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bakhshandeh--fatemeh
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ChemInform abstract: microwave-assisted rapid ketalization/acetalization of aromatic aldehydes and ketones in aqueous media [electronic resource]
, Article Journal of Chemical Research ; September 1999, Volume -, Number 9; Page(s) 562 to 563 ; Mirjalili, Bibi Fatemeh ; Sharif University of Technology
Abstract
Aromatic aldehydes and ketones are readily acetalized or ketalized under microwave irradiation in the presence of water as a solvent
Synthesis and characterization of poly(methacrylates) containing spiroacetal and norbornene moieties in side chain [electronic resource]
, Article Journal of Applied Polymer Science ; Volume 77, Issue 1, pages 30–38, 5 July 2000 ; Mirjalili, Bibi Fatemeh ; Sharif University of Technology
Abstract
A four-step synthetic strategy was applied to achieve novel methacrylic monomers. 5-Norbornene-2,2-dimethanol was prepared from a Diels–Alder reaction of cyclopentadiene and acrolein, followed by the treatment of the adduct with an HCHO/KOH/MeOH solution. The resulting 1,3-diol (1) was then acetalized with different aromatic aldehydes having OH groups on the ring to produce four spiroacetal derivatives. The reaction of methacryloyl chloride with the phenolic derivatives led to four new methacrylic monomers that were identified spectrochemically (mass, FTIR, 1H-NMR, and 13C-NMR spectroscopy). Free radical solution polymerization was used to prepare novel spiroacetal–norbornene containing...
Seismic Analysis of Multi-Degree Freedom Structures Equipped with Telescopic Metallic Yield Dampers (TLYD)
, M.Sc. Thesis Sharif University of Technology ; Eskandari, Morteza (Supervisor)
Abstract
Ordinary structures absorb a large amount of input energy by structural elements whereas failure in these elements causes a huge loss in structure and it’s really difficult to repair or unrepairable. Nowadays a wide range of metallic dampers is used in structures as fuse elements. this research evaluates the response of structures that are equipped with a novel steel damper named Telescopic Lead Yield Damper (TLYD) which was introduced by Eskandari in 2018. As TLYD has a different yielding plateau it can tolerate large deformations. In this research firstly this novel damper was introduced and the performance of the damper under cyclic loading was demonstrated. Then a numerical model of 6,...
Prediction of DNA/RNA Sequence Binding Site to Protein with the Ability to Implement on GPU
, M.Sc. Thesis Sharif University of Technology ; Koohi, Sommaye (Supervisor)
Abstract
Based on the importance of DNA/RNA binding proteins in different cellular processes, finding binding sites of them play crucial role in many applications, like designing drug/vaccine, designing protein, and cancer control. Many studies target this issue and try to improve the prediction accuracy with three strategies: complex neural-network structures, various types of inputs, and ML methods to extract input features. But due to the growing volume of sequences, these methods face serious processing challenges. So, this paper presents KDeep, based on CNN-LSTM and the primary form of DNA/RNA sequences as input. As the key feature improving the prediction accuracy, we propose a new encoding...
Cross-Lingual Speaker Adaptation for Statistical Parametric Speech Synthesis
, M.Sc. Thesis Sharif University of Technology ; Sameti, Hossein (Supervisor)
Abstract
Speech synthesis and its applications have been very attractive recently. The main purpose of this technique is to produce a speech signal with natural characteristics of human speech like prosody and emotion. Among all existing methods for speech synthesis, statistical parametric speech synthesis methods are more promising because ofhigher flexibility in comparison to other methods. One of the applications of speech synthesis is speech to speech translation. In these systems, the generated voice in target language should have the same characteristics as the input voice in source language. The main purpose of this research is to review and evaluate the cross lingual speaker adaptation...
