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Kinetic Modeling of Propane Dehydrogenation on Industrial Pt-Sn/γ-Al2O3 in Presence of Oxygenated Compounds
, M.Sc. Thesis Sharif University of Technology ; Khorasheh, Farhad (Supervisor)
Abstract
The study on the propane dehydrogenation process has been receiving significant attention due to the growing demand for propylene. The aim of this research is to develop an appropriate kinetic mechanism for dehydrogenation of propane over an industrial Pt–Sn/γ-Al2O3 catalyst in the presence of a very small amount of water. The reaction is carried out over the temperature range of 575 – 620 º C at atmospheric pressure. The results showed that a small amount of water and methanol can improve the performance of catalyst and also, increase the selectivity to COx. Addition the 0.5, 0.45, 0.3 water and 0.1, 0.05, 0.02 methanol are the optimum amount of these oxygenated compounds in order at...
Exact and Metaheuristic Solution for Multi-skilled Project Scheduling Problem with Regards to Set-up Time
, M.Sc. Thesis Sharif University of Technology ; Shadrokh, Shahram (Supervisor)
Abstract
Multi-mode resource-constrained project scheduling problem (MRCPSP) is considered one of the most complex and most frequently applied problems in the science field of project scheduling and the science of operations research, which recently a new version of it called multi-skilled project scheduling problem (MSPSP) has emerged in research studies. The purpose of this new problem is to schedule activities with respect to precedence relationships and resource constraints of the workforce types with multiple skills, such that the requirements of any activity for a subset of skills must be met by the qualified members of the project. In this study, in addition to observing the constraints and...
Qualitative and quantitative project risk assessment using a hybrid PMBOK model developed under uncertainty conditions
, Article Heliyon ; Volume 6, Issue 1 , 2020 ; Shadrokh sikari, S ; Sharif University of Technology
Elsevier Ltd
2020
Abstract
This study presented a qualitative and quantitative project risk assessment using a hybrid PMBOK model developed under uncertainty conditions. Accordingly, an exploratory and applied research design was employed in this study. The research sample included 15 experienced staff working in main and related positions in Neyr Perse Company. After reviewing the literature and the Project Management Body of Knowledge (PMBOK), 32 risk factors were identified and their number reduced to 17 risks using the expert opinions via the fuzzy Delphi technique run through three stages. The results of the confirmatory factor analysis showed that all risks were confirmed by the members of the research sample....
Performance analysis and comparison of coded FH/MC-CDMA and MC-CDMA communication system
, Article 18th Annual IEEE International Symposium on Personal, Indoor and Mobile Radio Communications, PIMRC'07, Athens, 3 September 2007 through 7 September 2007 ; December , 2007 ; 1424411440 (ISBN); 9781424411443 (ISBN) ; Nasiri Kenari, M ; Sharif University of Technology
2007
Abstract
In this paper, we will combine the frequency hopping (FH) and the multi-carrier code division multiple access scheme (MC-CDMA) through an internal coding. The total bandwidth will be divided to a number of sub-bands with equal bandwidth. In each signalling interval, the output of a super orthogonal encoder selects one of the sub-bands for data transmission. Sub-carriers are modulated by a user specific PN sequence, and are transmitted over the selected sub-band similar to the MC-CDMA communications. We will derive the exact bit error rate of the MC-CDMA system and the new coded system. It will be shown by analysis and simulation that the proposed system performs much better than the MC-CDMA...
Meta-heuristic solution with considering setup time for multi-skilled project scheduling problem
, Article Operations Research Forum ; Volume 3, Issue 1 , 2022 ; 26622556 (ISSN) ; Sikari, S. S ; Sharif University of Technology
Springer International Publishing
2022
Abstract
The authors consider the Multi-Skilled Project Scheduling Problem (MSPSP) as a version of the Multi-mode Resource-Constrained Project Scheduling Problem (MRCPSP), which extends the well-known NP-hard Resource-Constrained Project Scheduling Problem (RCPSP). In the MSPSP, it is made up of activities, which require specific skills to be done. Moreover, resources are staff members who master fixed skill(s). Thus, each resource requirement of an activity corresponds to the number of persons doing the corresponding skill that must be assigned to the activity during its whole processing time. The authors focus on taking into account the setup times when performing work, depending on the appointment...
