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The Role of Quantum Coherence and Geometry on the Excitonic Energy Transfer in Photosynthetic Structures
, M.Sc. Thesis Sharif University of Technology ; Karimipour, Vahid (Supervisor) ; Rezakhani, Ali (Supervisor)
Abstract
It has been of great interest to know whether quantum effects can play an essential role in the biological processes. Considering that quantum features, such as coherence and entanglement,can be harnessed to perform quantum information processing tasks, which are believed to be hard classically, the question is whether nature has also exploited these features in order to enhance the performance of biological systems. Although the presence of warm and wet environment around the biological systems results in the rapid destruction of quantum effects, recent experiments reported the existence of quantum coherence in light-harvesting complexes of some photosynthetic systems.This coherence lasts...
Geometry, supertransfer, and optimality in the light harvesting of purple bacteria
, Article Journal of Physical Chemistry Letters ; Volume 7, Issue 19 , 2016 , Pages 3804-3811 ; 19487185 (ISSN) ; Kassal, I ; Sharif University of Technology
American Chemical Society
2016
Abstract
The remarkable rotational symmetry of the photosynthetic antenna complexes of purple bacteria has long been thought to enhance their light harvesting and excitation energy transport. We study the role of symmetry by modeling hypothetical antennas whose symmetry is broken by altering the orientations of the bacteriochlorophyll pigments. We find that in both LH2 and LH1 complexes, symmetry increases energy transfer rates by enabling the cooperative, coherent process of supertransfer. The enhancement is particularly pronounced in the LH1 complex, whose natural geometry outperforms the average randomized geometry by 5.5 standard deviations, the most significant coherence-related enhancement...
Distinguishing the roles of energy funnelling and delocalization in photosynthetic light harvesting
, Article Physical Chemistry Chemical Physics ; Volume 18, Issue 10 , 2016 , Pages 7459-7467 ; 14639076 (ISSN) ; Kassal, I ; Sharif University of Technology
Royal Society of Chemistry
2016
Abstract
Photosynthetic complexes improve the transfer of excitation energy from peripheral antennas to reaction centers in several ways. In particular, a downward energy funnel can direct excitons in the right direction, while coherent excitonic delocalization can enhance transfer rates through the cooperative phenomenon of supertransfer. However, isolating the role of purely coherent effects is difficult because any change to the delocalization also changes the energy landscape. Here, we show that the relative importance of the two processes can be determined by comparing the natural light-harvesting apparatus with counterfactual models in which the delocalization and the energy landscape are...
Distillation of free entanglement from bound entangled states using weak measurements
, Article Physical Review A - Atomic, Molecular, and Optical Physics ; Volume 88, Issue 6 , 2013 ; ISSN: 10502947 ; Rezakhani, A. T ; Sharif University of Technology
2013
Abstract
We propose a scheme for distillation of free bipartite entanglement from bipartite bound entangled states. The crucial element of our scheme is an ancillary system that is coupled to the initial bound entangled state via appropriate weak measurements. We show that in this protocol free entanglement can be always generated with nonzero probability by using a single copy of the bound entangled state. We also derive a lower bound on the entanglement cost of the protocol and conclude that, on average, applying weaker measurements results in relatively higher values of free entanglement as well as lower costs
Temperature effects on quantum cloning of states and entanglement
, Article Physics Letters, Section A: General, Atomic and Solid State Physics ; Volume 373, Issue 8-9 , 2009 , Pages 821-825 ; 03759601 (ISSN) ; Rezakhani, A. T ; Sharif University of Technology
2009
Abstract
Performances of the symmetric universal and phase-covariant cloning transformations and entanglement cloners - qubit case - are investigated when the initial state of the hardware or the original state to be cloned is weakly coupled to a thermal environment. Different behaviors of each of these transformations are analyzed and contrasted with the ideal cases. © 2009 Elsevier B.V. All rights reserved
Preparation of Nanofluid by Using Hybrid Nanostructures and Investigation of Thermal and Rheological Properties and Using it in the Petroleum Fluids
, M.Sc. Thesis Sharif University of Technology ; Rashtchian , Davood (Supervisor) ; Rashidi, Alimorad (Supervisor) ; Lotfi, Roghayeh (Co-Advisor)
Abstract
In this study, thermal and rheological properties of nanofluids of water/carbon nanotubes, water/spherical silica nanoparticles and water/hybrid nanoparticles (hybrid of carbon nanotubes and spherical silica nanoparticles) have been investigated. To do so, carbon nanotubes have been synthesized by CCVD process and spherical silica nanoparticles and hybrid nanoparticles by wet chemical method. After synthesis of nanomaterials, nanofluids have been prepared by using SDBS as a dispersant with the concentration of 1.5 times of concentration of nanomaterials and then thermal conductivity, kinematic viscosity, dynamic viscosity and density of nanofluids have been investigated. As the results show,...
