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    Synchronization of Two Chemical Reactors

    , M.Sc. Thesis Sharif University of Technology Babaei Pourkargar, Davood (Author) ; Shahrokhi, Mohammad (Supervisor)
    Abstract
    Chaotic behavior takes place in different physical systems such as chemical reactors. In this thesis, dynamical behavior of chemical reactors in which polymerization or series reactions take place has been considered. It has been shown that these reactors have chaotic dynamics under special condition. Two reactors of the second type (with series reactions) for cases of known and unknown parameters have been synchronized by a control method and stability of the proposed scheme has been established by the Lyapunov stability theorem. Simulation results show the effectiveness of proposed method. Since concentration measurement is difficult and expensive, an observer has been used for... 

    Thermodynamic and transport properties estimation of a complicated mixture of hydrocarbons by fuzzy clustering methods

    , Article 19th International Congress of Chemical and Process Engineering, CHISA 2010 and 7th European Congress of Chemical Engineering, ECCE-7, 28 August 2010 through 1 September 2010 ; 2010 Babaei Pourkargar, D ; Ahmadi Orkomi, A ; Bozorgmehry Boozarjomehry, R ; Sharif University of Technology
    2010
    Abstract
    Clustering is the term used in several research communities to describe methods for grouping of unlabeled data. The objective in clustering is to divide the data set in such a way that the intra-class similarity is high and inter-class similarity is low. It is very helpful to find a system's states distributions, but when the system's scale is large, e.g., considering a distillation column that has crude oil as its feed, if one of desired is finding concentration of most popular hydrocarbons (ethane, propane, octane, etc.) on each tray, it should be solve species continuity for each component. A mixture of 100 hydrocarbons was classified into 10 clusters by different clustering methods,... 

    Approximate fuzzy feedback linearization of amine gas sweetening plant via genetic algorithm

    , Article 19th International Congress of Chemical and Process Engineering, CHISA 2010 and 7th European Congress of Chemical Engineering, ECCE-7, 28 August 2010 through 1 September 2010, Prague ; 2010 Ahmadi Orkomi, A ; Babaei Pourkargar, D ; Bozorgmehry Boozarjomehry, R ; Sharif University of Technology
    2010
    Abstract
    A new approach for static state feedback linearization of single input and multi-input systems is put forward. The approach can be applied to wider class of systems than the classical feedback linearization. The main idea is to transform the nonlinear system via a change of coordinates and static state feedback into a linear system with desired dynamics. This circumvents the need to transform the input vector fields into constant vectors in the new coordinates. An amine gas sweetening process has been simulated as a nonlinear system, then the system is linearized using the approximate fuzzy feedback linearization method. The rules of the fuzzy system have been optimized by genetic algorithm... 

    Modeling catalyst deactivation in dehydrogenation of ethylbenzene to styrene

    , Article 11AIChE - 2011 AIChE Spring Meeting and 7th Global Congress on Process Safety, Conference Proceedings ; 2011 , Pages - ; 9780816910670 (ISBN) Babaei, J ; Baghalha, M ; Sharif University of Technology
    American Institute of Chemical Engineers  2011
    Abstract
    The long-term deactivation of a commercial K-promoted Fe2O3 catalyst used in the dehydrogenation of ethylbenzene to styrene monomer was investigated using 30 mo of operating data of three industrial SM radial fixed bed adiabatic reactors. The Langmuir-Hinshelwood, Hougen-Watson model was used for reaction kinetics modeling. The kinetics of coking from ethylbenzene and styrene and the short-term deactivation function due to the quick coke formation were considered in the model. The kinetics of long-term deactivation of the catalyst for ethylbenzene dehydrogenation to styrene at 550°-630°C were determined. Unknown parameters of the long-term activity function, related to the slow loss of... 