The modeling of kinetics and catalyst deactivation in propane dehydrogenation over Pt-Sn/γ-Al2O3 in presence of water as an oxygenated additive
, Article Petroleum Science and Technology ; Vol. 32, issue. 10 , Mar , 2014 , pp. 1139-1149 ; ISSN: 10916466 ; Fattahi, M ; Khorasheh, F ; Sharif University of Technology
2014
Abstract
A reduction in catalyst's activity with time-on-stream and the formation of side products are two of the problems associated with catalytic propane dehydrogenation (PDH). Previous studies have indicated that the presence of small amounts of oxygenated additives such as water can reduce coke formation and enhance catalyst activity. The aim of the present work was to develop an appropriate kinetic model for PDH over a commercial Pt-Sn/γ-Al 2O3 catalyst in the presence of small amounts of water. Experimental data were obtained from a previous study where catalytic PDH was carried out in a bench scale reactor system at atmospheric pressure in the temperature range of 575-620°C in the presence of...
Kinetic modeling of propane dehydrogenation over an industrial catalyst in the presence of oxygenated compounds
, Article Reaction Kinetics, Mechanisms and Catalysis ; Volume 107, Issue 1 , 2012 , Pages 141-155 ; 18785190 (ISSN) ; Fattahi, M ; Khorasheh, F ; Sharif University of Technology
Springer
2012
Abstract
The aim of this study was to develop an appropriate kinetic model for propane dehydrogenation (PDH) over an industrial Pt-Sn/γ-Al 2O 3 catalyst in the presence of small amounts of oxygenated compounds. Experimental data were obtained from a previous study where catalytic PDH was carried out in a laboratory scale reactor at atmospheric pressure in the temperature range of 575-620 °C in the presence of small amounts of water or methanol. The kinetics of the main dehydrogenation reaction was described and the effects of water and methanol on coke deposition and catalyst sintering were considered in a catalyst deactivation model to explain the observed optimum level in the amount of added...
An experimental study on permeability, diffusivity, and selectivity of CO2 and CH4 through [bmim][PF6] ionic liquid supported on an alumina membrane: Investigation of temperature fluctuations effects
, Article Journal of Membrane Science ; Volume 362, Issue 1-2 , 2010 , Pages 346-352 ; 03767388 (ISSN) ; Adibi, M ; Rashtchian, D ; Sharif University of Technology
2010
Abstract
In order to define a new temperature correction factor in this study, accurate experimental values were presented for permeability and diffusivity of carbon dioxide and methane in imidazolium-based room temperature ionic liquid: [bmim][PF6] (1-butyl-3-methylimidazolium hexafluorophosphate) immobilized on an inorganic membrane support. Results were presented as a function of temperature and pressure for temperatures within 300-320K and pressures below 50kPa. According to the literature, experimental values of permeability and diffusivity for CH4 in [bmim][PF6] vs. temperature are reported for the first time in this study. Results obtained for CO2 permeability revealed good agreement with data...
Design of a Fault Tolerant SPARC Based Micro Processor On FPGA
, M.Sc. Thesis Sharif University of Technology ; Rashidian, Bijan (Supervisor) ; Vosoughi Vahdat, Bijan (Supervisor)
Abstract
In this thesis, LEON Processor was chosen for its compatible architecture that can be implemented on a wide range of FPGAs. The final designed processor is aimed to conquer soft and hard errors that occur due to cosmic radiations in SRAM cells of an FPGA. The system can finally resist all single SEUs that happen in flip flops and all 4 random errors that take place in each register of the register file. All the flip flops and latches are protected using a TMR scheme. The information redundancy in the regiester file to overcome all 4 random errors is 168% and the errors are corrected by means of a mechanesim that is masked from the processor core. In cache memory, each 32 bit data is...