Hydroelastic Analysis of Surface Piercing Propeller
, M.Sc. Thesis Sharif University of Technology ; Seif, Mohamad Saeed (Supervisor)
Abstract
Surface piercing propellers are particular type of supercavitating propellers that are commonly used for High-speed vessels. Most studies on this type of propellers has been investigating the hydrodynamic forces. But in recent years with increase in SPPs diameter used in vessels, structural analysis of this type of propellers is considered. For this purpose, studies on the stresses exerted on the propeller structures under load is done with the help of Hydro elastic methods. In this type of analysis, structura of propeller is intended to be flexible and Displacements under pressure checked and Tensions resulting from it are studied.
The present Thesis using ANSYS software to analyze a...
The present Thesis using ANSYS software to analyze a...
Design of Low-Power Zero Temperature Coefficient (ZTC) CMOS Oscillators
, M.Sc. Thesis Sharif University of Technology ; Akbar, Fatemeh (Supervisor)
Abstract
The increasing demand for autonomous vehicles and reliable communication protocols and hardware interfaces, such as CAN bus and USB, underscores the necessity for stable clock sources that maintain a low temperature coefficient (TC) over wide temperature ranges. This demand is particularly emphasized in applications such as wearables, network sensors, downhole devices, WSNs, and IoT, where long-lasting battery life and frequency-stable clock sources over a broad temperature range (e.g. -20 °C to 100 °C) are crucial. Traditionally, variations in frequency caused by temperature have been mitigated by employing off-chip components like crystals or ceramic based oscillators, but this approach...
Data-Driven Pricing Based on Demand Prediction Using Machine Learning Methods
, M.Sc. Thesis Sharif University of Technology ; Sedghi, Nafiseh (Supervisor)
Abstract
Pricing plays an important and essential role in the profit and income of companies. The importance of pricing is not only related to its role in the company's profitability, but it also changes the customer's understanding and loyalty towards the company and can create the company's reputation or destroy it. Determining the right price will increase product sales and increase customer loyalty and create a competitive advantage for the company. One of the most important and influential variables in product pricing is the amount of demand. The main challenge of companies for product pricing is the uncertainty in their demand. In order to deal with this problem, data-driven pricing is used....
Silica chloride/wet SiO2 as a novel heterogeneous system for the deprotection of acetals under mild conditions [electronic resource]
, Article Phosphorus, Sulfur, and Silicon and the Related Elements ; Volume 178:2667-2670, Issue 12, 2003 ; Pourjavadi, Ali ; Zolfigol, Mohammad Ali ; Bamoniri, Abdolhamid
Abstract
A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition
A Study on the Effect of Morphology and Sol-gel Process Parameters on Photocatalytic Properties of Tialite
, M.Sc. Thesis Sharif University of Technology ; Maddah Hosseini, Hamid Reza (Supervisor)
Abstract
Enhancement of photocatalytic characteristics of semiconductors have been always a challenge for the researchers. Doping semiconductors for adjusting their energy gap and changing their morphology in order to increase their effective surface area and reaction sites are examples of their endeavor to overcome the challenge. In this research, nanostructured Aluminum Titanate powder was synthesized with Sol-Gel process and by altering synthesis parameters, the best synthesis condition to get the best possible band gap was discovered. Moreover, we examined the photocatalytic properties of the recently developed material “tialite”, which were not studied before and also evaluated the effect...
Synthesis, single crystal, electrochemical and study of fluorogenic dibenzodiaza-crown-appended with bis(ZnTPP) azo-tweezer and spectroscopic elucidation of photo-induced macrocycle-deformation-based chromotropism
, Article Polyhedron ; Volume 227 , 2022 ; 02775387 (ISSN) ; Mahdavian, M ; Bakhshandeh, M ; Kubicki, M ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
In the present research, a new tweezer T bearing azobenzene linker 1 was prepared, characterized by applying FT-IR spectroscopy, fluorescence spectroscopy, UV–visible spectroscopy, and elemental analysis 1H and 13C{1H} NMR. T crystals were obtained by reaction of 1 with ZnTPP in CHCl3/acetone. Under irradiation with a mercury lamp to achieve the trans-to-cis isomerization, a dramatic color change from violet to green in chloroform was observed. The X-ray crystallography of T revealed an observable macroring deformation of the ZnTPP for the trans isomer. We observed a deviation of 0.11 Å from planarity for the least-squares plane of ZnTPP owing to the axial coordination by the pyridine...
