Sharif Digital Repository

Acidizing is one of the common methods of stimulating the well to remove formation damage and Skin factor. In carbonate reservoirs, hydrochloric acid creates permeable channels called wormholes due to the reaction with the porous medium. Previous researches have studied the effect of the main rock and fluid parameters (temperature, pressure, type and concentration of acid and rock lithology) at the core scale. However, wellbore scale will different from core scale due to the difference in the wormhole density, the flow geometry, the amount of acid leakage from wormhole wall and competition. Very limited models predict these effects for large scales. In this research, the geometry of linear... 

In this thesis, by focusing on the hydraulics of three phase flow in vertical tubing to investigate asphaltene deposition problem, the solid particles behaviors in a turbulent flow is fully studied. Reasonable size distribution for particles (based on previous works and researches) was assumed and a model for 2 sections of a Marrat oil field well to evaluate their asphaltene deposition problem was developed. Three phase liquid-gas-solid flow in the well tubing was simulated. Asphaltene deposition profile on the well tubing, mean and maximum of the deposition rate and particle concentrations in the flow regime were calculated and compared with real field data. Better agreement with field data... 

Water in oil emulsion usually forms during natural water encroachment or enhanced oil recovery processes due to the reaction between asphaltenic and naphthenic acid part of oil with brine in some heavy oil reservoirs. This results in major production challenges because of high w/o emulsion viscosity which leads to significant pressure drops. Therefore, it is essential to investigate the dominant mechanisms of w/o emulsion flow in porous media to overcome the production challenges. In the present study, w/o emulsion behavior is investigated through both static and dynamic tests. The w/o emulsion was prepared through mixing of a crude with brine using magnet stirrer. Emulsion stability... 

Matrix acidizing operation is one of the popular methods of well stimulation in the oil and gas industry which is used to remove near wellbore damage, increase the permeability, hence improve the production rate from the formation. Hydrochloric acid is used in the carbonate reservoirs to remove formation damage and create wormhole deep in the rock. It has been shown that with the proper operating design, significant improvement in the production rate can be obtained. A successful acid operations involves the proper selection of the candidate wells, identify the type of formation damage, stimulation method selection, correct design acidizing scenario, implementation of the technique and... 

There is increasing evidence that injecting modified brines has a significant impact on the amount of oil recovered, but the exact mechanism by which this occurs is an unsettled issue, and is supposed to be a cause of the complex interactions occurring between the phases insitu. In this thesis, surface chemistry of smart water has been investigated. Fluid/solid and fluid/fluid interactions for Bangestan crude oil in tfhe presence of designed solutions and a set of dilutions of Persian Gulf seawater have been studied and compared. Fluid/solid interactions were investigated through wettability studies. Impact of salinity and ionic composition on this interaction was measured through contact... 

Oil and gas reservoirs in various parts of the world have declined over time, despite a high percentage of oil. Due to the increasing need for hydrocarbon resources, the need for more cost-efficient harvesting methods and less environmental damage is felt. Injection of saline water is one of the most cost-effective ways of harvesting due to the need for no expensive additives. On the other hand, microscopic glass modeling can be used to better understand and understand the performance of saline water at the microscopic scale. In this study we have been able to visualize the effective factors in infusion of saline water. Improved interfacial tensile and particle migration in kaolin-coated... 

Low salinity water flooding (LSWF) is one of the enhanced oil recovery (EOR) methods that can be applied in both secondary and tertiary recovery techniques. Some reports indicate no incremental oil recovery associated with this method, and the reason can be associated with the binary and tertiary interactions between oil-brine-rock (OBR) systems. In some OBRs, the initial conditions are not favourable in terms of initial wettability. One of the key factors is the local rock heterogeneities in permeability and mineralogy which can affect LSWF performance because the microscopic and macroscopic heterogeneities can impact the flow pattern of the injected water, oil displacement efficiency, and... 

Crude oil production could cause the thermodynamic equilibrium of the crude oil to be disturbed in the well column which results in asphaltene precipitation and deposition. The thickness of the deposited material grows over time until it completely blocks the well column.Due to the hard and insoluble nature of deposited asphaltene, the two main chemical and mechanical methods are found to be more effective. It should be noted that the actual organic sediments in the piping are not pure and consist of three components: asphaltene, resin and paraffin. Therefore, it is very important to know the composition of the deposited material before selecting the appropriate chemical solvent.The samples... 

Low salinity water flooding (LSWF) as an efficient enhanced oil recovery (EOR) technique is proved to affect both, fluid-fluid and rock-fluid interactions to potentially release the trapped oil from the porous rock. Despite more than one decade of extensive research works on the low salinity water effect (LSWE), there are still many parameters to be studied for very complex cases. Therefore, in the first part of the experimental study of the dissertation, a systematic investigation on the effect of the initial wetting state (water-wet or oil-wet) of pure calcite is conducted to study the importance of fluid/fluid and fluid/rock interactions for LSWE investigation. In the case of initially... 

Considering the water tensions, especially in the Middle East, water resources for the implementation of water-based EOR methods are shown to be critically limited. Water sources such as industrial wastewater hold great potential to be used for this purpose due to their significant available volume and the need for their disposal because of environmental regulations. In this research, the potential of injecting industrial wastewater, as low-salinity water, in an Iranian carbonated oil reservoir has been thoroughly investigated by conducting core-scale experiments. In this regard, we also developed a guideline for designing various types of experiments to use this "unconventional" injection... 

