Sharif Digital Repository

Because of corrosion resistance and antibacterial effects, shape memory Ni-Ti-Ag alloy can be considered for different biomedical applications. Mechanical alloying is used to produce nanostructured Ni-Ti-Ag alloy from elemental powders. X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) are used to characterize the product. Results show that after 1h milling, homogenous distribution of the elements occurs; while no intermetallic compounds is observed. After 3h milling, titanium dissolves in nickel to form amorphous and nanostructured solid phases. Peaks of B2 phase appear in the XRD pattern after the 3h milling of the powder mixture. Sintering of the 3h-milled... 

In this research, copper matrix composites reinforced with different amounts of titanium carbide particles were produced by mechanical milling and in-situ formation of reinforcements. Morphology and size of milled powders were inspected by scanning electron microscopy (SEM) several times during milling process. Changes in lattice parameter, crystallite size, lattice strain, dislocation density and Gibbs free energy changes (due to increasing in dislocation densities and grain boundaries) in different samples (with different TiC particles contents) were studied by X-Ray Diffraction technique with Cu-kα radiation and using Nelson-Riley method and Williamson-Hall equation. Microstructure of... 

Let T be a partial Latin square and L a Latin square such that T ⊆ L.Then T is called a Latin trade, if there exists a partial Latin square T * such that T* ∩ T = ∅ and (LT) ∪ T* is a Latin square.We call T* a disjoint mate of T and the pair (T,T*) is called a Latin itrade.A Latin bitrade where empty rows and columns are ignored, is called a Κ-homogeneous Latin bitrade, if in each row and each column it contains exactly κ elements, and each element appears exactly k times.The number of filled cells in a Latin trade is referred to as its volume.Following the earlier work on κ-homogeneous Latin bitrades by Cavenagh, Donovan, and Drápal (2003 and 2004) Bean, Bidkhori, Khosravi, and... 

A μ-way Latin trade of volume s is a collection of μ partial Latin squares T1, T2,⋯, Tμ, containing exactly the same s filled cells, such that, if cell (i,j) is filled, it contains a different entry in each of the μ partial Latin squares, and such that row i in each of the μ partial Latin squares contains, set-wise, the same symbols, and column j likewise. It is called a μ-wayk-homogeneous Latin trade if, in each row and each column, Tr, for 1≤r≤μ, contains exactly k elements, and each element appears in Tr exactly k times. It is also denoted as a (μ,k,m) Latin trade, where m is the size of the partial Latin squares. We introduce some general constructions for μ-way k-homogeneous Latin... 

High strength TRIP-aided steel sheets with high formability and better ductility are of industrial interest. Texture control and retained austenite characterization are considered as the main factors with respect to the formability and ductility. Processing parameter such as initial conditions of hot rolling, cold rolling to final size of sheet, intercritical annealing after cold rolling and subsequent isothermal heat treatment to achieve TRIP specification in product, affect bulk texture of sheets. Moreover, chemical composition of steel should be noted especially because it can change the intensity of orientation and final macro texture of sheet. In this work, the effect of cold rolling... 

Optimization of high strength and high formability of multiphase cold rolled sheet TRIP-aided steels is based on the composition and the austempering conditions. The effect of intercritical annealing temperature on the volume fraction and carbon concentration of the retained austenite was investigated in two different TRIP-aided steels. Experimental results show that the optimum annealing temperatures are 860 °C for Al-containing and 810 °C for Si-containing TRIP steels. It was demonstrated that the measurement of retained austenite can be successfully performed for textured TRIP steels by XRD. © 2006 Elsevier Inc. All rights reserved  

Ab initio quantum chemical calculations at the density functional theory (DFT) level were performed on eight pyridine derivative molecules as corrosion inhibitors for iron in an acidic solution. In this regard, the geometry of the molecules were optimized using the B3LYP/6-31G method first, and then interactions of these optimized structures with the iron atom were explored using the B3LYP/LANL1MB method. Two modes of adsorption were considered, i.e., planar adsorption (P) via the pyridine ring and vertical adsorption (V) through a nitrogen atom. The interaction energy was minimized through the variation of the inhibitor molecule-iron atom distance. These minimum energy values, along with... 

The interaction energies of 3,5 di-methyl pyridine (A) and 2,4 di-methyl pyridine (B) on the (100) surface of body-centered cubic (bcc) iron were determined via a cluster model and ab initio quantum chemical calculations at density functional theory level. The obtained energies were used to compare the inhibition behavior of these molecules for iron corrosion in hydrochloric acid solution. The iron surface and its adsorption sites (on-top, bridge, hollow) were considered as some clusters taken from two-layered 〈100〉 planes, i.e. Fe1(1), Fe4(2,2), and Fe5(4,1). So, the process for which quantum chemical calculations was carried out consists of adsorption of molecule A (B) on these clusters.... 

In present paper the theory of the micropolar fluid based on a Cosserat continuum model has been applied for analysis of Couette flow and turbulent flow through rough pipes. The obtained results for the velocity field have been compared with known results from experiments done by Reichardt at Max Plank institute for fluids in Gottingen [1,2] and analytical solution of the problem from Gradient theory by alizadeh[3] for couette problem and with known results from experiments done by Nikuradse (1932).the boundary condition used here was the no slip one and Trostel's slip boundary condition[4].a good agreement between experimental results and the results of the problem for Reynolds near 18000... 

