Sharif Digital Repository

Hydrocracking is a hydrogen addition process that permits refineries to convert heavier, less expensive crudes, into highly-valued transportation fuels such as gasoline, kerosene and diesel. Development of an accurate kinetic model for hydrocracking reactions is crucial to correctly predict the detailed product distribution under different operating conditions for a range of feedstocks as well as for reactor design, process optimization and catalyst selection. In this thesis a mechanistic kinetic model was developed for thermal hydrocracking of a paraffinic feedstock. This model was based on a molecular approach that was able to capture the fundamental chemistry of hydrocracking process. To... 

By far, the most expensive part of the production optimization process is the evaluation of the objective function because this requires computationally expensive reservoir simulations to be performed.One way to reduce this high computational cost isby using surrogates or proxies for the reservoir simulator. There are different methods for constructing a surrogate that their aims are mimicking the reservoir behavior with high accuracy and low computational cost. In reservoir engineering surrogate modeling has been used for the problem of well placement optimization,while in the context of production optimization it has not yet been investigated in the literature. Moreover, most of surrogate... 

According to global improving consumption of distillate products, like gasoline and diesel, reduction in light petroleum production and growth in exploring and extraction of heavy and sour petroleum, changing in refining structure of worldwide oil refineries is necessary and it is crucial to apply special processes for refining, conversion and cleaning of these heavy and extra-heavy petroleum. Gasification of these fuels, i.e. partial thermal oxidation of feed in the presence of gasifying agent (air, oxygen, steam or mixture of them) in the gasifier, is one of the new ways to convert heavy fuel oil to synthetic gas (syngas), that this gas can be used widely in downstream processes. Here,... 

Fractured carbonate reservoirs are mostly oil-wet to intermediate-wet. Due to the negative capillary pressure of the matrix poor spontaneous imbibition of reservoir brine occurs in such reservoirs, and water flooding leads into early break through due to the high conductivity of the fracture network. Some surfactants have the ability to change the wettability of rock matrix toward water-wet state by adsorbing onto the rock surface. The phenomenon can result in spontaneous imbibition improvement and thereby increasing water flooding efficiency and recovery from fractured carbonate reservoirs. In this thesis the effect of some surfactants on the wettability of Iranian carbonate reservoir rocks... 

Todays, the most important thing in the oil and gas fields is how to find the main properteis as porosity and permeability; therefere in this project was tryed to estimate to correct porosity in the reservoir area with using estimated porosity from siesmic attributes. For this study Mishrif reservoir in Sarvak formation was selected and the used data are 3D siesmic and also corrected porosity estimated by analysing siesmic attributes from five wells. For combination sresmic and log data, Simulated Annealing was seleted as a Neural Network optimizer for this project.
 

One of the suitable methods in EOR processes is miscible and immiscible gas injection. By gas injection, it is possible to replace all the oil, which is in contact with the gas. However, reservoir heterogeneity, low density, and low viscosity of gas result in problems such as gravity segregation, and fingering and consequently the gas reach the production well without any significant contact with reservoir oil. A way to deal with this problem is gas injection in the form of foam. In fact, gas injection in this manner increases the oil production by decreasing gas mobility and the negative effects of reservoir heterogeneity on gas displacement. Foam stability has a key role on the efficiency... 

Many technologies should be applied for transportation or consumption of natural gas. There are many different ways for transporting natural gas from origin of production to the location of consumption which the simplest way is transportation via pipelines but for transportation of natural gas for long distances, we can not use this method in this way we should apply other technologies such as converting the natural gas to the liquid state. For using this method, first we should liquefy the natural gas up to -162 degree of centigrade at the atmospheric pressure and then transport it with large cargo ships. By using this method, the transportation costs are decreased in compared with the... 

In this work the effect of composition changes of the injection gas (Hydrocarbon gas + carbon dioxide) on Water Alternating Gas (WAG) performance in immiscible flooding which has been rarely attended in the available literature is investigated. Core flood experiments are conducted on a 10 cm length Sarvak sandstone core sample at 46 degree C and at immiscible condition, i.e., below the minimum miscible pressure (MMP) of the oil sample using pure CO2 as injected Gas.The influence of injection WAG ratio on oil recovery also is investigated. Artificial injection brine which is made by dissolving NaCl into distilled water with 5000 ppm (mg/L), NaftShahr oil which has about 41 API gravity and... 

