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    Kinetic Modeling of Propane Dehydrogenation on Industrial Pt-Sn/γ-Al2O3 in Presence of Oxygenated Compounds

    , M.Sc. Thesis Sharif University of Technology Barghi, Bijan (Author) ; Khorasheh, Farhad (Supervisor)
    Abstract
    The study on the propane dehydrogenation process has been receiving significant attention due to the growing demand for propylene. The aim of this research is to develop an appropriate kinetic mechanism for dehydrogenation of propane over an industrial Pt–Sn/γ-Al2O3 catalyst in the presence of a very small amount of water. The reaction is carried out over the temperature range of 575 – 620 º C at atmospheric pressure. The results showed that a small amount of water and methanol can improve the performance of catalyst and also, increase the selectivity to COx. Addition the 0.5, 0.45, 0.3 water and 0.1, 0.05, 0.02 methanol are the optimum amount of these oxygenated compounds in order at... 

    Exact and Metaheuristic Solution for Multi-skilled Project Scheduling Problem with Regards to Set-up Time

    , M.Sc. Thesis Sharif University of Technology Barghi, Behrad (Author) ; Shadrokh, Shahram (Supervisor)
    Abstract
    Multi-mode resource-constrained project scheduling problem (MRCPSP) is considered one of the most complex and most frequently applied problems in the science field of project scheduling and the science of operations research, which recently a new version of it called multi-skilled project scheduling problem (MSPSP) has emerged in research studies. The purpose of this new problem is to schedule activities with respect to precedence relationships and resource constraints of the workforce types with multiple skills, such that the requirements of any activity for a subset of skills must be met by the qualified members of the project. In this study, in addition to observing the constraints and... 

    Qualitative and quantitative project risk assessment using a hybrid PMBOK model developed under uncertainty conditions

    , Article Heliyon ; Volume 6, Issue 1 , 2020 Barghi, B ; Shadrokh sikari, S ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    This study presented a qualitative and quantitative project risk assessment using a hybrid PMBOK model developed under uncertainty conditions. Accordingly, an exploratory and applied research design was employed in this study. The research sample included 15 experienced staff working in main and related positions in Neyr Perse Company. After reviewing the literature and the Project Management Body of Knowledge (PMBOK), 32 risk factors were identified and their number reduced to 17 risks using the expert opinions via the fuzzy Delphi technique run through three stages. The results of the confirmatory factor analysis showed that all risks were confirmed by the members of the research sample.... 

    Performance analysis and comparison of coded FH/MC-CDMA and MC-CDMA communication system

    , Article 18th Annual IEEE International Symposium on Personal, Indoor and Mobile Radio Communications, PIMRC'07, Athens, 3 September 2007 through 7 September 2007 ; December , 2007 ; 1424411440 (ISBN); 9781424411443 (ISBN) Barghi, S ; Nasiri Kenari, M ; Sharif University of Technology
    2007
    Abstract
    In this paper, we will combine the frequency hopping (FH) and the multi-carrier code division multiple access scheme (MC-CDMA) through an internal coding. The total bandwidth will be divided to a number of sub-bands with equal bandwidth. In each signalling interval, the output of a super orthogonal encoder selects one of the sub-bands for data transmission. Sub-carriers are modulated by a user specific PN sequence, and are transmitted over the selected sub-band similar to the MC-CDMA communications. We will derive the exact bit error rate of the MC-CDMA system and the new coded system. It will be shown by analysis and simulation that the proposed system performs much better than the MC-CDMA... 

    Meta-heuristic solution with considering setup time for multi-skilled project scheduling problem

    , Article Operations Research Forum ; Volume 3, Issue 1 , 2022 ; 26622556 (ISSN) Barghi, B ; Sikari, S. S ; Sharif University of Technology
    Springer International Publishing  2022
    Abstract
    The authors consider the Multi-Skilled Project Scheduling Problem (MSPSP) as a version of the Multi-mode Resource-Constrained Project Scheduling Problem (MRCPSP), which extends the well-known NP-hard Resource-Constrained Project Scheduling Problem (RCPSP). In the MSPSP, it is made up of activities, which require specific skills to be done. Moreover, resources are staff members who master fixed skill(s). Thus, each resource requirement of an activity corresponds to the number of persons doing the corresponding skill that must be assigned to the activity during its whole processing time. The authors focus on taking into account the setup times when performing work, depending on the appointment... 

