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Modeling of Reactive Flow in Carbonate Rocks with Continuum Approach from Pore Scale to Core Scale
, M.Sc. Thesis Sharif University of Technology ; Ayatollahi, Shahabeddin (Supervisor)
Abstract
Carbonate reservoir acidizing is one of the most important well stimulation operations that has been widely used in recent years. Modeling the operation prior to any laboratory tests has always been one of the motivations of scientists in recent years due to the complexity of modeling to consider both mass transfer and reaction phenomena. There are several models have been proposed to simulate the acid injection process in carbonate rocks in recent years, the most important one is the Two-Scale Continuum Model (TSCM). This model utilizes the combination of Darcy-scale transfer and reaction equations and a series of pore scale relations to investigate acid injection into two-dimensional...
Modeling of Asphaltene Deposition in Flow Lines Considering Pressure and Temperature Drop
, M.Sc. Thesis Sharif University of Technology ; Ayatollahi, Shahabeddin (Supervisor) ; Assareh, Mehdi (Supervisor)
Abstract
Crude oil is made up of dozens of chemicals which based on their structural similarity, SARA test separate it into four categories: saturates, aromatics, resins and asphaltene. Asphaltenes are recognized as the largest, heaviest and the most polarizable fraction of the crude oil which are in thermodynamic equilibrium with oil at reservoir conditions. Each of the physical, chemical, electrical or mechanical disruption of this balance during production can result in instability and asphaltene precipitation may occur and eventually led to deposition in the reservoir, wells, pipelines, etc. Due to the fact that most changes in temperature and pressure will generated in the wells, thus...
Investigating the Effects of Different Parameters on Asphaltene Deposition Using Electrodeposition Technique
, M.Sc. Thesis Sharif University of Technology ; Ayatollahi, Shahabeddin (Supervisor) ; Taghikhani, Vahid (Supervisor)
Abstract
Additional to Temperature, Pressure and Compositional changes of crude oils, Electro-kinetics and Electrical potential effects are also known as the most influencing parameters on Asphaltene deposition during oil production and processing.Mechanisms of electro-kinetics and asphaltene charge generation are very complex and unclear. In the previous studies on asphaltene precipitation and deposition, mostly electro-kinetics effects are ignored.While, recent studies show the great effects of electrical filed on asphaltene deposition during production and processing phase of crude oils.At reservoir porous medium and crude flow line, an electrical field can be developed along the length of the...
Investigation of the Effect of Asphaltene on Interfacial Tension Behavior of CO2/Oil Systems during CO2 Injection into Asphaltenic Oil Reservoirs
, M.Sc. Thesis Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Ayatollahi, Shahabeddin (Supervisor)
Abstract
Interfacial Tension (IFT) behavior of crude oil/CO2 system is recognized as the main factor affecting the efficiency of CO2 flooding during enhanced oil recovery (EOR) process. Adding paraffin group hydrocarbon to asphaltenic crude oils as an asphaltene precipitant component is aimed to mimic asphaltene precipitation process during crude oil production and transportation. Asphaltene precipitation would critically effects the IFT behavior of crude oil/CO2 systems. In the first part of this study, the equilibrium densities of oil samples which contain different heptane ratio were measured at different pressures and the temperature of 323 K. Then, the equilibrium IFT between CO2 and the crude...
Experimental Investigation of Optimum Acid Injection Rate for Matrix Acidizing in Carbonate Reservoir
, M.Sc. Thesis Sharif University of Technology ; Ayatollahi, Shahabeddin (Supervisor) ; Ghotbi, Sirous (Supervisor)
Abstract
Matrix acidizing as a well stimulation technique is performed to increase the production index by increasing the permeability and removing the formation damage in the near wellbore region. However, several challenges such as corrosion of the tubulars and iron precipitation in the formation are hindering this process. To encounter these challenges, different chemicals, or additives, such as corrosion inhibitors and iron control agents are added to the acid solution. Carbonate acidizing has been carried out using HCl-based stimulation fluids for decades. However, at high temperatures, HCl does not produce satisfactory results because of its fast reaction, acid penetration, and hence surface...