In past three decades, use of crude oil’s derivatives increased dramatically. The critical environmental condition of today’s world, which majorly caused by unclean fuels, forces governments to legislate new rules to increase quality of fuels. These rules force refinery industries to produce clean fuels. One of the main processes in producing clean fuels is Desulfurization process. For fuel desulfurization there are different kinds of processes like HydroDesulfruization, Oxidative Desulfurization, Bio-desulfurization, etc. From these processes Hydro-desulfurization is the conventional process for desulfurization. Because of significant problems of this process, like high operational cost,... 

The main EOR method after heat recovery is gas injection. Minimum miscibility pressure is one of the parameters that affect gas injection. This project includes computational and laboratory sections to estimate the MMP. The MMP were estimated during the injection of CO2, Ga, Gb and methane gases into two oil samples. In the computational part of the project, MMP is estimated through cell to cell simulation and using Peng_Robinson equation of state. Also, the MMP is measured by using slim tube apparatus which is used so widely in the industry. According to the results, CO2 has the lowest miscibility pressure among other gases. It was miscible into oil even at pressures near the bubble... 

Unconventional fracturing applications such as long-term waterflooding at fracturing pressure, produced water re-injection and waterfracs, etc., are characterized by very high fluid leakoff velocity, long operation time and significant changes in stress, pore pressure, and/or permeability and porosity, affecting possibly large regions around the wellbore and/or fracture. These special characteristics make fracturing modeling methods developed for conventional fracturing applications inadequate. Some of the problems encountered include grid effects resulting in oscillation of fracture growth with time (limiting the stability of conventional fracture modeling models), singularity of material... 

As many oil fields are reaching their final stage of production, new technologies are required in order to maintain production and increase recovery of hydrocarbons. Among these techniques of enhanced oil recovery (EOR), chemical injection method focuses on increasing the effectiveness of waterflooding. Due to the relatively high costs and considerable adsorption on the rock formations, this method is no longer used. In Recent years nanofluids (nanoparticles dispersed in brine) have been used as a cheap, efficient and environmentally friendly alternative more than any other chemicals. It has been stated that the Smart Water method and enhanced oil recovery by SiO2 nanoparticles are effective... 

Management decisions, Enhanced Oil Recovery, and reservoir development plans in petroleum industries are based on predictions by reservoir simulation. Due to uncertainties in model parameters or engineering assumptions, the simulation results are not accurate, while they are correct. One remedy is to match simulation results with engineering measurements, typically pressure and flow rate, by adjusting model parameters. In Reservoir Engineering literature, this is called History Matching and is an optimization problem. Common methods of history matching are based on finite difference simulation, and therefore have a very low speed. In addition, these methods usually ignore Geostatistical... 

By continuous decreasing the fossil fuel energy resources and increasing demand of such energies on the other hand with decreasing exploration of the new ones, production from these limited resources are in grate consideration. As a few percentages of the oil recovers by primary oil production and also remaining a lot of oil after water and gas injection in the secondary oil recovery process, causes that new methods to increase the oil recovery has been proposed. Water injection is a simple and common method in enhanced oil recovery process. Also water alternating gas injection and simultaneous water and gas injection causes considerable increase in oil recovery. Recently utilization of... 

The acid fracturing process is a thermal, hydraulic, mechanical, geochemical and geomechanical coupled phenomena in which the behavior of these variables are interrelated. To model the flow behavior of an acid into a fracture, mass and momentum balance equations are used to draw 3D velocity and pressure profiles. Part of the fluid diffuses or leaks off into the fracture walls and dissolves part of the fracture face.An acid balance equation is used to draw the concentration profile of the acid and to account for the quantity of rock dissolved. An algorithm is developed for this process to generate the final conductivity distribution after fracture closure. The objective of modeling acid... 

Natural gas power plant installed in power system as rapid start unit. In the recent decades, with increasing in the number of gas generating units in the world, consideration of natural gas transmission network in optimal solution of security-constrained unit commitment (SCUC) become a non-negligible problem. The gas transmission grid constraints integrated into the scheduling of thermal units in the proposed model for minimizes power system operating cost. In a power plant transmission of natural gas to power plant is very important because congestion in natural gas pipeline increases. This model could consider natural gas storage tank in gas transmission network as decision variable....