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In situ emulsion polymerization and characterization of PVAc nanocomposites including colloidal silica nanoparticles for wood specimens bonding
, Article Journal of Applied Polymer Science ; Volume 137, Issue 15 , 2020 ; Ramezani Saadat Abadi, A ; Haddadi, S. A ; Ghaderi, S ; Azamian, F ; Sharif University of Technology
John Wiley and Sons Inc
2020
Abstract
Polyvinyl acetate (PVAc) nanocomposites for wood adhesives containing different amounts of colloidal silica nanoparticles (CSNs) were synthesized via in situ one-step emulsion polymerization. The adhesion strength of wood specimens bonded by PVAc nanocomposites was investigated by the tensile test. Thermal properties of PVAc nanocomposites were also characterized by differential scanning calorimetry and thermogravimetric analysis. Rheological and morphological properties of the PVAc nanocomposites were investigated using rheometric mechanical spectrometry and field emission scanning electron microscopy (FESEM), respectively. The obtaining results showed that the shear strength of PVAc...
Developing an Integrated Energy and Environment Management System in Industrial Parks. Case Study: Siri Island
, M.Sc. Thesis Sharif University of Technology ; Saboohi, Yadollah (Supervisor)
Abstract
Industrial parks represent integrated industrial systems where it helps implementing efficient measures for managing natural and fossil fuel resources and their impact on environment quality. In Iran, the most industrial parks have faced serious problems due to the irreversible effects on ecosystems. mass/energy flows management and optimization based on industrial ecology, can lead to minimizing the environmental impacts and to maximizing the value added of industrial parks simultaneously. In the present research, sustainable development in Siri island as Eco-industrial park in Iran has been investigated. The island includes: extraction, separation, operation and transportation of crude oil...
The tolerance level of the ecosystem as a limited constrain in the development planning
, Article Ecological Indicators ; Volume 132 , 2021 ; 1470160X (ISSN) ; Saboohi, Y ; Azamian, S ; Sharif University of Technology
Elsevier B.V
2021
Abstract
There are several methods for assessing ecosystem tolerance level, each method is defined according to the target of the ecosystem development. This paper seeks a way to plan for the development of the existing ecosystems modified for human activities. For this purpose, two methods have been applied to assess the effects of local development on the local ecosystem tailored to the different demands. Thus, after gathering data in a coastal region all technologies being capable to be applied in this region regarding ecotourism development (population growth) were determined. Via different indicators, the quality of the ecosystem was evaluated. The Ecosystem Quality Index (EQI) and Technique for...
Water- food- energy- ecosystem nexus model development: Resource scarcity and regional development
, Article Energy Nexus ; Volume 10 , 2023 ; 27724271 (ISSN) ; Saboohi, Y ; Azamian, S ; Sharif University of Technology
Elsevier Ltd
2023
Abstract
Demographic, economic, social, and climate change are all putting pressure increasing on natural resources through global energy, food, and water demand growth, which threatens the well-being of the ecosystems. To address this scientific and political challenge, a dual-purpose optimization tool has been proposed with the approach of minimizing the environmental effects and development costs of the region in line with resource consumption management, which optimally takes resources from the ecosystem, and regarding development approach (ecotourism development in this study), it has suggested the optimal strategy to improve the economic benefits. Moreover, this model is able to propose some...
Exergy analysis of a bio-system: Soil–plant interaction
, Article Entropy ; Volume 23, Issue 1 , 2021 , Pages 1-28 ; 10994300 (ISSN) ; Saboohi, Y ; Valero, A ; Azamian, S ; Sharif University of Technology
MDPI AG
2021
Abstract
This paper explains a thorough exergy analysis of the most important reactions in soil– plant interactions. Soil, which is a prime mover of gases, metals, structural crystals, and electrolytes, constantly resembles an electric field of charge and discharge. The second law of thermodynamics reflects the deterioration of resources through the destruction of exergy. In this study, we developed a new method to assess the exergy of soil and plant formation processes. Depending on the types of soil, one may assess the efficiency and degradation of resources by incorporating or using biomass storage. According to the results of this study, during different processes from the mineralization process...