Modification of carbohydrate polymers via grafting in air. 1. Ceric-Induced synthesis of starch-g-polyacrylonitrile in presence and absence of oxygen [electronic resource]
, Article Starch - Starke ; Volume 54, Issue 3-4, pages 140–147, April 2002 ; Zohurian Mehr, Mohammad J
Abstract
Monomer grafting, a unique technique for polysaccharide modification, is always performed under inert (e.g., N2) atmosphere. This work is the first report related to evaluating the possibility and efficiency of the grafting of acrylonitrile (AN) onto starch in presence of oxygen. Thus, corn starch (in both granular and gelatinized states) as well as soluble starch were grafted by AN using a ceric-carbohydrate redox initiating system. Graft copolymerizations were performed under nitrogen, air, and oxygen atmospheres at similar conditions. Grafting occurrence was verified using chemical and spectral proofs. The polymerization mechanism and kinetics were investigated by recording the...
Modification of carbohydrate polymers via grafting in Air. 2. Ceric-Initiated graft copolymerization of acrylonitrile onto natural and modified polysaccharides [electronic resource]
, Article Starch - Stärke ; Volume 54, Issue 10, pages 482–488, October 2002 ; Zohuriaan-Mehr, Mohammad J
Abstract
Acrylonitrile (AN) was grafted onto various natural and modified polysaccharides (i.e., gum arabic, gum tragacanth, xanthan gum, sodium alginate, chitosan, sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose) by using ceric-carbohydrate redox initiating system. After overcoming practical problems, mainly from the high viscosity of the aqueous solutions of the different substrates, the graft copolymerization reactions were run either in air or in N2 atmosphere under similar conditions. Grafting was confirmed using chemical and spectral (FTIR) proofs. The reactions were kinetically investigated using semi-empirical expressions and time-temperature profiles. An anomalous...
Bound entanglement in quantum phase transitions
, Article Physical Review A - Atomic, Molecular, and Optical Physics ; Volume 81, Issue 4 , 2010 ; 10502947 (ISSN) ; Alipour, S ; Rezakhani, A. T ; Sharif University of Technology
2010
Abstract
We investigate quantum phase transitions in which a change in the type of entanglement from bound entanglement to either free entanglement or separability may occur. In particular, we present a theoretical method to construct a class of quantum spin-chain Hamiltonians that exhibit this type of quantum criticality. Given parameter-dependent two-site reduced density matrices (with prescribed entanglement properties), we lay out a reverse construction for a compatible pure state for the whole system, as well as a class of Hamiltonians for which this pure state is a ground state. This construction is illustrated through several examples
Modeling of in Plane Behavior of Retrofitted Adobe Walls with Finite Element Method under Cyclic Loading
, M.Sc. Thesis Sharif University of Technology ; Bakhshi, Ali (Supervisor) ; Ghannad, Mohammad Ali (Co-Advisor)
Abstract
Statistical studies indicate the fact that in Iran, like many other developing countries, a significant percentage of buildings are made of traditional materials and most of them are adobe buildings especially in rural areas. Furthermore, geological data indicates that Iran is located in alps-Himalayas seismic zone and exposed by destructive earthquakes and adobe buildings suffer the most damages comparing with other type of the structures. According to these explanations, this research deals with adobe buildings behavior and provides solutions for reinforcing them and improving the seismic response of these buildings. These studies include numerical modeling with finite elements methods by...
Silica chloride/wet SiO2 as a novel heterogeneous system for the deprotection of acetals under mild conditions [electronic resource]
, Article Phosphorus, Sulfur, and Silicon and the Related Elements ; Volume 178:2667-2670, Issue 12, 2003 ; Pourjavadi, Ali ; Zolfigol, Mohammad Ali ; Bamoniri, Abdolhamid
Abstract
A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition
Distributed Fault-tolerant Computation for Massive Data
, M.Sc. Thesis Sharif University of Technology ; Maddah-Ali, Mohammad Ali (Supervisor)
Abstract
In this thesis we consider the problem of distributed computation by many processors.We mainly concentrate on matrix multiplication problem in this thesis because of its importance. A distributed system consists of N worker processors and one master processor. The master processor should distribute the computation between workers and after computation in each of them, collect the results. In this thesis, we are going to mitigate the effect of straggler processors by using coding methods. Straggler processors can cause delays in the computation time.In this thesis, we firstly introduce a method to multiply any number of matrices in each other. The proposed method occurred in one shot without...
Incomplete Reduction of Iron Ore in a Fluidized Bed Reactor
, M.Sc. Thesis Sharif University of Technology ; Halali, Mohammad (Supervisor)
Abstract
The main goal of current investigation was partial reduction of Fe2O3 available in Hematite-rich ore to Magnetite by Fludization Bed method. The reductive gas, CO, was produced by incomplete combustion of Acetylene and Airmixed in inappropriate ratio. X-Ray Diffraction and X-Ray Florescence analyses were implemented in order to conducting qualitative analysis of present phases before and after reduction of the ore. Quantitative analysis of the same phases was also conducted by Titration. The latter analysis revealed the precise magnitude of available iron in each of the oxide containing phases. The chemical composition of the reactor gas was also determined before and after reduction...