We show that a metal-organic framework (MOF) sustained by a nanosized Ag12 cuboctahedral node can be applied to selectively extract traces of lead(II) ion from environmental water samples. The MOF was characterized by thermogravimetric and differential thermal analysis, scanning electron microscopy, FTIR, and X-ray diffraction. The effects of pH value, flow rates, of type, concentration and volume of the eluent, of break-through volume and potentially interfering ions on the separation and determination of lead were evaluated. Following desorption with EDTA, Pb(II) was quantified by FAAS. The use of the MOF results in excellent analytical figures of merit including an analytical range from 2... 

Silver-based nanomaterials have attracted considerable attention due to their antimicrobial activities. In this work, a silver (Ag)-based metal organic framework (Ag-MOF) is embellished with graphene-oxide (GO), leading to the fabrication of a novel Ag-based nanocomposite (GO-Ag-MOF) whose biocidal activity is higher than those of Ag-MOF and GO nanomaterials. The nanocomposite is characterized using X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscope, Fourier transform infrared spectra, ultraviolet−visible absorption spectra, X-ray powder diffraction, dynamic light scattering, and nitrogen gas adsorption/desorption. The characterization shows that... 

Free Content Selective synthesis of conjugated enynes from α-arylalkynols using LiCl-Acidic Al2O3 under solvent-free conditions  

7H-benzimidazo[2,1-a]benz[de]isoquinolin-7-one compounds were prepared in a selective manner by reaction between o-phenylenediamines and appropriate 1,8-naphthalenedicarboxylic anhydrides using acidic alumina under microwave irradiation  

Shell and tube heat exchanger with single twisted tube bundle in five different twist angles, are studied using computational fluid dynamics (CFD) and compared to the conventional shell and tube heat exchanger with single segmental baffles. Effect of shell-side nozzles configurations on heat exchanger performance is studied as well. Heat transfer rate and pressure drop are the main issues investigated in the paper. The results show that, for the same shell-side flow rate, the heat transfer coefficient of heat exchanger with twisted tube bundle is lower than that of the heat exchanger with segmental baffles while shell-side pressure drop of the former is even much lower than that of the... 

An experimental investigation is conducted here to study the effects of applying frictional sliding fuses (FSF) in concrete infilled steel frames. Firstly, the influences of some parameters on the behavior of the sliding fuse are studied: Methods of adjusting the FSF for a certain sliding strength are explained and influences of time duration, welding and corrosion are investigated as well. Based on the results, time duration does not significantly affect the FSF, however influences of welding and corrosion of the constitutive plates are substantial. Then, the results of testing two 1/3 scale single-storey single-bay concrete infilled steel frames having FSF are presented. The specimens were... 

This article presents a new method for determination of meshing stiffness of the gear teeth using three dimensional analysis of tooth stiffness. The teeth are treated as explicit capacitive fields and their compliance matrix is determined by considering virtual interconnected springs located at defined nodes on tooth profile. The stiffness of any arbitrary point on the profile can then be determined as a linear function of neighboring nodes stiffness. The results of this analysis help in determination of load distribution for a pair of meshing gears under real operation conditions where deflections and misalignments are inevitable. Copyright © 2005 by ASME  

The molecular behavior of some benzimidazole (C7H 6N2) derivatives as corrosion inhibitors ojiron in hydrochloric acid (HCl) solution was investigated quantum electrochemically via the inhibitors' chemical potential (μ), molecular softness (σ), and the extent of charge transfer from the inhibitor to the metal (ΔN). These quantities were obtained from density functional theory (DFT) calculations for three models, i.e., isolated inhibitors (in vacua), inhibitors in solution, and, finally, inhibitors in electrical double layer (EDL). In these models, the effects of solvent, substrate, and electric field were considered using a polarized continuum model, iron Fe13(9,4) cluster, and a... 

This paper suggests a method, called distributed voting, to overcome the problem of the single point of failure in a TMR system used in robotics and industrial control applications. It uses time redundancy and is based on TMR with disagreement detector feature. This method masks faults occurring in the voter where the TMR system can continue its function properly. The method has been evaluated by injecting faults into Vertex2Pro and Vertex4 Xilinx FPGAs. An analytical evolution is also performed. The results of both evaluation approaches show that the proposed method can improve the reliability and the mean time to failure (MTTF) of a TMR system by at least a factor of (2-R v(t)) where Rv(t)... 

In present paper the theory of the micropolar fluid based on a Cosserat continuum model has been applied for analysis of Couette flow. The obtained results for the velocity field have been compared with known results from experiments done by Reichardt at Max Plank institute for fluids in Gottingen [1,2] and analytical solution of the problem from Gradient theory by alizadeh[3].the boundary condition used here was the no slip one and Trostel's slip boundary condition[4].a good agreement between experimental results and the results of the problem for Reynolds near 18000 has beeen found. A new dimensionless number introduced that indicates the theoretical relation between cosserat theory and... 

In present paper the theory of the micropolar fluid based on a Cosserat continuum model has been applied for analysis of Couette flow. The obtained results for the velocity field have been compared with known results from experiments done by Reichardt at Max Plank institute for fluids in Gottingen [1,2] and analytical solution of the problem from Gradient theory by alizadeh[3].the boundary condition used here was the no slip one and Trostel's slip boundary condition[4].a good agreement between experimental results and the results of the problem for Reynolds near 18000 has beeen found. A new dimensionless number introduced that indicates the theoretical relation between cosserat theory and...