    Modeling catalyst deactivation in dehydrogenation of ethylbenzene to styrene

    , Article AIChE Annual Meeting, Conference Proceedings, 13 March 2011 through 17 March 2011 ; March , 2011 ; 9780816910670 (ISBN) Babaei, J ; Baghalha, M ; Sharif University of Technology
    2011
    Abstract
    Long-term deactivation of a commercial K-promoted Fe 2O 3 catalyst used in the dehydrogenation of ethylbenzene to styrene monomer was studied using 30 months of operating data of three industrial SM radial fixed bed adiabatic reactors. The Langmuir-Hinshelwood, Hougen-Watson model (LHHW) was used for reaction kinetics modeling. The kinetics of coking from ethylbenzene and styrene and the short-term deactivation function due to the quick coke formation were also considered in the model. The kinetics of long-term deactivation of the catalyst for ethylbenzene dehydrogenation to styrene between 550 and 630 °C were determined by allowing the effects of temperature and time on the catalyst... 

    Effects of temperature and mixing modes on the performance of municipal solid waste anaerobic slurry digester 09 Engineering 0907 Environmental Engineering 09 Engineering 0904 Chemical Engineering

    , Article Journal of Environmental Health Science and Engineering ; Volume 17, Issue 2 , 2020 , Pages 1077-1084 Babaei, A ; Shayegan, J ; Sharif University of Technology
    Springer  2020
    Abstract
    Purpose: Anaerobic digestion is a promising technology for simultaneous treatment of biodegradable organic matter of municipal solid waste (MSW) and production of renewable energy. Mixing modes and temperature have influences on biogas production in anaerobic digesters treating MSW. Therefore, in this study, digester was operated at different modes of mixing and temperatures to obtain design criteria. Methods: The experiments were carried out in a semi-continuous digester. In the first part of the investigation, temperature was set at 25, 28, 31 and 34 °C. During this step, digester content was mixed in an intermittent mode by mechanical mixers. In the second part of the study, mixing... 

    Traffic Source Particle Pollution Distribution Using Micro-scale Simulation

    , M.Sc. Thesis Sharif University of Technology Babaei, Mahdi (Author) ; Hosseini, Vahid (Supervisor)
    Abstract
    Today air pollution has become one of the major urban management concerns. Air pollution could have dangerous effects on human health in short time or long time in many situations. Numerical modelling is one of the most applicable among different ways for predicting pollutant concentration like field measurement, physical model in wind tunnel, and simulation. Modelling of pollutant dispersion is a way for estimating concentration and aggregation of the pollutant near the surface and with different distances from pollution source. In different dispersion models, one of simplest is the Gaussian model. In this approach it is supposed that emission plume obeys from Gaussian distribution and is... 

    Point to point Control of a Brachiation Robot Based on Neural Network

    , M.Sc. Thesis Sharif University of Technology Babaei, Bashir (Author) ; Vossoughi, Gholamreza (Supervisor)
    Abstract
    • Brachiation robot is a kind of under-actuated robots. A brachiating robot is a type of a mobile arm that is capable of moving from branch to branch similar to a long-armed ape. The purpose of this thesis is control of a two link Brachiation robot. The purpose of this thesis is control of a two link Brachiation robot using neural network and geometry control. For this purpose a genetic algorithm based training Neural Network is used to produce a suitable path for the second link of the robot and then using input-output linearization method, the second link is controlled to follow the path. The simulations shows that the Nero Controller designed in this thesis is suitable. The controller can... 

    Seismic Rehabilitation of Irregular Steel Structures Using Friction Dampers

    , M.Sc. Thesis Sharif University of Technology Babaei, Hossein (Author) ; Moghaddam, Hassan (Supervisor)
    Abstract
    The purpose of this study was to find the optimal position and slip force of friction dampers, for improving the seismic performance of regular and irregular steel structures and comparison of dampers final pattern of these buildings.In this regard, one to six floor regular and irregular buildings were designed. These buildings were modeled three-dimensionally in the OpenSees Software, and were subjected to horizontal components of seven far field accelerogram in order to investigate the need for their rehabilitation. The results of the time history analysis of these buildings showed that inter-story drifts exceeds the acceptance criteria which has been assumed 2.5% according to the Life... 