Comparison of Lateral Dispersion in Flexible and Semi-Rigid Emergent Aquatic Canopies with Staggered, Random, and In-Line Arrangements
, M.Sc. Thesis Sharif University of Technology ; Jamali, Mirmosadegh (Supervisor)
Abstract
Hydrodynamics of flow is affected by physical and biological interactions between flow and aquatic vegetation. This study represents the role of array distribution on lateral dispersion in emergent aquatic vegetation using two flexible and semi-rigid models. Experiments were carried out with three different arrangements, including random, staggered, and in-line. The Reynolds numbers at the stem scale ranged from 120 to 690, and the stem densities were 1% and 1.44%. Furthermore, the effects of stem flexibility and, specifically, stem resonance on lateral dispersion were examined. An image processing technique was used to measure plume width and calculate lateral dispersion. It was found that...
A Comprehensive Review of Studies Conducted in Entrepreneurship Education in Order to Achieve a Codified Framework
, M.Sc. Thesis Sharif University of Technology ; Feyzbakhsh, Alireza (Supervisor)
Abstract
In the current situation and considering the economic conditions, entrepreneurship and self-employment are important factors of business growth. To prepare people in this field, there is a need for effective training that can motivate people. Identifying the effective methods and different dimensions of the entrepreneurship education framework that can lead to setting up a successful program for training people and facilitate the way to achieve the goal of education is one of the important goals of this research. By studying the literature from 2010 onwards, this research systematically examined 96 articles and tried to improve the framework of entrepreneurship education that was stated in...
Leaching kinetics of stibnite in sodium hydroxide solution
, Article International Journal of Engineering, Transactions B: Applications ; Volume 27, Issue 2 , February , 2014 , Pages 325-332 ; SSN: 10252495 ; Halali, M ; Hakim, M ; Bakhshandeh, M. R ; Sharif University of Technology
2014
Abstract
The leaching kinetics of stibnite in basic solution has been investigated. Spherical pellets of antimony sulphide were dissolved in 1 molar sodium hydroxide solutions at different temperatures. It was found that the shrinking core with ash layer model could satisfactorily explain the dissolution process. Using this model, it was found that initially the rate controlling step was a chemical reaction with activation energy of 10.2 kJ/mol. As the ash layer built up, diffusion through the ash layer became the rate controlling step. The activation energy for this step was found to be 33.4 kJ/mol. It was also observed that smaller particle size, larger solid to liquid ratio, and higher NaOH...
Design of a Novel Cable Driven Robotic System for Simulation of in vivo Loading of Cadaveric Lumbar Spine with Robustness-adaptive Controller for in vitro Spine Testing
, M.Sc. Thesis Sharif University of Technology ; Parnianpour, Mohammad (Supervisor) ; Arjmand, Navid (Supervisor)
Abstract
In this project we plan to propose a mechanism for controlling the profile of vertebra displacment and intera-discal pressure in in-vitro tests. Spineis the one of the most important members of the human musculoskeletal system. Health and stability of the spine help the people to moves on two legs. So any problems with this organ, causing movement problems and pain. For the treatment of spinal diseases, several methods such as surgery, insertion of implants and stabilizing were used. To ensure the accuracy of these methods, laboratory examination is essential. One of the ways to test these interventions, the implementation of in vitro tests on samples obtained from the bodies of the spine....
Oxidative Addition of Amines to Aldehydes Catalyzed by Supported Cobalt Nanoparticles on SBA-15
, M.Sc. Thesis Sharif University of Technology ; Saidi, Mohamad Reza (Supervisor) ; Rajabi, Fatemeh (Co-Advisor)
Abstract
Considering the widespread applications of amides, synthesis of these compounds is of great importance. The one pot oxidative addition of amines to aldehydes is one of the most simple and appealing approaches to synthesis amides. With the aim of developing a mild and convenient approach towards preparation of amides, numerous methods have been reported for this important process over the past few decades. These improvements have been mostly related to the optimization of reaction conditions and the use of more challenging substrates including diverse derivatives of aldehydes, and also design a novel and effective catalytic systems. Due to the various advantages of supported heterogeneous...