Mathematical Modeling of Diffusion in Fractured Media for Gas Injection
, M.Sc. Thesis Sharif University of Technology ; Masihi, Mohsen (Supervisor) ; Shadizadeh, Reza (Supervisor) ; Ayatollahi, Shahabeddin (Co-Advisor)
Abstract
It is common to inject gas in naturally fractured reservoirs to maintain the reservoir pressure. Recovery will be the result of the complex interplay of several mechanisms such as viscous flow, extraction by molecular diffusion, gravity drainage, oil swelling and capillary force. Generally the main mechanism is gravity drainage However in many cases like low permeability of matrix, small matrix block size and high capillary pressure; gravity drainage may be very low or ineffective. Low permeability results inefficient viscous displacement too. Therefore in these cases the main mechanism is diffusion. The parameters influences the diffusion are: The nature of the injected gas, the composition...
Preparation of Thermosensitive Polymer Nanoparticles to Apply in Smart Enhanced Oil Recovery Process
, Ph.D. Dissertation Sharif University of Technology ; Ramazani Saadatabadi, Ahmad (Supervisor) ; Ayatollahi, Shahabeddin (Supervisor) ; Masihi, Mohsen (Co-Advisor)
Abstract
With the decline in oil discoveries during the last decades, it is believed that enhanced oil recovery (EOR) technologies will play a key role to meet the energy demand in coming years. Polymer flooding has been commonly used worldwide as one of the EOR processes. Literature reviews show that the active water-soluble polymers have a number of limitations related to their surface absorption, undesirable plugging, polymer concentration limitation,expensive, and low thermal, mechanical, bacterial, and salt tolerance. Up to now, five different polymer categories (i.e. polyacrylamide, hydrolyzed polyacrylamide, acrylamidebased resistant copolymers, associative copolymers, and thermoassociative...
Nanotechnology-assisted EOR techniques: New solutions to old challenges
, Article Society of Petroleum Engineers - SPE International Oilfield Nanotechnology Conference 2012 ; 2012 , Pages 382-396 ; 9781622761104 (ISBN) ; Zerafat, M. M ; Sharif University of Technology
SPE
2012
Abstract
Enhanced Oil Recovery techniques are gaining more attention worldwide as the proved oil reserves are declining and the oil price is hiking. Although many giant oil reservoirs in the world were already screened for EOR processes, the main challenges such as low sweep efficiency, costly techniques, possible formation damages, transportation of huge amounts of EOR agents to the fields especially for offshore cases, analyzing micro-scale multi-phase flow in the rock to the large scale tests and the lack of analyzing tools in traditional experimental works, hinder the proposed EOR processes. Our past experiences on using nanotechnology to the upstream cases, especially EOR processes, revealed...
Design and Realization of a Microstrip Antenna Array for Both Automotive Radar Application and 5G Communications at 78/28 GHZ Band
, M.Sc. Thesis Sharif University of Technology ; Farzaneh, Forouhar (Supervisor)
Abstract
With the advancement of automotive technology, the use of automotive radar for collision avoidance and pedestrian detection has been increasingly become universal. In this thesis, our goal is to design a dual-band radar antenna for obstacle detection and a 5G omnidirectional antenna for communication purposes in self-driving cars. We will first introduce the automotive radar and its operation. Next, the FMCW radar, which is simultaneously effective for speed, distance and direction estimation is introduced. Then we introduce the leaky wave antenna as the frequency scanning antenna. This is realized in an SIW waveguide technology. The main issue in this part is the achievement of high...
Effect of resins on asphaltene deposition and the changes of surface properties at different pressures: A microstructure study
, Article Energy and Fuels ; Vol. 28, issue. 4 , April , 2014 , pp. 2415-2421 ; ISSN: 08870624 ; Zolghadr, A ; Ayatollahi, S ; Sharif University of Technology
2014
Abstract
Asphaltene deposition has hindered oil production from asphaltenic oil reservoirs through deposition in reservoir rock and surface facilities. This paper investigates the effect of resin on asphaltene deposition at different pressures. To investigate the asphaltene deposition in the presence of resins at reservoir temperature and different pressures, a pressure, volume, and temperature (PVT) visual cell was designed. A high-resolution microscope and image processing software were used to detect and determine the amount of deposited asphaltene as well as its size distribution at different conditions. Two types of Iranian crude oils with different potential of deposition (low and high) were...
