Sharif Digital Repository

Hydrogen bond is a type of molecular bond which occurs between hydrogen and a highly electronegative atom (usually F, N and O) and results in special properties.Alkyl phosphonic acids and their derivatives have several applications as pesticides, antibiotics and anti-viruses. Furthermore, some chemicals in human nervous system hydrolyze to alkyl phosphonates and finally to methyl phosphonic acid. Linear alkyl phosphonic acids and their saults have both organic nonpolar hydrophobic groups and inorganic hydrophilic groups and used as surfactants.Different substituents can affect the acidity of alkyl phosphonic acids. Investigation have shown that hydroxyl functional group can increase the... 

A swarm robotic is made up of a number of similar robots (identical) that these robots alone do not have any potential, but they can with each other have considerable potential. In recent years, engineers have become more interested in swarm robotic. Swarm robotic allows the use of several colleague robots instead of an advanced robot that eliminates excessive complexity and expensive equipment. The purpose of this study is to provide a method for solving the crossing problem and interfering between robot swarms. In previous studies conducted at the Sharif University of Technology, the main goal was to design algorithms for the swarm behavior of a swarm robotic. In this research, the aim is... 

In this research, numerical simulation of the impact of a drop on a flat surface with oblique velocity has been performed, using two-phase model of Lattice Boltzmann Method (conservative phase-field). During impact, it is important to investigate two-dimensional drop dynamics and to evaluate the effectiveness of the numerical method used. The model used here restores conservative phase field and preserves mass both locally and globally. In addition, to calculate the slope of the phase field, it calls the center points without engaging finite difference calculations. This makes it efficient for running parallel computations. A fixed dry and hard surface is considered and the drop impacts it... 

In today's era, metal nanoparticles play an important role in technologies emerging from different sciences, such as chemistry, physics, optics, material science, due to their unique characteristics. In the development of nanooptics science, it can be said that metal nanoparticles play an important role. The ability of conductive electrons collective oscillation causes surface charge density fluctuations in nanoparticles, this phenomenon is known as surface plasmons. Surface plasmons are surprisingly coupled with light and cause the significant increase in the intensity of optical fields induced in nanoparticles. Therefore, with the presence of localized surface plasmons or plasmon... 

Understanding of the Molecules is the main purpose of the chemistry. Ab-initio molecular dynamics (AIMD) as a branch of the computational chemistry, tries to give us a deep comprehension of the molecule, and its chemical, physical and optical activities. This comprehension, relies on the accuracy of quantum mechanics, in addition to the speed of the classical mechanics. The mixing of the quantum mechanics and the classical mechanics could simulate activities of the atoms in the time-domain, provided the mixing is done with precaution. This, in turn, helps us to forecast the response of a molecule in different situations, and also translating the macroscopic phenomena in a nanoscopic... 

To date, the plasmonic properties of many metallic and semi-conducting materials have been investigated and used in various industries. One of the plasmonic material categories that have always been considered is polycyclic aromatic hydrocarbon or PAH, whose plasmonic resonance energy depends on the charge state of the molecule. In this regard, it is easy to change the plasmonic resonance energy via changing the induced charge, which is a unique feature of the mentioned materials. In addition, plasmonic structures with excitations in the infrared region are able to enhance the vibration intensity of absorbed molecules by increasing the electric field around themselves. Therefore, they have... 

Ultrafast signal processing in time-domain with high resolution and reconfigura-bility is a challenging task. This paper, for the first time, introduces a time-varying metasurface consisting of graphene microribbon array for implementing time-lens in the terahertz domain. Given that the surface conductivity of graphene is proportional to the Fermi energy level in the THz regime, it is possible to change the phase property of the incident electromagnetic pulse by changing the Fermi level while the Fermi level itself is a function of voltage. Upon this fact, a quadratic temporal phase modulator, namely time-lens has been realized. This phase modulation is applied to the impinging signal in the... 

In this research, the problem of locating fire stations and allocating equipment has been studied and a simulation-optimization approach has been presented to solve the problem. The mathematical models of this research were developed based on the idea of the randomness of the covered demand and the maximum expected coverage model. In these models, the issue of non-availability of equipment to cover accidents, the random nature of accidents, various fire incidents and the equipment needed to cover them are considered. Two mathematical models with deterministic and non-deterministic approach with different scenarios for demand are proposed. The non-deterministic model is developed with the aim... 

One of the main concerns of industrial companies’ managers is providing an efficient logistics system. To achieve an efficient logistics system, the fleet planning problem is studied by many researchers in recent years. This problem consists of multiple sub-problems at three levels: operational, tactical, and strategic. These sub-problems are closely related to each other and need to be studied and addressed in an integrated manner. In this research, an attempt is made to provide an integrated framework to solve the vehicle routing problem (operational), outsourcing problem (tactical), and fleet composition problem (strategic). These problems have various uncertainties, including customer...