    Cryptanalysis of a Class of McEliece-like Code-Based Signature Schemes

    , M.Sc. Thesis Sharif University of Technology Babaei, Ali (Author) ; Eghlidos, Taraneh (Supervisor)
    Abstract
    With the advent of quantum computers, the security of cryptographic primitives, including digital signature schemes, has been compromised. Therefore, a kind of signature scheme has been introduced to resist these computers. These schemes are based on hard problems that have so far resisted against quantum computers, known as post-quantum schemes. One group of these schemes is based on the hard problems of coding theory, which are called code-based cryptographic schemes. The first code-based cryptosystem was the McEliece encryption scheme. A number of code-based signature schemes are based on the McEliece encryption scheme. Some of these schemes use three matrices including a non-singular... 

    Iranian Household Saving Behavior

    , M.Sc. Thesis Sharif University of Technology Samaee, Kian (Author) ; Souri, Davood (Supervisor)
    Abstract
    This paper decomposes the saving rate into cohort, age and year effects. This objective is accomplished by constructing a pseudo-panel that amalgamates nineteen consecutive, cross-sectional Household Income and Expenditure Surveys from 1991 to 2009. To construct year-of-birth cohorts with consistent composition over time, analyses are limited to those born between 1926 and 1975. Results reveal that those belonging to younger cohorts save a higher fraction of their income relative to their predecessors at the same age. Moreover, the increase in the saving rate can not be explained by the significant decline in household size or rise in educational attainment among younger cohorts. Closer... 

    The Effect of Fence to Dilute the Dense Gas Dispersion Using CFD Model

    , M.Sc. Thesis Sharif University of Technology Maroofi, Jooya (Author) ; Rashtchian, Davood (Supervisor)
    Abstract
    Release of toxic gases and hazardous materials is very dangerous for health of people that presence in near of release places. Whereas if the concentration of some toxic materials is more than a definite limit, it may cause of irreparable hurt to health of people in very short times, hence reduce the concentration of released materials can get the time for refuge in safe sites for people that presence in released site in initial times.
    In this paper with use the Computational Fluid Dynamics models the effect of fence in reduce the concentration of dense gases and delay the distribution of these gases has been studied. The two toxic gas (chlorine and methyl-isocyanate ) have been... 

    Offering a Simple Method to Determine Safe Distance between Gas Pipelines and Vicinal Areas

    , M.Sc. Thesis Sharif University of Technology Bagheri, Mojtaba (Author) ; Rashtchian, Davood (Supervisor)
    Abstract
    Sour Gas is more dangerous than sweet gas because of its hydrogen sulfide contents. So it requires more safety considerations. In this project, the effect of wall thickness and design factor of pipeline on the safe distance was examined by using risk assessment method. The safe distance tables for 4 pipelines with different wall thicknesses and design factors were prepared based on operating pressure, pipe diameter and hydrogen sulfide concentration in gas by using PHAST and PHAST RISK softwares. In this project, the depth of cover parameter was considered in safe distance determination. Also the leak of sour gas was simulated by using... 

    Modeling of Atmospheric Toxic Release and Dispersion Using CFD

    , M.Sc. Thesis Sharif University of Technology Mokhtari, Mojtaba (Author) ; Rashtchian, Davood (Supervisor)
    Abstract
    In this project, ammonia dispersion in the environment have been investigated and the experimental data have been used in order to show accuracy of calculations. Also, the results of CFD have been compared with the results of PHAST software. The results show that when there is no obstacle in the way of gas release, dispersion models will get good results, but due to existence of the obstacle, their error will be increased to 300%. However, the error resulting from CFD is less than 24% even if there are obstacle there. The effects of obstacle’s distance and height on the dispersion of ammonia gas are investigated. This study showed that the concentration of ammonia increase, when the distance... 

    Optimum Process Unit Layout via Risk Assessment

    , M.Sc. Thesis Sharif University of Technology Kareshki, Hamid (Author) ; Rashtchian, Davood (Supervisor)
    Abstract
    One of the most important stages to designing a process plant is layout of equipment in unit area. There are plenty of routine procedures to find out equipment arrangement and their separation distances based on process and cost criteria. Although some studies have been carried out to enter safety parameters to conventional procedures, the problem complexity because of the number of involved equipment is still of concern. To clear these ambiguities, the new approach presented in this thesis is aimed at quantifying the effects of adjacent equipment on each other. In this way, fire radiation and explosion have been selected as the major hazard that any equipment can expose on the other items,... 

