Sharif Digital Repository

In this paper, the use of colloid chemistry in the synthesis of 5 A° lead sulfide semiconductor nanoparticles has been described. Here, hydrogen sulfide gas dissolved in water is used for the chemical reaction, instead of purging the H2S gas into the solution, which has an influence on particle size. In this technique, the growth of particles was controlled by the addition of EDTA. A fast evolution of the optical absorption spectrum demonstrated the following synthesis. Soon after synthesis reaction, the sample exhibits a structural absorption spectrum with one well-defined peak in a 240 nm wavelength. The absorption spectrum shows a featureless structure, with no tail near the absorption... 

Desulfurization by molten caustic leaching (MCL) at 400–500 °C has been investigated in order to reduce the sulfur content of petroleum coke. Effective parameters on desulfurization of petroleum coke, other than temperature, include alkali to feed (petroleum coke) mass ratio, time and mesh size in the ranges of 0.5–1.5, 1–3 h and 200–600 µm, respectively. In this work, petroleum coke desulfurization conditions using solid KOH have been studied. Maximum petroleum coke desulfurization by MCL method has been obtained by Taguchi L9 design using alkali to feed mass ratio of 1, temperature of 600 °C, time of 2 h and mesh size of 200 µm. The changes in the main groups on the coke surface have been... 

The present work describes sensing application of modified TiO 2 nanotubes having carbon-Pt nanoparticles for simultaneous detection of dopamine and uric acid. The TiO 2 nanotubes electrode was prepared using anodizing method, followed by electrodeposition of Pt nanoparticles onto the tubes. Carbon was deposited by decomposition of polyethylene glycol in a tube furnace to improve the conductivity. The C-Pt-TiO 2 nanotubes modified electrode was characterized by cyclic voltam-metry and differential pulse voltammetry methods. The modified electrode displayed high sensitivity towards the oxidation of dopamine and uric acid in a phosphate buffer solution (pH 7.00). The electro-oxidation currents... 

The relation between porosity and permeability parameters in carbonated rocks is complicated and indistinct. Flow units are defined with aim of better understanding reservoir unit flow behavior and relation between porosity and permeability. Flow units reflect a group of rocks with same geological and physical properties which affect fluid flow, but they do not necessarily coincide with boundary of facies. In each flow unit homogeneity of data is preserved and this homogeneity fades in the boundaries. Here, in this study, three methods are used for identification of flow units and estimation of average porosity and permeability in three wells of Tabnaak gas field located in south of Iran.... 

The compressive strength of mass concrete in dams is obtained from laboratory experiments of various cylindrical specimens with diameters of 150, 250, and 300 mm, and heights of 300, 500, and 450 mm, respectively. These specimens with 37.5, 75, and 150 mm maximum size of aggregate were investigated. The 7- and 90-day compressive strength of concrete was found to be between 20 and 58 MPa depending on the size of the specimens. The results reveal the existence of a significant size effect. Based on test results, relationships between the strength of mass concrete specimens and their size and shape are developed. Finally, results and a discussion are presented regarding compressive strength... 

A simple modified TiO2 nanotubes electrode was fabricated by electrodeposition of Pd, Pt and Au nanoparticles. The TiO2 nanotubes electrode was prepared using the anodizing method, followed by modifying Pd nanoparticles onto the tubes surface, offering a uniform conductive surface for electrodeposition of Pt and Au. The performance of the modified electrode was characterized by cyclic voltammetry and differential pulse voltammetry methods. The Au/Pt/Pd/TiO2 NTs modified electrode represented a high sensitivity towards individual detection of dopamine as well as simultaneous detection of dopamine and uric acid using 0.1 M phosphate buffer solution (pH 7.00) as the base solution. In both case,... 

The effects of hydrogen addition, diluent addition, injection pressure, chamber pressure, chamber temperature and turbulence intensity on methane-air partially premixed turbulent combustion have been studied experimentally using a constant volume combustion chamber (CVCC). The fuel-air mixture was ignited by centrally located electrodes at given spark delay times of 1, 5, 40, 75, and 110 ms. Experiments were performed for a wide range of hydrogen volumetric fractions (0% to 40%), simulated diluent volumetric fractions (0% to 25% as a diluent), injection pressures (30-90 bar), chamber pressures (1-3 bar), chamber temperatures (298-432 K) and overall equivalence ratios of 0.6, 0.8, and 1.0.... 

This study presents fundamentals of spray and partially premixed combustion characteristics of directly injected methane inside a constant volume combustion chamber (CVCC). The constant volume vessel is a cylinder with inside diameter of 135 mm and inside height of 135 mm. Two end of the vessel are equipped with optical windows. A high speed complementary metal oxide semiconductor (CMOS) camera capable of capturing pictures up to 40, 000 frames per second is used to observe flow conditions inside the chamber. The injected fuel jet generates turbulence in the vessel and forms a turbulent heterogeneous fuel-air mixture in the vessel, similar to that in a compressed natural gas (CNG) direct... 