Reduction of fine migration in different pH and salinity conditions using nanofluid
, Article SPE - European Formation Damage Conference, Proceedings, EFDC ; Volume 2 , 2013 , Pages 737-743 ; 9781627486101 (ISBN) ; Pourafshary, P ; Ayatollahi, S ; Sharif University of Technology
2013
Abstract
Movement and transportation of fine particles in formations leads to clogging the pores and reduction in permeability. This type of formation damage is stronglycontingent upon water salinity and ionic conditions in the formation. The main parameters which control the particle release are the interactions and forces between particles and porous medium surfaces. Changing salinity which leads to pH alteration, affects these interactions and subsequently the fine migration process. Hence, pH and salinity variations should be considered to study and evaluate the portion of fine migration in formation damage. The principal challenge in this research therefore, is to try to change the surface...
The gas-oil interfacial behavior during gas injection into an asphaltenic oil reservoir
, Article Journal of Chemical and Engineering Data ; Volume 58, Issue 9 , 2013 , Pages 2513-2526 ; 00219568 (ISSN) ; Mehranbod, N ; Ayatollahi, S ; Sharif University of Technology
2013
Abstract
Oil displacement and recovery efficiency during gas injection depends on the competition between driving forces and capillary resistance that is governed by gas-oil interfacial behavior. Detailed study of the interfacial forces during gas injection is the main objective of this research work. The effects of injecting gas composition and the possibility of asphaltene precipitation in a wide pressure range were determined through comprehensive experimental study. This was performed by measurement of interfacial tension of a highly asphaltenic Iranian crude oil in three surrounding gas mediums. The results showed that as pressure increases, the rate to reach miscibility reduces in the vicinity...
Temperature and composition effect on CO2 miscibility by interfacial tension measurement
, Article Journal of Chemical and Engineering Data ; Volume 58, Issue 5 , March , 2013 , Pages 1168-1175 ; 00219568 (ISSN) ; Escrochi, M ; Ayatollahi, S ; Sharif University of Technology
2013
Abstract
Crude oil reservoirs have different temperatures, compositions, and pressures, therefore oil recovery performance by CO2 injection varies from one case to another. Furthermore, it is predicted that lower interfacial tension between injected CO2 and reservoir fluid results in more oil recovery. In this study, we investigate the effect of temperature on the equilibrium interfacial tension between CO2 and three different oil fluids at different pressures. Also minimum miscible pressure (MMP) is measured by the vanishing interfacial tension (VIT) technique to determine the temperature effect on the CO2 miscible gas injection. The results on different pure and mixtures of hydrocarbon fluids show...
Investigation of effects of salinity, temperature, pressure, and crude oil type on the dynamic interfacial tensions
, Article Chemical Engineering Research and Design ; Volume 115 , 2016 , Pages 53-65 ; 02638762 (ISSN) ; Riazi, M ; Ayatollahi, S ; Sharif University of Technology
Institution of Chemical Engineers
2016
Abstract
The main objectives of this study are to determine the influence of crude oil type, salinity, temperature and pressure on the dynamic interfacial tension (DIFT) of crude oil based on the experiments and modeling approaches. DIFT is also modeled using dynamic adsorption models, mono-exponential decay model as well as empirical equations. The results showed that when temperature increases, unlike deionized water which inversion phase temperature was observed, the equilibrium IFT of crude oils/sea water increases due to reduction of surface excess concentration of natural surfactants at the fluid/fluid interface as a dominant mechanism
Visual investigation and modeling of asphaltene precipitation and deposition during CO2 miscible injection into oil reservoirs
,
Article
Fuel
;
Volume 160
,
2015
,
Pages 132-139
;
00162361 (ISSN)
; Dashti, H
; Ayatollahi, S
;
Sharif University of Technology
Elsevier Ltd
2015
Abstract
Abstract Miscible carbon dioxide (CO2 ) flooding has become the most commonly and favorable approach in Enhanced Oil Recovery (EOR) because of its high oil reservoir sweep efficiency and contribution to the reduction of greenhouse gas emissions. Despite this, it can significantly favor the asphaltene deposition, which leads to the wettability reversal and formation damage. A novel experimental setup was utilized to study asphaltene deposition on the model rock at reservoir condition. The evolution of asphaltene deposition was monitored by a microscope; then analyzed by image processing software to check the amount of deposited asphaltene and its size distribution at different...