    The modeling of kinetics and catalyst deactivation in propane dehydrogenation over Pt-Sn/γ-Al2O3 in presence of water as an oxygenated additive

    , Article Petroleum Science and Technology ; Vol. 32, issue. 10 , Mar , 2014 , pp. 1139-1149 ; ISSN: 10916466 Barghi, B ; Fattahi, M ; Khorasheh, F ; Sharif University of Technology
    2014
    Abstract
    A reduction in catalyst's activity with time-on-stream and the formation of side products are two of the problems associated with catalytic propane dehydrogenation (PDH). Previous studies have indicated that the presence of small amounts of oxygenated additives such as water can reduce coke formation and enhance catalyst activity. The aim of the present work was to develop an appropriate kinetic model for PDH over a commercial Pt-Sn/γ-Al 2O3 catalyst in the presence of small amounts of water. Experimental data were obtained from a previous study where catalytic PDH was carried out in a bench scale reactor system at atmospheric pressure in the temperature range of 575-620°C in the presence of... 

    Kinetic modeling of propane dehydrogenation over an industrial catalyst in the presence of oxygenated compounds

    , Article Reaction Kinetics, Mechanisms and Catalysis ; Volume 107, Issue 1 , 2012 , Pages 141-155 ; 18785190 (ISSN) Barghi, B ; Fattahi, M ; Khorasheh, F ; Sharif University of Technology
    Springer  2012
    Abstract
    The aim of this study was to develop an appropriate kinetic model for propane dehydrogenation (PDH) over an industrial Pt-Sn/γ-Al 2O 3 catalyst in the presence of small amounts of oxygenated compounds. Experimental data were obtained from a previous study where catalytic PDH was carried out in a laboratory scale reactor at atmospheric pressure in the temperature range of 575-620 °C in the presence of small amounts of water or methanol. The kinetics of the main dehydrogenation reaction was described and the effects of water and methanol on coke deposition and catalyst sintering were considered in a catalyst deactivation model to explain the observed optimum level in the amount of added... 

    An experimental study on permeability, diffusivity, and selectivity of CO2 and CH4 through [bmim][PF6] ionic liquid supported on an alumina membrane: Investigation of temperature fluctuations effects

    , Article Journal of Membrane Science ; Volume 362, Issue 1-2 , 2010 , Pages 346-352 ; 03767388 (ISSN) Barghi, S. H ; Adibi, M ; Rashtchian, D ; Sharif University of Technology
    2010
    Abstract
    In order to define a new temperature correction factor in this study, accurate experimental values were presented for permeability and diffusivity of carbon dioxide and methane in imidazolium-based room temperature ionic liquid: [bmim][PF6] (1-butyl-3-methylimidazolium hexafluorophosphate) immobilized on an inorganic membrane support. Results were presented as a function of temperature and pressure for temperatures within 300-320K and pressures below 50kPa. According to the literature, experimental values of permeability and diffusivity for CH4 in [bmim][PF6] vs. temperature are reported for the first time in this study. Results obtained for CO2 permeability revealed good agreement with data... 

    Microwave-induced Cannizzaro reaction over neutral γ-alumina as a polymeric catalyst [electronic resource]

    , Article Reactive and Functional Polymers ; 01/2002; 51(1):49-53 Pourjavadi, A. (Ali) ; Soleimanzadeh, B ; Marandi, G. B
    Abstract
    γ-Alumina is used to catalyze the Cannizzaro reaction in the absence of any base under microwave irradiation in high yields. In the case of terephthalaldehyde the reaction is carried out with high selectivity  

    SnCl4/SiO2: an efficient heterogeneous alternative for one-pot synthesis of β-acetamidoketones

    , Article Journal of the Chinese Chemical Society ; Volume 56, Issue 2 , 2009 , Pages 386-391 ; 00094536 (ISSN) Mirjalili, B. B. F ; Mahmoodi Hashemi, M ; Sadeghi, B ; Emtiazi, H ; Sharif University of Technology
    2009
    Abstract
    Enolizable ketones have been reacted in a one-pot method with aromatic aldehydes, acetyl chloride and acetonitrile at room temperature in the presence of SnCl4/SiO2 to furnish the corresponding β-acetamidoketones in improved yields. Acetylation of an aromatic hydroxyl group was observed while using 4-hydroxybenzaldehyde or vanillin and the corresponding β-acetamidoketones were isolated in an excellent yield  

    Turbulent flow in converging nozzles, part one: Boundary layer solution

    , Article Applied Mathematics and Mechanics (English Edition) ; Volume 32, Issue 5 , 2011 , Pages 645-662 ; 02534827 (ISSN) Maddahian, R ; Farhanieh, B ; Firoozabadi, B ; Sharif University of Technology
    2011
    Abstract
    The boundary layer integral method is used to investigate the development of the turbulent swirling flow at the entrance region of a conical nozzle. The governing equations in the spherical coordinate system are simplified with the boundary layer assumptions and integrated through the boundary layer. The resulting sets of differential equations are then solved by the fourth-order Adams predictor-corrector method. The free vortex and uniform velocity profiles are applied for the tangential and axial velocities at the inlet region, respectively. Due to the lack of experimental data for swirling flows in converging nozzles, the developed model is validated against the numerical simulations. The... 

