Sharif Digital Repository

Liquid-liquid extraction is one of most important processes in chemical industries. So determination of operating condition effects is very critical. In this thesis we modeled concentration profile in the jet via mathematical equations and compare with experimental data. The major problem in concentration profile and solving equations is lack of knowledge in velocity profile within the jet was formed. Therefore, different flow models such as piston flow model, parabolic flow model, vortex flow model and a cone flow model was used and terminal concentrations inside the jet compared with laboratory values. Results shows the most accurate model to predict the flow concentration along the... 

Emissions of carbon dioxide (CO2) from fossil fuels are a potential issue for the global climate. One way to meet this challenge is to electrochemically convert CO2 molecules to reduced carbon species such as formates, alcohols, hydrocarbons, etc., which is a difficult process due to the poor kinetics of CO2 reduction. Therefore, the use of catalysts, while preventing undesirable side reactions, can also play an important role in reducing CO2. In this study, a two-step synthesis of CuS (1, 5, 12, 24 hr) @ Cu-MOF has been reported as an advanced electrocatalyst for CO2 reduction in neutral pH environments. Bismuth has been used to improve the electrocatalytic properties of the samples. Bi-CuS... 

Because of higher hydrogen demand in recent years, study of hydrogen separation from gas mixtures is highly regarded. Because of some parameters such as high surface to volume ratio and ability to withstanding high pressure, polymeric hollow fiber membranes have a good potential of hydrogen recovery. So in this study, fabrication of single-layer and dual-layer hollow fiber membranes have been investigated. Selective polymer that used in both single and dual layer membranes is polyethersulfone. Membranes were fabricated by dry-wet phase inversion method and effects of extrusion rates and their ratio, composition and temperature of polymer solution, composition of bore fluid, coating and air... 

In recent years, the reductive dehalogenation of the chlorinated hydrocarbons using nanoscale zerovalent iron (nZVI) represents a promising approach for underground remediation. Regarding commercialization of this technique, instability and unknown nature of nZVI particle are still challenging tasks that should be considered.
In the current work, Nanoscale zero-valent iron (nZVI) and palladized iron (Pd/Fe) bimetallic particles were synthesized and employed to react with chlorinated compound (PCE) in water to investigate its degradation behaviors. The results show that the reactant ratio, stabilizer amount and temperature are the main parameters with the considerable effect on PCE... 

In this research, initially the Glycerol liquid membrane with dissolved sodium carbonate carriers, which is supported by CA porous filter, was prepared. The effects of Na2CO3 concentration and pressure difference on gas permeability were investigated. Permeability of CO2 and N2 were measured at pressure difference of 0.7, 1.6, 2.1 and 2.8 bar with carbonate sodium concentration of 0, 1 and 2 mol/lit. Permeability of CO2 was found to be higher than N2. Increasing the pressure difference resulted in an increase in the N2 permeability coefficient while decreased the CO2 permeability coefficient. Increasing the concentration of sodium carbonate increased the CO2 permeability drastically but... 

In liquid-liquid extraction, as in gas absorption, two phases must be brought into good contact to permit transfer of material. The presence of nanoparticles in liquid phase can enhanced the rate of gas-liquid mass transfer. The benefits of nanofluids can be used to enhance the heat and mass transfer of liquid-liquid extraction. Standard test system with low interfacial tension that recommended by EFCE: n-butanol/water/succinic acid, was used in this project. The CNTs/n-butanol that was saturated of water used as dispersed phase. Water and succinic acid used as continuous phase and solute. Since there is no chemical reaction to take place between CNTs and n-butanol, In order to obtain well... 

In this project, the continuous phase mass transfer and backflow coefficients are optimized, using the experimental data from two RDC columns. The continuous and dispersed phases are modeled by stage wise and forward mixing model, respectively. Genetic Algorithm is applied to find the optimized parameters of the model. Olney model is employed to find the slip velocities of drops. The dispersed phase mass transfer coefficients were calculated using Handlos-Baron model. In the other part of the project, the Rigid Drop model was modified to predict the mass transfer coefficients of dispersed phase and the modification parameter was optimized by genetic algorithm. The effect of rotor speed and... 