Exergy cost analysis of soil-plant system
, Article International Journal of Exergy ; Volume 38, Issue 3 , 2022 , Pages 293-319 ; 17428297 (ISSN) ; Saboohi, Y ; Valero, A ; Azamian, S ; Sharif University of Technology
Inderscience Publishers
2022
Abstract
In this paper, inspired by a gas turbine power plant, the interaction between plant-soil processes has been simulated. It is aimed to indicate that solar energy in the photosynthesis process is equivalent to the fuel in combustion chambers. In the glucose production process, when solar exergy is considered as a fuel, 99.4% of total exergy cost is supplied by solar exergy and only 0.6% of the exergy cost is provided by nutrients’ content. In general, 30% of the total exergy entering the Calvin cycle is consumed in glucose production and the remaining 70% is related to biomass generation (as flue gas in the gas turbine). Moreover, 98% of the total exergy cost of the soil box is related to...
Role of Affective Commitment in the Relationship between Ostracism and Turnover Intention
, M.Sc. Thesis Sharif University of Technology ; Banki, Sara (Supervisor)
Abstract
A lot of researchers have suggested that ostracism as a disruptive behavior, has been widespread among organizations and a lot of researches has been studied its consequences in recent years.This research studies ostracism’s consequences and proposes a theoretical model of organizational ostracism with affective commitment, intention to turnover and organizational dependability as one of affective commitment’s antecedents. This study has been done on 231 employees of three medium knowledge-based organizations to identify the effects of ostracism on employee’s turnover behavior. Results show that ostracism, due to its impact on the affective commitment of ostracized peoples, reduces this type...
Study of the Poly (vinyl acetate)/SiO2 Nanocomposites Produced by in Situ Polymerization
, M.Sc. Thesis Sharif University of Technology ; Ramazani Saadat Abadi, Ahmad (Supervisor)
Abstract
The main object of this thesis is synthesizing poly(vinyl acetate)/ colloidal silica nanocomposites via emulsion and in-situ polymerization methods. At the first, nanocomposites were produced in the presence of poly(vinyl alcohol) as the protective colloid, ammonium persulphate as the initiator and sodium bicarbonate as the buffer in an aqueous solution. Then, structural, thermal, rheological, mechanical and surface properties of produced nanocomposites with various colloidal silica content (0.5 %, 1 %, 1.5 %) were evaluated by DLS, FTIR, SEM-EDS, DSC, TGA, dynamic and steady rheological tests, tensile and shear mechanical tests, AFM and static water contact angle. The particle size of...
Chitosan/Gelatin/Mg Substituted Hydroxyapatite Nano Composite Scaffold for Bone Tissue Engineering
, M.Sc. Thesis Sharif University of Technology ; Mohammadi, Mohammad Reza (Supervisor) ; Fathi, Mohammad Hossein (Co-Advisor)
Abstract
The present study is work on fabrication and characterization of a chitosan/ gelatin/ Mg substituted hydroxyapatite nano composite scaffold for bone tissue engineering. At the first step pure and Mg-substituted hydroxyapatite (HA) (Ca10-xMgx(PO4) 6OH2) nano-hexagonal rods with 14–45 nmdiameter.for this, calcium nitrate, magnesium phosphate hydrate and potassium dihydrogenphosphate were used as precursors for Ca, Mg, and P, respectively. Calculated amounts of magnesium ions (Mg+2) especially from 0 to 8% (molar ratio) were incorporated as substituted into the calcium sol solution. Deionized water was used as a diluting media for HA sol preparation and ammonia was used to adjust the pH= 9....
Identifying Active Followership Behaviors in Interaction with Managers with Autocratic Leadership Style in an Iranian Organization
, M.Sc. Thesis Sharif University of Technology ; Alavi, Babak (Supervisor) ; Banki, Sara (Supervisor)
Abstract
Purpose: The purpose of this thesis was to identify active followership behaviors of followers in interaction with autocratic leaders. An active follower thinks critically and takes initiatives.
Design: Given that Followership literature is still in its infancy, the research questions needed a qualitative approach, in this case grounded theory. In total, 19 top- & middle-level managers were interviewed as leaders and followers, accordingly, using semi-structured interviews.
Findings: 4 categories of active followership were found, each having 3-4 specific behaviors. These categories are: precautionary behaviors, facilitating behaviors, modificating behaviors, and consolidating...
Design: Given that Followership literature is still in its infancy, the research questions needed a qualitative approach, in this case grounded theory. In total, 19 top- & middle-level managers were interviewed as leaders and followers, accordingly, using semi-structured interviews.
Findings: 4 categories of active followership were found, each having 3-4 specific behaviors. These categories are: precautionary behaviors, facilitating behaviors, modificating behaviors, and consolidating...