Design of a Fault Tolerant ARM-Based Processor on FPGA
, M.Sc. Thesis Sharif University of Technology ; Rashidian, Bijan (Supervisor) ; Vosughi Vahdat, Bijan (Supervisor)
Abstract
The charged particles in space strike the silicon surface of an embedded system in a satellite and cause fault occurrence in its operation. So some methods should be employed to reduce the effects of the faults. The methods that are implemented in system level are widely used because of their low cost and high reliability. The processors are responsible for performing main processes in embedded systems. On the other hand, the ARM processors are good choices for utilizing in satellites because of their low size, low power consumption and high performance. Also, FPGAs have made a major improvement in embedded system design. So with implementing ...
Low Grade Heat Driven Multi-Effect Distillation and Desalination
, Book ; Chua, Hui Tong
Elsevier
2017
Abstract
Low Grade Heat Driven Multi-effect Distillation and Desalination describes the development of advanced multi-effect evaporation technologies that are driven by low grade sensible heat, including process waste heat in refineries, heat rejection from diesel generators or microturbines, and solar and geothermal energy. The technologies discussed can be applied to desalination in remote areas, purifying produced water in oil-and-gas industries, and to re-concentrate process liquor in refineries.
This book is ideal for researchers, engineering scientists, graduate students, and industrial practitioners working in the desalination, petrochemical, and mineral refining sectors, helping them...
This book is ideal for researchers, engineering scientists, graduate students, and industrial practitioners working in the desalination, petrochemical, and mineral refining sectors, helping them...
Numerical Investigation of Two-Phase Flow Contains Water and Oil in Hydrocyclones
, M.Sc. Thesis Sharif University of Technology ; Farhanieh, Bijan (Supervisor)
Abstract
Having an efficient and reliable system for oil-water separation is of crucial importance in oil and gas industry. Hydrocyclones have been used for more than a century to separate oil from water as well as sand from liquid or gas. The main objectives of this research are as follows: Determination the hydrocyclone principle of operation, based on computational fluid dynamic simulations. Hydrocyclones, in a spite of simple structure, are widely used in industry such as Petrochemical, Mining, Chemical Industries, Pharmacy, Food and Pulp Industries. The CALC BFC is one phase flow numerical code based on finite volume method and SIMPLEC algorithm. It was extended for simulating the two phase flow...
Deposition and Analysis of Indium-Tin-Oxide NanoStructures Using Sputtering
, M.Sc. Thesis Sharif University of Technology ; Rashidian, Bijan (Supervisor)
Abstract
Transparent conductive materials have been widely used in semiconductor technology. Among them all, Indium tin oxide (ITO) has been utilized as electrodes in liquid crystal displays, solar cells, heat reflecting films and gas sensors.In general, the desired properties of transparent conductive oxides are high conductance and transmission. However, due to the complexity of ITO molecular structure, the film properties strongly depend on the depositon parameters.In first part of this thesis, physical properties and electrical characteristic of ITO films, different deposition techniques, and effects of deposition parameters (substrate temperature, pressure, power, etc. ) on film properties are...
Fabrication of Metallic Nano-Tip Field Emitters and Measurement
, M.Sc. Thesis Sharif University of Technology ; Rashidian, Bijan (Supervisor)
Abstract
The need for integration of electron guns together with thermal considerations of thermionic cathodes has led to design new cold cathode guns based on field emission phenomenon. In first part of this thesis, basic field emission theories, fabrication methods of field emitter arrays, effect of different parameters on the field emission properties of field emitter arrays and applications of these arrays are investigated. After setting up fabrication methods of nano-tip field emitters, in the second part of thesis, Si nano-tips and Si field emitter arrays are fabricated using of thermal oxidation of silicon substrate, lithography, and chemical etching of silicon oxide and silicon substrate. Si...