    Dispersion Modeling of Toxic Release (Chlorine) by CFD in Industrial and Urban Areas

    , M.Sc. Thesis Sharif University of Technology Asgari, Sepideh (Author) ; Rashtchian, Davood (Supervisor)
    Abstract
    Chlorine is used in large quantities, in urban and industrial installations. Since chlorine is a toxic gas, its dispersion in such environments may have unpleasant consequences. On the point of Emergency Response Planning, it is important to know how such gases disperse. In this thesis, chlorine atmospheric dispersion is studied as an example of toxic dense gas dispersion. Chlorine accidental release from one of the storage tanks of Sohanak water refinery is selected for the case study. Laleh residential town is located in west of Sohanak refinery. According to the prevailing wind direction in Tehran (which is from the west to the east), the influence of the buildings of Laleh town on gas... 

    Safety of Plant Layout by Risk Assessment

    , M.Sc. Thesis Sharif University of Technology Moghaddasi, Mahboubeh (Author) ; Rashtchian, Davood (Supervisor)
    Abstract
    One of the most important stages to designing a process plant is layout of equipment in unit area. There are plenty of routine procedures to find out equipment arrangement and their separation distances based on process and cost criteria. One of this Procedures is the use of codes and standards. Although some studies have been carried out to enter safety parameters to conventional procedures, the problem complexity because of the number of involved equipment is still of concern. To clear these ambiguities, the new approach presented in this thesis is aimed at quantifying the effects of adjacent equipment on each other. In this way, fire radiation and explosion have been selected as the major... 

    Consequences Analysis of Dust Explosions to Determine the Damage to Humans and Buildings

    , M.Sc. Thesis Sharif University of Technology Bakhtiari, Saeed (Author) ; Rashtchian, Davood (Supervisor)
    Abstract
    Dust explosions are a serious hazard in many process industries and storage facilities. More than 70% of dusts processed in industry are combustible. This implies that majority of industrial plants that have dust processing equipment are susceptible to dust explosions. Dust explosions pose the most serious and widespread of explosion hazards in the process industry alongside vapour cloud explosions (VCE) and boiling liquid expanding vapour explosions (BLEVE). Dust explosions almost always lead to serious financial losses in terms of damage to facilities and down time. They also often cause serious injuries to personnel, and fatalities. In this project we presented a systematic algorithm in... 

    Process Modeling of Liquid-Ring Compressor for Flare Gas Recovery

    , M.Sc. Thesis Sharif University of Technology Mesbah, Mohammad (Author) ; Rashtchian, Davood (Supervisor)
    Abstract
    The main application of flares is to protect facilities, staff, and surrounding area. Nevertheless, the flares flue gas contains environmental hazardous compounds like nitrogen oxides, sulfur oxides, and greenhouse gases like carbon dioxide and carbon monoxide. These compounds may spread in environment with unburned hydrocarbons. Due to the contamination risk and energy loss in flaring system, optimization and system enhancement is of vital importance. Flare gas recovery unit consist of equipment like multi-phase separator, Liquid Seal Drum, and compressor. The compressor is the most important part of this unit. Due to the process requirements and the probability of two-phase feed entering... 

    Consequence Modelling of Ethylene Oxide Reactor of Morvarid Petrochemical Co

    , M.Sc. Thesis Sharif University of Technology Shahriari, Esmaeel (Author) ; Rashtchian, Davood (Supervisor)
    Abstract
    As Ethylene Oxide is a highly toxic, flammable, and hazardous material, the consequences of any malfunction in an Ethylene Oxide reactor may be irreparable. The aim of this thesis is to evaluate the probable consequences of an accident in Morvarid Petrochemical Co.’s Ethylene Oxide Reactor in order to find probable hazardous scenarios. In this project, probable accidents were modelled and evaluated by Phast software in different scenarios, and the outcomes were investigated. In addition, if necessary, a set of solutions were proposed to decrease casualties in hazardous scenarios. The results may be used to change layouts according to Consequence Modelling. Results illustrated that...