With the increasing demand for clean energy and the need to reduce greenhouse gas emissions, underground hydrogen storage has emerged as an effective strategy for managing energy demand and optimizing the use of renewable resources. Given the importance of the wettability of the hydrogen-water-rock system and its spatial distribution within pores on the performance of hydrogen storage and production from aquifers, and the lack of studies in this field, this fundamental research aims to investigate the effect of rock properties, including wettability distribution and microporosity, on hydrogen and water flow behavior at the pore scale Pore-scale simulations were conducted using computational... 

In field management workflow, after preparation of dynamic reservoir model, next step is determining the uncertain parameters and history matching. In this step, simulation model is conditioned to available field data. In this inverse problem, different geological and petrophysical properties may provide equally good history matches. Such diverse models are likely to show different production behaviors in future. This ties the history matching with the second step, uncertainty quantification of predictions. Multiple history matched models are essential for a realistic uncertainty estimate of the future field behavior.This thesis introduces the application of two novel population-based... 

Acidizing as the most frequent stimulation technique in the field, has been extensively used to increase the production rate. Even though acidizing treatments is well established, there is still an inherent risk for self-induced formation damage through incompatibilities of the fluids involved in this process.
A main potential problem during acidizing is the incompatibility of the acid and the reservoir’s crude oil. Acid interaction with crude oil can produce two major damage mechanisms that could offset partially, if not totally the benefit of the acid stimulation. These mechanisms are the rigid film emulsion formation and the acid-sludge precipitation, result in well productivity... 

Formation damage is probable to occur while drilling, work-over operations, and well completion in near wellbore zone due to different reasons; which leads to excess pressure drop through this area. Well stimulation operations are proposed to remove these damages and improve oil production; among which, acidizing is known as a traditional applicable method to stimulate oil and gas wells. Although this approach is accepted and chosen as a well stimulation method to remove formation damages, its poor design and implementation results in new formation damages. One of these arises when acid contacts asphaltic oil, which causes asphaltene particle instability and asphaltic sludge rapid... 

Underground gas storage has been a topic of discussion and investigation in recent decades. In recent years, with the increasing focus on clean energy and the rise in its production, hydrogen has emerged as a potential option for storing this type of energy. However, there are numerous challenges and obstacles to the large-scale commercialization of underground hydrogen storage. The most significant challenges relate to its physical properties and thermodynamic behavior. These challenges necessitate the exploration of alternative candidates for large-scale energy storage alongside hydrogen. In this research, ammonia is examined as a potential energy carrier, and the novel idea of using it... 

Chemical flooding has great potential to recover significant fractions of remaining oil for medium to heavy oil reservoirs not applicable for thermal recovery techniques. Nowadays, with gradual crude oil price increase the chemical process is receiving renewed attention, however, illustration of the possibility of various chemical injection scenarios for medium to heavy oil reservoirs has not been clearly reported and these kinds of reservoirs require more investigation for the applicability of these techniques in the fields. The interfacial active molecules are responsible for providing low IFT range and water/oil emulsions which in many cases could improve the oil displacement efficiency.... 

Despite the proven advantage of the engineered water flooding technique, a coherent and mechanistic understanding of the fundamental phenomena occurring at pore scale is lacking. Most of the available simulation models have a phenomenological approach and have limited predictive capability. One of the key questions is how to justify and relate large (Darcy) scale observations to effects and phenomena that essentially occur at much smaller scales (i.e. pore and molecular level). Furthermore, two-phase flow dynamics and the effect of complex interplay between wettability, capillary number, and ions dispersion in a heterogeneous porous medium on the trapping and mobilization of oil at pore... 

The study of low-salinity water flooding or smart water flooding as secondary or tertiary oil recovery methods started in 1960 and many researchers have studied the effect of ions types on asphaltene precipitation/deposition during the injecting water into the oil reservoirs. To reduce the asphaltene challenges, one needs to properly investigate this phenomenon and better understanding of the cause of precipitation. It is already known that the amount of asphaltene deposition can be reduced by controlling the deposition criteria. For example, water microemulsion in the oil phase would cause the asphaltenes to be adsorbed on the water oil interface by hydrogen bonds due to heteroatom... 

The increasing trend of greenhouse gas production and the limited resources of fossil fuels has forced industries to find cleaner energy resources. Since hydrogen has the highest amount of energy per unit mass compared to other used fuels, it is expected to play an important role as an energy carrier. Underground hydrogen storage (UHS) is proposed to solve the imbalance between supply and demand of clean energy. UHS in abandoned gas reservoirs is more favorable because the remaining gas in place can play as the cushion gas for more hydrogen recovery. This technique increases the efficiency of hydrogen production however, the purity of the produced hydrogen decreases because of its mixing... 

Due to the potential risk of formation damage caused by organic deposition in enhanced oil recovery processes, laboratory investigations are crucial before making any operational decisions. One of the well-known methods for oil recovery is low-salinity water injection, which may lead to formation damage. This study primarily focuses on experimental evaluation of rock/fluid/fluid interactions and the role of salinity in parameters such as interfacial tension, reservoir rock wettability, emulsion stability, and organic deposition. To achieve this, various experiments—including interfacial tension measurements, emulsion viscosity analysis, contact angle determination, and ionic composition...