model but almost follows the Avrami-Erofe'ev. Magnetic coercivity and hysteresis loss values of the annealed samples at 823 K were 7.5 A m-1 and 1.2 J m-3, compared to 17.1 A m-1 and 37.1 J m-3 for as spun samples. Magnetic measurements show the... 

The nanocrystallization process of amorphous Fe73.5Si13.5B9Nb3Cu 1 was investigated by active screen plasma nitriding (ASPN) treatment at temperatures ranging from 410 °C to 560 °C for 3 h in two gas mixtures of 75% N2-25% H2 and 25% N2-75% H2 at 5 mbar atmosphere. The amorphous ribbons were then annealed under vacuum at the same time and temperatures mentioned above. The structure of the samples was analyzed using various techniques such as X-ray diffraction (XRD), atomic force microscopy (AFM) and differential scanning calorimetry (DSC). Microhardness measurements, electrical resistivity and Vibrating Sample Magnetometer (VSM) were used to study mechanical, electrical and magnetic... 

In this paper, a size-dependent formulation is presented for mechanical analyses of inhomogeneous micro-plates based on the modified couple stress theory. The plate properties can arbitrarily vary through the thickness. The governing differential equations of motion are derived for functionally graded (FG) plates with arbitrary shapes utilizing a variational approach. Moreover, the boundary conditions are provided at smooth parts of the plate periphery and also at the sharp corners of the periphery. Utilizing the derived formulation, the free-vibration behavior as well as the static response of a rectangular FG micro-plate is investigated  

The nonlocal continuum theories are capable to reflect the small length characteristic of nanostructures. In this work, variational principles are presented for the stability analysis of multi-walled carbon nanotubes under various mechanical loadings based on the nonlocal elastic Donnell's shell by the semi-inverse method. In this manner, a set of proper essential and natural boundary conditions for each layer of the multi-walled nanotube is derived  

In this paper, the coupled three-dimensional flexural vibration of micro-rotors is investigated by taking into account the small-scale effects utilizing the strain gradient theory, which is a powerful nonclassical continuum theory in capturing small-scale effects. A micro-rotor consists mainly of a flexible micro-rotating shaft and a disk. With the aid of Hamilton's principle, governing equations of motion are derived and then transformed to the complex form. By implementing the Galerkin's method, a coupled ordinary differential equation is attained for the system. Expressions for the first two natural frequencies of the spinning micro-rotors are obtained with truncated two-term equation.... 

A semi-analytical three-dimensional elasticity solution for rotating functionally graded disks for both of hollow and solid disks is presented. The aim is to generalize an available two-dimensional plane-stress solution to a three-dimensional one. Although for the thin disks problems the two-dimensional solution provides appropriate results, for the thick disks, a three-dimensional elasticity solution should be considered to avoid poor results. It is shown that although the plane-stress solution satisfies all the governing three-dimensional equations of motion and boundary conditions, it fails to give a compatible three-dimensional strain field. A valid three-dimensional solution has been... 

The nonlinear coupled three-dimensional vibrations of microspinning Rayleigh beams are analytically studied utilizing the modified couple stress theory to take into account the small-scale effects. The considered nonlinearity is of geometrical type due to the mid-plane stretching. The rotary inertia and gyroscopic effects are both included in the formulation. Governing equations of motion are derived with the aid of the Hamilton Principle and then transformed into complex form. Then, the Galerkin and multiple scales methods are utilized to solve the nonlinear partial differential equation. Approximate analytical expressions for nonlinear natural frequencies of the spinning beams in forward... 

In the present paper, some new basis-free expressions for an arbitrary objective corotational rate of the general Eulerian strain measures are provided which are in compact form. Moreover, a complete discussion on the requirements for the continuity of the objective corotational rates are presented. © 2008 Springer Science+Business Media B.V  

The concept of energy conjugacy for stress and strain measures states that a stress tensor T is conjugate to a strain measure E if T: Ė provides the rate of change of the internal energy per unit reference volume of the body in an adiabatic process. The applications of the conjugate stress and strain measures are in the development of the basic relations in nonlinear analysis of solids. In this paper using eigenprojection method, unified explicit basis-free relation between two arbitrary stress tensors T(f) and T (g), respectively conjugate to two measures of Hill's strains is determined. The result is valid for arbitrary dimension of the Euclidean inner product space and for all cases of...