CO2 separation from air was investigated in this work. An immobilized liquid membrane (ILM) which contains triethylene glycol (TEG) and diethanolamine (DEA) was used for this purpose. In this kind of membranes a liquid, which improves permeability of gas species through the membrane, fills the pores of a polymeric membrane as support. Because of low vapor pressure of solution, liquid loss was negligible. Transport of CO2 was facilitated due to reversible chemical reaction between CO2 and amine solution. A polyvinylidene fluoride (PVDF) membrane was chosen to have chemical resistance against the solution and prevent destruction of polymer by solution. A flat sheet and hydrophilic PVDF was... 

In this research, initially the Triethylene glycol and Diglycol amine liquid membrane which is supported by PVDF, was prepared in order to separate the Carbone dioxide from CO2-Air mixture. A polyvinylidene fluoride (PVDF) membrane was chosen to have chemical resistance to solution. The effect of Pressure, Concentration of TEG and DGA solution and the percentage of carbon dioxide in feed; in rate and permeability of CO2, N2 and O2 and also selectivity of CO2/ N2 , CO2/ O2 and N2/ O2 was investigated. Transport of CO2 was facilitated due to reversible chemical reaction between CO2 and amine solution. The experiments were done in 0.4, 0.6 and 0.8bar and different concentration of solution.... 

In this research, the effect of feed flow concentration on the separation of gas mixture of carbon dioxide and oxygen was investigated by using supported liquid membrane in the presence of nano particles. In order to achieve this purpose, supported liquid membranes were prepared by impregnating a porous hydrophilic PVDF support with TEG, cyclohexanol, TEG/Fe3O4 nano particles and cyclohexanol/ Fe3O4 nano particles. Permeability and selectivity of mixed gases CO2 and O2 were examined at five different CO2 concentrations in feed flow, constant feed flow rate and constant total pressure difference.
In all tests, the permeance of carbon dioxide through cyclohexanol and TEG membranes was... 

In various industries, for energy production, fossil fuels are burned. Oxygen needed for combustion, taken directly from the ambient air; So that the inert gas is about 80%. The presence of this inert gas, mainly nitrogen, reduce combustion efficiency and increase the use of combustible material. In this project with the help of membrane technology, was used to remove the amount of nitrogen in the air so that the incoming air into the combustion chamber is enriched with oxygen. For this purpose, several gas separation membrane was applied and evaluated. Then, according to the oxygen enrichment, fuel efficiency and the amount of savings, increasing chamber temperature, reduction manufacturing... 

In the present study, a heat recovery system for a distributed generation plant (DG) with a 1 MW gas combustion engine has been designed. The purpose of this designing is converting the power plant to a CHP system. For the existing heat recovery system, a shell & tube heat exchanger is designed to recover the thermal energy from exhaust gases and a plate heat exchanger is designed to recover the thermal energy from the engine jacket cooling fluid. The heat exchanger design has been calculated manually and also by use of software. In the software calculation, the heat exchanger design has been done by use of the Aspen HTFS +2006.5 software. In the manual one, the Kern equation (1950) was... 

The main objective of this project is to study the effect of the presence of nanoparticles on mass transfer in liquid-liquid systems. To do this research, TiO2/water, Al2O3/water, CNTs/water and CNTs/toluene have been used as nanofluids. The experiments of TiO2/water nanofluid were been carried out in water-acetone-toluene system at two weigh percents of TiO2 nanoparticles. The result showed that mass transfer decreased in 0.5wt% of TiO2, compared to base fluid, and it increase in 1 %wt. Also in 0.5%wt the decrease in interfacial tension decreased diameter of drops and as a result mass transfer decreased too. In 1%wt the increase in viscosity increased the diameter of drops and then the... 

Employing array of antennas in amny signal processing application has received considerable attention in recent years due to major advances in design and implementation of large dimentional antennas. In many applications we deal with such large dimentional antennas which challenge the traditional signal processing algorithms. Since most of traditional signal processing algorithms assume that the number of samples is much more than the number of array elements while it is not possible to collect so many samples due to hardware and time constraints.
In this thesis we exploit new results in random matrix theory to charachterize and describe the properties of Sample Covariance Matrices... 

Range Profile (RP) is known as one of the most important tools for radar target recognition. The main problem with range profile for radar target recognition is its sensitivity to aspect angle. To overcome this problem, range profiles are assumed to have the same statistical characteristics in small frames of aspect angles or context dependent models such as HMM may be used. All methods presented, seems to have some shortcomings to offer a model based on physical circumstances of target maneuver. For example in such models, consecutive samples of RPs in an aspect frame are assumed to be statistically independent with the same distribution (IID). Here we propose dynamic system (DS) for...