Evaluation of the Damage to Steel MRF Structures Under Near Field Earthquake Pulses Using a Performance-Based Design Approach
, M.Sc. Thesis Sharif University of Technology ; Rahimzadeh Rofooei, Fayaz (Supervisor)
Abstract
Research on the characteristics of the near field earthquakes has been very popular in recent years due to the considerable damages they have caused to the structures located within the vicinity of seismic sources. The incapability of response spectra for structural damage assessment has been revealed through recent investigations. The recorded data show that the near field earthquakes are often accompanied by a large energy pulse in the beginning of the records caused by the so-called directivity phenomenon. That has encouraged many researchers to study the possibility of using the velocity pulse of these records to evaluate the imposed seismic demands on structures. Thus, investigating the...
Optimization and characterization of tannic acid loaded niosomes for enhanced antibacterial and anti-biofilm activities
, Article Advanced Powder Technology ; 2020 ; Akbarzadeh, I ; Nourouzian, D ; Mirzaie, A ; Bakhshandeh, H ; Sharif University of Technology
Elsevier B.V
2020
Abstract
The purpose of this study was to prepare and characterize an optimized system of tannic acid-loaded niosomes as a potential carrier for antibacterial and anti-biofilm delivery. The niosomal formulation was optimized using response surface methodology (RSM). The effects of the molar ratio of surfactant to cholesterol, drug concentration, and molar ratio of Span 60 to Tween 60 on particle size and drug entrapment efficiency of the niosomal nanocarrier were studied. The optimized nanoparticles were characterized in terms of the morphology, in vitro release profile, and antibacterial properties. Moreover, Fourier-transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC)...
Are aluminium titanate-based nanostructures new photocatalytic materials? Possibilities and perspectives
, Article Journal of Photochemistry and Photobiology A: Chemistry ; Volume 353 , 2018 , Pages 316-324 ; 10106030 (ISSN) ; Azarniya, A ; Madaah Hosseini, H. R ; Jafari, S ; Sharif University of Technology
Elsevier B.V
2018
Abstract
Nanostructured aluminum titanate (AT) was synthesized by the sol-gel method. The calcination temperature was selected as a processing variable to obtain different phase ratios of AT and its parent phases i.e. TiO2 and Al2O3. The main aim behind the present work was to cast light on the photocatalytic performance of AT-based nanocomposites and evaluate their capability to serve as a novel photocatalyst. X-ray diffraction (XRD) analysis and field-emission scanning electron microscopy (FE-SEM) studies were conducted to evaluate the microstructure-sensitive properties of the synthesized powders. Diffuse reflectance spectroscopy (DRS) and the methylene blue degradation test were carried out to...
Novel azo-containing polymethacrylates bearing spiroacetal-norbornene moiety and methylene spacers: synthesis and characterization [electronic resource]
, Article European Polymer Journal ; Volume 37, Issue 10, October 2001, Pages 2111–2121 ; Mirjalili, Bibi Fatemeh ; Entezami, Ali A ; Zohuriaan-Mehr, Mohammad J ; Sharif University of Technology
Abstract
An eight-step synthetic strategy was followed to prepare a series of novel azobenzene-containing methacrylate monomers bearing spiroacetal-norbornene moiety and methylene spacers. Thus, the adduct 2, obtained from cyclopentadiene and acrolein, was converted to 1,3-diol 3. The diol was acetalized with nitrobenzaldehyde 4 under microwave irradiation to obtain nitro compound 5 that was then reduced to amino compound 6. Diazonium salt of 6 was coupled with phenol to produce phenolic compound 7 which was then reacted with n-dibromoalkanes (n=2, 4, 6, 8, 10) to yield bromo compounds 9a–e. Nucleophilic substitution reaction of the bromo compounds with lithium methacrylate produced the methacrylic...