The effects of hydrogen addition, diluent addition, injection pressure, chamber pressure, chamber temperature and turbulence intensity on methane-air partially premixed turbulent combustion have been studied experimentally using a constant volume combustion chamber (CVCC). The fuel-air mixture was ignited by centrally located electrodes at given spark delay times of 1, 5, 40, 75 and 110 milliseconds. Experiments were performed for a wide range of hydrogen volumetric fractions (0% to 40%), exhaust gas recirculation (EGR) volumetric fractions (0% to 25% as a diluent), injection pressures (30-90 bar), chamber pressures (1-3 bar), chamber temperatures (298-432 K) and overall equivalence ratios... 

Mn1.5Co1.5O4 oxide spinels are widely used as protective coatings for stainless steel interconnects within planar solid oxide fuel cell stacks. Containing both cubic and tetragonal crystalline phases, these Mn/Co oxide spinels exhibit favorable thermal stability and electronic conductivity for the SOFC interconnect application. Slurry-based coating applications of Mn/Co oxides require precursor powders, which can benefit from being nano-structured. In this study, the sol-gel synthesis of nanocrystalline Mn1.5Co1.5O4 spinel is investigated. The decomposition of sol-gel precursors, as well as the crystalline phase structures and microstructures of the product Mn1.5Co1.5O4 are characterized by... 

Introduction: The Coronavirus disease 2019 (COVID-19) pandemic has caused irreparable damage to the world. In order to prevent the spread of pathogenicity, it is necessary to identify infected people for quarantine and treatment. The use of artificial intelligence and data mining approaches can lead to prevention and reduction of treatment costs. The purpose of this study is to create data mining models in order to diagnose people with the disease of COVID-19 through the sound of coughing. Method: In this research, Supervised Learning classification algorithms have been used, which include Support Vector Machine (SVM), random forest, and Artificial Neural Networks, that based on the standard... 

The potential of electrospun cellulose acetate/chitosan/single walled carbon nanotubes/ferrite/titanium dioxide (CA/chitosan/SWCNT/Fe3O4/TiO2) nanofibers was investigated for the removal of Cr(VI), As(V), Methylene blue and Congo red from aqueous solutions via the adsorption and photocatalytic reduction processes. The properties of synthesized SWCNT/Fe3O4/TiO2 and fibers were characterized using TEM, SEM, FTIR, XRD, TGA and BET analysis. In adsorption process, the influence of adsorbent type including SWCNT to Fe3O4 ratio, TiO2 to SWCNT/Fe3O4 ratio and SWCNT/Fe3O4/TiO2 concentration as well as the adsorption parameters including pH, contact time, and initial concentration of adsorbates on... 

The chitosan-grafted-poly(N-vinylcaprolactam) (chitosan-g-PNVCL) nanofibers were synthesized via electrospinning method. ZIF-8 metal-organic frameworks nanoparticles were incorporated into the nanofibers for adsorption of Cr(VI), As(V) and phenol from water. The BET, FTIR, XRD and SEM analysis were carrfried out to obtain the characteristics of nanofibers. The optimum parameters of ZIF-8 content, pH, contact time, adsorbent dosage, and initial concentration of adsorbates on the Cr(VI), As(V) and phenol removal were studied. The reusability of synthesized nanofibers for five sorption-desorption cycles was also examined. The maximum experimental adsorption capacity of the... 

This paper aims to study the behavior of UPVC-confined columns reinforced with polypropylene fibers under axial compression. A sum of 42 column specimens has been tested, including 18 Unconfined Concrete Cylinders (UCC) and 24 confined Concrete-Filled UPVC Tube (CFUT) specimens. To investigate the sensitivity of these columns to various parameters, different levels of material volumes have been used, which include two concrete strengths of 40 and 50 MPa, two tube grades of PN6 and PN10, and three polypropylene fiber content of 0, 1 and 3 kg/m3 of the concrete mixture. The influence of each variable on the ultimate strength, ductility and confinement effectiveness of the specimens have been... 

The morphology of the perovskite layer, the effective extraction of the charge carriers, and their transport are the main factors determining the power conversion efficiency (PCE) of the perovskite solar cells (PSCs). In this work, we demonstrated that the geometric and electronic structures of the PSCs could be modified by using a conductive polymer additive in the lead (Pb) halide layer prepared by a two-step deposition method. Polypyrrole (PPy) as a conductive polymer is used in the perovskite layers which could increase the PCE of CH3NH3PbI3-xClx mixed-halide PSCs. By adding an optimized amount of PPy, PCE has been raised from 10.4 to 13.2%. PPy acts as a conductive channel facilitating... 

Two-dimensional (2D) and three-dimensional (3D) numerical simulations of an external compression supersonic ramped inlet are presented for a free stream Mach number of 2. A comparison made between numerical results and experimental data showed that multi-block structured gird using standard k - " turbulence model gives acceptable results. The shape of present inlet diffuser was transformed gradually into a circular one to encompass the Aerodynamic Interface Plane (AIP). It was observed that the 3D simulation predicted a more accurate static pressure distribution during the length of supersonic inlet and total pressure distribution at the AIP in comparison with the 2D one. Further, a better...