Effects of native and non-native resins on asphaltene deposition and the change of surface topography at different pressures: an experimental investigation
, Article Energy and Fuels ; Volume 29, Issue 9 , July , 2015 , Pages 5487-5494 ; 08870624 (ISSN) ; Zolghadr, A ; Ayatollahi, S ; Sharif University of Technology
American Chemical Society
2015
Abstract
Asphaltene deposition during oil production and transportation causes extensive damage to reservoirs and wellhead equipment. In this study, the effects of native and non-native resins as well as those of their mixtures on the asphaltene deposition process are investigated. A novel pressure, volume, and temperature (PVT) visual cell is used to check the effect of resin on asphaltene deposition at different pressures and reservoir temperatures. Two Iranian crude oil samples with different potentials of asphaltene deposition (low and high) were used in these tests. During depressurizing in the presence of native and non-native resins, the amount of asphaltene deposited was measured. To monitor...
Study of Absorption Enhancement of CO2 by SiO2, Al2O3, CNT, and Fe3O4 Nanoparticles in Water and Amine Solutions
, Article Journal of Chemical and Engineering Data ; Volume 61, Issue 4 , 2016 , Pages 1378-1387 ; 00219568 (ISSN) ; Keshavarz, P ; Ayatollahi, S ; Sharif University of Technology
American Chemical Society
2016
Abstract
In this work, the absorption process of carbon dioxide is performed in a custom designed high pressure experimental setup in which the gas and nanofluid are in direct contact at static state in a closed vessel. The initial condition of the tests are set at 20, 30, and 40 bar and 308 K. Nanoparticles of SiO2, Al2O3, Fe3O4, and carbon nanotubes (CNTs) are dispersed in pure water to form nanofluids at concentrations of 0.02, 0.05, and 0.1 wt %. Also, CNT nanoparticle has been dispersed in methyldiethanolamine and diethanolamine aqueous solutions at the concentration of 0.02 wt %. The absorption performances of different nanofluids are compared with the base solutions and with other nanofluids...
Effect of CO2 and natural surfactant of crude oil on the dynamic interfacial tensions during carbonated water flooding: experimental and modeling investigation
, Article Journal of Petroleum Science and Engineering ; Volume 159 , 2017 , Pages 58-67 ; 09204105 (ISSN) ; Riazi, M ; Ayatollahi, S ; Sharif University of Technology
2017
Abstract
Carbonated water has been recently proposed as an enhanced oil recovery method for crude oil reservoirs. Interfacial tension (IFT) plays a crucial rule on the displacement of trapped oil ganglia in the porous media. This investigation is designed to systematically assess the dynamic interfacial tension (DIFT) of two different types of crude oils with carbonated water (CW). In addition, the measured experimental data were applied into specified models. The DIFT behavior of acidic and non-acidic crude oil samples/CW and deionized water (DW) are also compared to find the effect of dissolved carbon dioxide in water on IFT. At the next stage, DIFT of all the results were used through three...
Experimental Investigation of Acidizing in Natural Fractured Carbonates to the Optimum Injection Condition
, M.Sc. Thesis Sharif University of Technology ; Ayatollahi, Shahabodin (Supervisor)
Abstract
In many cases, oil and gas extraction from reservoirs due to damage and permeability reduction near wellbore is lower than optimum level and reduces the flow of oil into the well. In fact, formation damage is the collapse of natural condition of reservoirs, In addition to delaying production and increasing costs, it causes early desertification of wells. Well stimulation methods are used to solve this problem and increase production. One of the most effective ways to increase the production of wells is well acidizing. In this study, the acid performance of the fractured carbonate reservoirs has been investigated. In this type of reservoirs, due to the existence of high permeable paths of the...
Effect of CO2 and crude oil type on the dynamic interfacial tension of crude oil/carbonated water at different operational conditions
, Article Journal of Petroleum Science and Engineering ; Volume 170 , 2018 , Pages 576-581 ; 09204105 (ISSN) ; Riazi, M ; Ayatollahi, S ; Sharif University of Technology
Elsevier B.V
2018
Abstract
Concerns about climate change have persuaded the researchers to examine CO2 injection in the form of carbonated water (CW) into oil reservoir as a safe and effective CO2 storage and enhanced oil recovery process. Although interfacial tension (IFT) between crude oil and injected fluid has a vital role on the displacement of fluids in porous media, the effect of CO2 and crude oil type on the dynamic IFT of crude oil under different operational conditions is not well understood. Accordingly, this study was carried out to assess the effects of temperature, pressure, crude oil type and CO2 on the dynamic IFT of crude oil/CW. To achieve this goal, two types of crude oil were provided from southern...