    Numerical investigation of steady density currents flowing down an incline using v2̄ - F turbulence model

    , Article Journal of Fluids Engineering, Transactions of the ASME ; Volume 129, Issue 9 , 2007 , Pages 1172-1178 ; 00982202 (ISSN) Khakzad, N ; Firoozabadi, B ; Farhanieh, B ; Sharif University of Technology
    2007
    Abstract
    The governing equations of two-dimensional steady density currents are solved numerically using a finite volume method. The v2̄-f turbulence model, based on standard k - s model, is used for the turbulence closure. In this method, all Reynolds stress equations are replaced with both a transport equation for v2̄ and an elliptic relaxation equation for f, a parameter closely related to the pressure strain redistribution term. The Simple-C procedure is used for pressure-velocity coupling. In addition, Boussinesq's approximation is used to obtain the momentum equation. The computed height of the progressive density current is compared to the measured data in the literature, resulting in good... 

    Numerical simulation of turbid-density current using v2̄ - f turbulence model

    , Article 2005 ASME International Mechanical Engineering Congress and Exposition, IMECE 2005, Orlando, FL, 5 November 2005 through 11 November 2005 ; Volume 261 FED , 2005 , Pages 619-627 ; 08888116 (ISSN); 0791842193 (ISBN); 9780791842195 (ISBN) Mehdizadeh, A ; Firoozabadi, B ; Farhanieh, B ; Sharif University of Technology
    2005
    Abstract
    The deposition behavior of fine sediment is an important phenomenon, and yet unclear to engineers concerned about reservoir sedimentation. An elliptic relaxation turbulence model (v2̄ - f model) has been used to simulate the motion of turbid density currents laden whit fine solid particles. During the last few years, the v2̄ - f turbulence model has become increasingly popular due to its ability to account for near-wall damping without use of damping functions. In addition, it has been proved that the v2̄ - f model to be superior to other RANS methods in many fluid flows where complex flow features are present. Due to low Reynolds number turbulence of turbidity current,(its critical Reynolds... 

    Analytical solution for creeping motion of a viscoelastic drop falling through a Newtonian fluid

    , Article Korea Australia Rheology Journal ; Vol. 26, issue. 1 , 2014 , pp. 91-104 ; ISSN: 1226119X Vamerzani, B. Z ; Norouzi, M ; Firoozabadi, B ; Sharif University of Technology
    2014
    Abstract
    In this paper, an analytical solution for steady creeping motion of viscoelastic drop falling through a viscous Newtonian fluid is presented. The Oldroyd-B model is used as the constitutive equation. The analytical solutions for both interior and exterior flows are obtained using the perturbation method. Deborah number and capillary numbers are considered as the perturbation parameters. The effect of viscoelastic properties on drop shape and motion are studied in detail. The previous empirical studies indicated that unlike the Newtonian creeping drop in which the drop shape is exactly spherical, a dimpled shape appears in viscoelastic drops. It is shown that the results of the present... 

    Theoretical and experimental study on the motion and shape of viscoelastic falling drops through Newtonian media

    , Article Rheologica Acta ; Volume 55, Issue 11-12 , 2016 , Pages 935-955 ; 00354511 (ISSN) Vamerzani, B. Z ; Norouzi, M ; Firoozabadi, B ; Sharif University of Technology
    Springer Verlag  2016
    Abstract
    In this paper, creeping motion of a viscoelastic drop falling through a Newtonian fluid is investigated experimentally and analytically. A polymeric solution of 0.08 % xanthan gum in 80:20 glycerol/water and silicon oil is implemented as the viscoelastic drop and the bulk viscous fluids, respectively. The shape and motion of falling drops are visualized using a high speed camera. The perturbation technique is employed for both interior and exterior flows, and Deborah and capillary numbers are considered as perturbation parameters up to second order. The product of Deborah and capillary numbers is also used as a perturbation parameter to apply the boundary condition on the deformation on the... 