An Investigation of the Mediating role of Organizational Cynicism on the Relations between the Politics Perception and Organizational Commitment
, M.Sc. Thesis Sharif University of Technology ; Alavi, Babak (Supervisor) ; Banki, Sara (Supervisor)
Abstract
There is no consensus definition of cynicism in literature. In this research different definitions of cynicism have been investigated and two concept of organizational cynicism and trait cynicism have been taken into consideration. Organizational cynicism is a negative attitude that is prevalent in employees. In literature some antecedents and consequences of organizational cynicism have been suggested. It seems organizational cynicism can be investigated in a more complex relations. The focus of this research is on the mediating role of organizational cynicism on the likely relations between politics perception and organizational commitment. That is to say organizational cynicism can...
The Influence of Authentic Leadership on the Relationship between Transformational Leadership, and Feedback-seeking Behaviors
, M.Sc. Thesis Sharif University of Technology ; Alavi, Babak (Supervisor) ; Banki, Sara (Supervisor)
Abstract
Feedback-seeking behavior is the effort of employees to get feedback from the environment and around people about their performance. One of the research questions in this field is about the factors that increase this behavior in the staff. Transformational leadership as a leadership style, stimulates, and motivates followers to achieving desirable operational results. In addition, an important consequence of this style could be increasing the followers' capabilities. Transformational leaders are trying to empower their followers to build and empower them, which can provide a strong incentive for employees to move and grow, which may encourage them to have a better performance. One of...
Applying Gamification in Corporate Entrepreneurship Culture, Specially Missionary Organizations; Through SafirFilm Case Study
, M.Sc. Thesis Sharif University of Technology ; Yavari, Elham (Supervisor) ; Banki, Sara ($item.subfieldsMap.e)
Abstract
Although existing literature on organizational culture and its change process contains meaningful and rich theories but our studies show that there is no perfect and detailed framework on linking organizational culture change and corporate entrepreneurship culture. In addition to that, Gamification –defined as taking the game design elements into non-game contexts– is a fruitful and academically rich research area. Fortunately an idea proposed recently to explain a method for enhancements in organizational culture in general, and in corporate entrepreneurship culture in particularby Yavari and Jafarian based on using game mechanisms. In their paper "A Gamification-Based Method for Corporate...
Synthesis of Tin and Ti2n Nanostructured Coatings on Ti alloys Using Magnetron Sputtering System And Comparison of Their Biocompatibility Properties
, M.Sc. Thesis Sharif University of Technology ; Nemati, Ali (Supervisor) ; Khamse, Sara (Supervisor)
Abstract
Considering the importance of biocompatibility of implantable prothesis’, metallic alloys have weaker corrosion resistance than ceramics. In order to extend usage of nanomaterials to improve the bio-properties of materials, Nano-structured ceramic coatings are being suggested to improve corrosion resistance and biocompatibility of prosthesis. Meanwhile, very good properties of TiN, such as corrosion resistance and mechanical properties as a thin film coating are undeniable. In this study, TiN and Ti2N thin film were deposited on Ti-based substrate, using PVD and Magnetron sputtering at different argon to nitrogen ratio. The crystal structure of the films was examined using Grazing XRD...
The Instructional Effect of Dynamic-assessment, Non-dynamic Traditional Assesment, and Non-assessment Courses on Iranian EFL Learners' Interlanguage Pragmatic Production
, M.Sc. Thesis Sharif University of Technology ; Tajeddin, Zia (Supervisor) ; Alemi, Minoo (Supervisor)
Abstract
There are several methods proposed for the instruction and assessment of interlanguage pragmatic competence of foreign language learners. Dynamic assessment as one of the recent methods arising from Vygotsky’s sociocultural theory of mind incorporates assessment and instruction by engaging learners in a process of interaction with the mediator while the learners are trying to perform a challenging task. The present study aimed to explore the advantage of Dynamic Assessment as an instructional instrument over the Non-dynamic (traditional) Assessment and Non-assessment approaches and their effects on the Iranian intermediate level students. The target speech acts of apology, complaint, and...