Sequential Competitive Facility Location In Continuous Geometric Space
, M.Sc. Thesis Sharif University of Technology ; Abam, Mohammad Ali (Supervisor)
Abstract
Abstract The problem of competetive facility location can be defined as follows: There are a number of customers in the form of points in space, and two players arrange a number of facilities in the form of points in space, given some limitations, respectively. Each customer’s connection to each facility has a cost for the customer and an advantage for the facility, and each customer wants to be connected to at most one of the facilities which has the lowest cost for him. The goal is to find the strategy of placing the facilities and determining the cost which the facility receives from the customer, in such a way that the player’s profit is maximised.In this thesis, we first sought to...
Distributed Verifiable Computing: Algorithms and Analysis
, M.Sc. Thesis Sharif University of Technology ; Maddah Ali, Mohammad Ali (Supervisor)
Abstract
Zero knowledge proofs allow a person (prover) to convince another person (verifier) that he has performed a specific computation on a secret data correctly, and has obtained a true answer, without having to disclose the secret data. QAP (Quadratic Arithmetic Program) based zkSNARKs (zero knowledge Succinct Non-interactive Argument of Knowledge) are a type of zero knowledge proof. They have several properties that make them attractive in practice, e.g. verifier's work is very easy. So they are used in many areas such as Blockchain and cloud computing. But yet prover's work in QAP based zkSNARKs is heavy, therefore, it may not be possible for a prover with limited processing resource to run...
Privacy Preserving Communication Schemes for Light Clients in Blockchain Networks: Algorithms and Analysis
, M.Sc. Thesis Sharif University of Technology ; Pakravan, Mohammad Reza (Supervisor) ; Maddah Ali, Mohammad Ali (Co-Supervisor)
Abstract
Lightweight clients are a type of blockchain users who do not store all the blocks in the blockchain due to limited resources. These users store only a small part of each block and when needed, request transactions from full nodes that store the entire blockchain. These users have no role in block validation and only want to receive transactions related to their addresses with proof of the inclusion in the block from full nodes.Since light clients rely on full nodes for receiving transactions, their privacy against full nodes is important. The current implementation of Bitcoin uses Bloom filters for privacy, but this offers very little privacy to the users.In this thesis, we study the...
Investigating the rheological properties of nanofluids of water/hybrid nanostructure of spherical silica/MWCNT
, Article Thermochimica Acta ; Volume 578 , 20 February , 2014 , Pages 53-58 ; ISSN: 00406031 ; Rashidi, A ; Soleimanisalim, A. H ; Rashtchian, D ; Sharif University of Technology
2014
Abstract
Regarding the importance of rheological properties of water based drilling fluids, the effects of silica nanospheres, multiwall carbon nanotubes (MWCNTs) and two types of their hybrid, i.e. H1 (80 wt.% silica nanosphere/20 wt.% MWCNT) and H2 (50 wt.% silica nanosphere/50 wt.% MWCNT) on the viscosity and density of distilled water were investigated. According to the results, viscosity and density of the nanofluids increased with the concentration, while they were reduced by increasing the temperature. At high concentrations, the least increase in the viscosity of distilled water by adding the nanomaterials is related to H2 (8.2% increase at 1.0 wt.%). Likewise, the optimum operating...
The Effect of Soli-Structure Interaction on Dynamic Characteristics of Structures with Embedded Fondation
, M.Sc. Thesis Sharif University of Technology ; Ghannad, Mohammad Ali (Supervisor)
Abstract
Soil-structure interaction has significant effect on dynamic behavior of the super structure. This effect is usually investigated in two separate parts, i.e., the Kinematic Interaction effect and the Inertial Interaction effect. The first modifies the input ground motion to the foundation as a result of difference in soil and foundation stiffness. The later, i.e., the II effect, introduces the effect of soil flexibility and radiation of waves into the supporting medium on the response of the structure. These effects are usually considered by introducing a replacement oscillator with modified natural period and damping ratio subjected...
Perusing Metal Perusing Metal Insulator Transistors with in the Dynamical Field Approximation at Finite Temperature
, Ph.D. Dissertation Sharif University of Technology ; Vesaghi, Mohammad ALi (Supervisor)
Abstract
The aim of this work is to investigate some theoretical models developed in recent years for describing electronic correlation and apply them to some special problems and metallicity and insulating behavior of one type of paramagnetic systems. One of the vast‐applied and effective routines for investigating the strongly correlated electron systems is Dynamical Mean Field Theory (DMFT). In the first part, the equations of DMFT are solved on nearly real frequency axis with a effective and more reliable solver a little parameter γ above the real axis. This approach appears fine structures that can’t be captured with the ...
On a Bounded Budget Network Creation Game
, M.Sc. Thesis Sharif University of Technology ; Safari, Mohammad Ali (Supervisor)
Abstract
In this thesis, we consider a network creation game in which, each player (vertex) has a limited budget to establish links to other players. In our model, each link has a unit cost and each agent tries to minimize its cost which is its local diameter or its total distance to other players in the (undirected) underlying graph of the created network. Two variants of the game are studied: in the MAX version, the cost incurred to a vertex is the maximum distance between that vertex and other vertices, and in the SUM version, the cost incurred to a vertex is the sum of distances between that vertex and other vertices. We prove that in both versions pure Nash equilibria exist, but the problem of...