    Minimizing uplink delay in delay-sensitive 5G CRAN platforms

    , Article 2nd IEEE 5G World Forum, 5GWF 2019, 30 September 2019 through 2 October 2019 ; 2019 , Pages 154-160 ; 9781728136271 (ISBN) Ataie, A ; Kanaanian, B ; Khalaj, B. H ; Sharif University of Technology
    Institute of Electrical and Electronics Engineers Inc  2019
    Abstract
    In this paper, we consider the problem of minimizing the uplink delays of users in a 5G cellular network. Such cellular network is based on a Cloud Radio Access Network (CRAN) architecture with limited fronthaul capacity, where our goal is to minimize delays of all users through an optimal resource allocation. Earlier works minimize average delay of each user assuming same transmit power for all users. Combining Pareto optimization and Markov Decision Process (MDP), we show that every desired balance in the trade-off among infinite-horizon average-reward delays, is achievable by minimizing a properly weighted sum delays. In addition, we solve the problem in two realistic scenarios;... 

    Microwave-induced Cannizzaro reaction over neutral γ-alumina as a polymeric catalyst

    , Article Reactive and Functional Polymers ; Volume 51, Issue 1 , 2002 , Pages 49-53 ; 13815148 (ISSN) Pourjavadi, A ; Soleimanzadeh, B ; Marandi, G. B ; Sharif University of Technology
    2002
    Abstract
    Microwave induced Cannizzaro reaction, which was performed in presence of neutral γ-alumina as a polymeric catalyst, was discussed. Cannizzaro reaction was carried out on alumina surface and other unknown products were also obtained. Solvent extraction method was utilized to isolate mild and selective benzyl alcohol and carboxylic acids  

    Feedback bit reduction for antenna selection methods in wireless systems

    , Article 2005 13th IEEE International Conference on Networks jointly held with the 2005 7th IEEE Malaysia International Conference on Communications, Kuala Lumpur, 16 November 2005 through 18 November 2005 ; Volume 1 , 2005 , Pages 229-233 ; 1424400007 (ISBN); 9781424400003 (ISBN) Shariatpanahi, P ; Babadi, B ; Hossein Khalaj, B ; Sharif University of Technology
    2005
    Abstract
    A well known method to reduce the intrinsic complexity of Multiple Input Multiple Output (MIMO) systems is to choose a subset of available antennas which have stronger links than the others, in order to perform the specified MIMO algorithm. The data resulted from the antenna selection process (at the receiver side) is sent back to the transmitter side via a feedback channel. There seems to be a need to reduce the number of feedack bits, specially when the number of antennas is not small. In this paper, we investigate the problem of reducing the number of feedback bits in antenna selection techniques. We've proposed two methods using vector quantization techniques to perform feedback bit... 

    A distributed locality-aware neighbor selection algorithm for P2P video streaming over wireless mesh networks

    , Article 2012 6th International Symposium on Telecommunications, IST 2012 ; 2012 , Pages 639-643 ; 9781467320733 (ISBN) Moayeri, F ; Akbari, B ; Khansari, M ; Ahmadifar, B ; Sharif University of Technology
    2012
    Abstract
    Nowadays, deployment of peer-to-peer video streaming systems over wireless mesh networks has attained raising popularity among large number of users around the world. In this paper, we present an efficient peer-to-peer live video streaming architecture over multi-hop wireless mesh networks. In our proposed architecture, we take the physical topology of network into account and based on a distributed distributed locality-aware neighbor selection algorithm in the overlay construction phase, we generate an efficient mesh-based overlay on top of wireless mesh networks. In locality-aware neighbor selection algorithm, instead of choosing randomly, peers find their best neighbors based on their... 

    Weighted sparse signal decomposition

    , Article ICASSP, IEEE International Conference on Acoustics, Speech and Signal Processing - Proceedings ; 2012 , Pages 3425-3428 ; 15206149 (ISSN) ; 9781467300469 (ISBN) Babaie Zadeh, M ; Mehrdad, B ; Giannakis, G. B ; Sharif University of Technology
    IEEE  2012
    Abstract
    Standard sparse decomposition (with applications in many different areas including compressive sampling) amounts to finding the minimum ℓ 0-norm solution of an underdetermined system of linear equations. In this decomposition, all atoms are treated 'uniformly' for being included or not in the decomposition. However, one may wish to weigh more or less certain atoms, or, assign higher costs to some other atoms to be included in the decomposition. This can happen for example when there is prior information available on each atom. This motivates generalizing the notion of minimal ℓ 0-norm solution to that of minimal weighted ℓ 0-norm solution. On the other hand, relaxing weighted ℓ 0-norm via...