, M.Sc. Thesis Sharif University of Technology ; Farhanieh, Bijan (Supervisor)
Abstract
Centrifugal Fans are widely used in industrial and commercial applications, from shop ventilation to material handling to boiler applications. They consume extremely high amount of energy each year. Because of this high consumption, even a small efficiency improvement could led to high amount of energy saving. Many projects have been done with this goal up to now, and present work is one of them, with aim to optimize a industrial centrifugal BI fan performance, with wheel diameter about 400 mm. The research has been done based on 3D numerical methods, done by commercial code Fluent 6.3, in steady state. MRF and k-E models have been used to simulate flow around blades, and turbulence...
, M.Sc. Thesis Sharif University of Technology ; Farhanieh, Bijan (Supervisor)
Abstract
Development of cities as well as population growth causes to development of public transportation especially subway lines. Fire is the one of the most important issues that may occur in subways. The difference in flame size, emission heat, smoke and pollutants generation of subway fires attracts an especial attention of fire investigators. The emergency ventilation of subways in the case of fire should have the ability of discharging heat, smoke and pollutants from passenger escape route and preparing a safe place for a specific duration. The aim of this research is simulating fire in subway stations and defining proper regional fire scenarios to prepare a safe route for passengers escape....
Numerical Investigation of Turbulent Flow Inside De-Oiling Hydrocyclones Using Large Eddy Simulation Approach
, M.Sc. Thesis Sharif University of Technology ; Farhanieh, Bijan (Supervisor)
Abstract
Hydrocyclones are used for separating different materials from liquids in a variety of applications. Compactness, efficiency, reliability and low maintenance costs are their noteworthy characteristics. Dewatering and deoiling hydrocyclones used for refining crude oil or oily waste water in offshore platforms are examples of liquid-liquid hydrocyclones. Separation process in hydrocyclones is based on the fact that swirl flow induces a centrifugal force and leads to separation due to density difference. The density difference in liquid-liquid mixtures is smaller than solid-liquid types and trying to separate one liquid from another takes much more effort than the other type. Increase of...
Numerical Simulating of a Railcar fire in Tunnel
, M.Sc. Thesis Sharif University of Technology ; Farhanieh, Bijan (Supervisor)
Abstract
Fire phenomenon and its hazards through urbun transportation systems like subway is a major debate in management of these territories. Recently, varios factors, such as great deal of passengers whom travel by these systems, financial damages and psychological disorders due to fire accidents resulte in noticeable investigation to prevent and reduce these subjects. In this research, simulating of railcar fire has been conducted to estimate the amount of heat release rate (HRR) and parameters which affect on it by modelling behavior of combustible materials inside railcar. As regards to materials which are available inside railcar that participate in fire, their behavior face to heat flux has...
Simulation of Fire in Tunnels Using Fire Dynamics Simulator Code (FDS)
, M.Sc. Thesis Sharif University of Technology ; Farhanieh, Bijan (Supervisor)
Abstract
Designing of an efficient emergency ventilation system is one of the main approaches to prevent the perilous fire in tunnel phenomenon. For this purpose, firstly, fire behavior and its heat release rate should be investigated. Knowing about temperature distribution and smoke movement is the second step. One of the most considerable factors in smoke control is critical velocity. It means the minimum velocity to prevent backlayering flow. If longitudinal ventilation velocity were less than this amount, smoke and hot gases originated from the fire can enter the upstream zone. This may cause lack of oxygen and decrease visibility for the passengers when they are escaping from the fire field. In...
Simulation of New Methods in Ventilation of Underground Station Sand Tunnels
, M.Sc. Thesis Sharif University of Technology ; Farhanieh, bijan (Supervisor)
Abstract
Due to growth of the number of passengers in subway transportation systemsthe capacity of the metro stations are on the rise.The generated heat loads in subway line shall be increased by thegrowth of the its capacity. As a result, current subway ventilation systems cannot provide comfort conditions for passengers. Nowadays, modern ventilation systems are designedto improve ventilation performance and to create suitable thermal conditions. Among of these, the under platform andover track exhaust systems and use of platform screen doors can be Cited. The aim of this study is three-dimensional simulation of air flow in modern ventilation systems of subway stations. Numerical simulations are in...