Monitoring of Structure Characteristics, Humidity, Temperature and Torsion Using Optical Fiber Sensor
, Ph.D. Dissertation Sharif University of Technology ; Bahrampour, Alireza (Supervisor) ; Tofighi, Sara (Supervisor)
Abstract
Fiber optic sensors have found industrial applications due to their unique characteristics and wide range of environmental parameters. Specifically, distributed optical fiber sensors which have applications in borders protection, intrusion detection, oil and gas leakage detection and smart irrigation of farms and gardens, have attracted significant attention from research groups around the world in recent years. According to the forecasts, among all kind of optical fiber sensors, the temperature and acoustic/vibration sensors will seize the market during the coming years. In this thesis, three kind of optical fiber sensors are proposed for environment health monitoring. First, distributed...
A credible role of copper oxide on structure of nanocrystalline mesoporous titanium dioxide
, Article Journal of the Iranian Chemical Society ; Volume 5, Issue 3 , September , 2008 , pp. 367-374 ; 1735207X ; Rahman Setayesh, S. (Shahrbanoo) ; Gholami, M. R. (Mohammad Reza) ; Sharif University of Technology
2008
Abstract
Copper oxide-titania catalysts with nanocrystalline mesoporous structure were prepared by sol-gel technique using tetra isopropyl ortho titanate (TiPT) as the inorganic precursor and amino-2 ethanol as the swelling agent. Characterization was performed using X-ray diffraction (XRD), fourier transformed infrared spectra (FTIR), scanning electron microscopy (SEM), diffuse reflectance UV-Vis spectroscopy (DRS), and N2 adsorption-desorption measurements. It was found that CuO (0.025-0.1 mol ratio) has some effect on the particle size, surface area, pore-volume, pore-diameter, crystallinity of the particles, and crystalline phase of TiO2 nanocrystalline. The results indicated that 0.1 CuO-TiO2...
Design and Fabrication of Microfluidic Biosensors based on Modified Electrospun Nanofibrous Membranes for Biomarkers Detection
, Ph.D. Dissertation Sharif University of Technology ; Vosoughi, Manuchehr (Supervisor) ; Soleimani, Masoud (Supervisor) ; Soudi, Sara (Supervisor)
Abstract
The accurate assessment of biomarkers likes proteins, hormones or other biomolecules that amount of them changes with state of disease or level of treatment and gives diagnostic information is a difficult duty. In these samples, pathogens exist in small quantity compared to other background molecules. Therefore, appropriate sampling process for concentrating and separating pathogens from the matrix should be developed in order to provide rapid and accurate pathogen detection test. In this thesis design and fabrication of microfluidic biosensors based on the modified nanofibrous membranes were investigated and explained. PES nanofibrous membrane with carboxyl functional groups for covalent...
Surfactant-assisted synthesis and characterization of hydroxyapatite nanorods under hydrothermal conditions
, Article Materials Science- Poland ; Volume 27, Issue 4 , 2009 , Pages 961-971 ; 01371339 (ISSN) ; Solati Hashjin, M ; Sara Shafiei, S ; Goudarzi, A ; Salarian, R ; Nemati, A ; Sharif University of Technology
2009
Abstract
Hydroxyapatite (HAp) nanorods with uniform morphology and controllable size were successfully synthesized by precipitating Ca(NO3) 24H2O and (NH4)2HPO4 in the presence of cetyltrimethylammonium bromide (CTAB) and polyethylene glycol 400 (PEG 400) as cationic surfactant and non-ionic cosurfactant, respectively, under hydrothermal conditions. The effect of hydrothermal temperature on the composition, morphology and size of HAp particles was studied using X-ray diffraction (XRD), Fourier transform infrared spectrometry (FTIR) and scanning electron microscopy (SEM). Results revealed that the morphology and size of HAp particles can be effectively controlled by the presence of CTAB and PEG...
Designing an Intelligent System to Analyze Electrograms of Induced Pluripotent Stem Cell-Derived Cardiomyocytes
, M.Sc. Thesis Sharif University of Technology ; Rabiee, Hamid Reza (Supervisor) ; Soleymani, Mahdieh (Supervisor) ; Pahlavan, Sara (Co-Advisor)
Abstract
Ability to differentiate induced pluripotent stem cells to cardiomycocytes has attracted attentions,considering crucial role of the heart in the human body and great potential applications of these cells like disease modeling, new treatment methods and basic research. We are able to analyze the performance of beating cells through recording extracellular field potentials of cardiomyocytes using multi-electrode array (MEA) technology. This analysis is an essential step to use cardiac cells in any future development and experiment. Currently, the electrophysiology experts analyze recorded extracellular field potentials of induced cardiomyocytes by observing all the episodes of each record....