Sharif Digital Repository

Fuel cells convert the chemical energy of hydrogen and oxygen directly into the electricity. Their high efficiency and low emissions have made them a prime candidate for powering the next generation electric vehicles. Polymer electrolyte membrane is a key component of the PEM fuel cells. One of the critical problems to overcome in some PEM fuel cells is the water management because If there is not enough water, the membrane becomes dehydrated which leads to a rapid increase in ohmic resistance. On the other hand, if too much water is present, flooding may occur resulting in the pores of the gas diffusion filled by water and the available passage for reactant gases is decreased. In this work... 

The main object of this thesis is production and investigation of polypropylene-fumed silica nanocomposites by using bi-supported Ziegler-natta catalytic system and in-situ polymerization. Magnesium ethoxide and fumed silica were used as supports of catalyst. TiCl4 was accompanied by triisobutyl aluminum(TiBA) and diisobutyl phthalate(DIBP) as electron doner constituting Ziegler-Natta catalytic system. Preparation of catalyst and polymerization were taken place in slurry phase under the argon atmosphere. At the beginning of the polymerization experiment, several type of nanocomposites were made under various conditions(such as different Al/Ti molar ratio) to find optimum condition to...