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CO2/N2 Mixed Gas Separation in Glycerol Liquid Membrane Containing Sodium Carbonate Carriers
, M.Sc. Thesis Sharif University of Technology ; Bastani, Darush (Supervisor)
Abstract
In this research, initially the Glycerol liquid membrane with dissolved sodium carbonate carriers, which is supported by CA porous filter, was prepared. The effects of Na2CO3 concentration and pressure difference on gas permeability were investigated. Permeability of CO2 and N2 were measured at pressure difference of 0.7, 1.6, 2.1 and 2.8 bar with carbonate sodium concentration of 0, 1 and 2 mol/lit. Permeability of CO2 was found to be higher than N2. Increasing the pressure difference resulted in an increase in the N2 permeability coefficient while decreased the CO2 permeability coefficient. Increasing the concentration of sodium carbonate increased the CO2 permeability drastically but...
Effect of Packing Roughness on the Cooling Tower's Performance
, M.Sc. Thesis Sharif University of Technology ; Bastani, Darush (Supervisor)
Abstract
The application of wet cooling towers is cooling the circulating water which in many processes extract the exess heat in the system. Any cooling tower involves different parts and one of these parts is packings. The effect of changing packing's charactorizations on the cooling tower's performance is significant and was studied in different researches. In this project the effect of packing roughness on the heat transfer, mass transfer and pressure drop in two arrays of packings and in different conditions of water flow rate, air flow rate and inlet water temperature was studied experimentally. For calculating and investigating the change of mass transfer coefitient, the Poppe model was ...
Stagewise modeling of liquid-liquid extraction column (RDC)
, Article International Journal of Engineering, Transactions B: Applications ; Volume 17, Issue 1 , 2004 , Pages 7-17 ; 1728-144X (ISSN) ; Sharif University of Technology
National Research Center of Medical Sciences
2004
Abstract
Stagewise forward mixing model considering coalescence and redispersion of drops was used to predict the performance of Rotating Disc Liquid-Liquid Extraction Contactors. Experimental data previously obtained in two RDC columns of 7.62 cm diameter, 73.6cm height and 21.9cm diameter, 150cm height were used to evaluate the model predictions. Drop-side mass transfer coefficients were predicted applying Handlos-Baron drop model and Olney's model was used to predict drop velocities. According to the results obtained the followings could be concluded: (1) If the height of coalescence and redispersion i.e.: h = h pφp /φ could be estimated, the stagewise forward mixing with coalescence and...
, M.Sc. Thesis Sharif University of Technology ; Bastani, Daruoosh (Supervisor)
Abstract
In liquid-liquid extraction, as in gas absorption, two phases must be brought into good contact to permit transfer of material. The presence of nanoparticles in liquid phase can enhanced the rate of gas-liquid mass transfer. The benefits of nanofluids can be used to enhance the heat and mass transfer of liquid-liquid extraction. Standard test system with low interfacial tension that recommended by EFCE: n-butanol/water/succinic acid, was used in this project. The CNTs/n-butanol that was saturated of water used as dispersed phase. Water and succinic acid used as continuous phase and solute. Since there is no chemical reaction to take place between CNTs and n-butanol, In order to obtain well...
RDC Column Performance Prediction Using Axial Dispersion Model for Continuous and Forward Mixing Model for Dispersed Phase
, M.Sc. Thesis Sharif University of Technology ; Bastani, Dariush (Supervisor)
Abstract
In this project, the continuous phase mass transfer and backflow coefficients are optimized, using the experimental data from two RDC columns. The continuous and dispersed phases are modeled by stage wise and forward mixing model, respectively. Genetic Algorithm is applied to find the optimized parameters of the model. Olney model is employed to find the slip velocities of drops. The dispersed phase mass transfer coefficients were calculated using Handlos-Baron model. In the other part of the project, the Rigid Drop model was modified to predict the mass transfer coefficients of dispersed phase and the modification parameter was optimized by genetic algorithm. The effect of rotor speed and...
Separation of CO2 from CO2-air Mixture Using ILM Membrane Containing TEG-DEA
, M.Sc. Thesis Sharif University of Technology ; Bastani, Dariush (Supervisor)
Abstract
CO2 separation from air was investigated in this work. An immobilized liquid membrane (ILM) which contains triethylene glycol (TEG) and diethanolamine (DEA) was used for this purpose. In this kind of membranes a liquid, which improves permeability of gas species through the membrane, fills the pores of a polymeric membrane as support. Because of low vapor pressure of solution, liquid loss was negligible. Transport of CO2 was facilitated due to reversible chemical reaction between CO2 and amine solution. A polyvinylidene fluoride (PVDF) membrane was chosen to have chemical resistance against the solution and prevent destruction of polymer by solution. A flat sheet and hydrophilic PVDF was...
Separation of Carbondioxide from CO2-Air Mixture Using ILM Membrane Containg DGA-TEG
, M.Sc. Thesis Sharif University of Technology ; Bastani, Dariush (Supervisor)
Abstract
In this research, initially the Triethylene glycol and Diglycol amine liquid membrane which is supported by PVDF, was prepared in order to separate the Carbone dioxide from CO2-Air mixture. A polyvinylidene fluoride (PVDF) membrane was chosen to have chemical resistance to solution. The effect of Pressure, Concentration of TEG and DGA solution and the percentage of carbon dioxide in feed; in rate and permeability of CO2, N2 and O2 and also selectivity of CO2/ N2 , CO2/ O2 and N2/ O2 was investigated. Transport of CO2 was facilitated due to reversible chemical reaction between CO2 and amine solution. The experiments were done in 0.4, 0.6 and 0.8bar and different concentration of solution....
Separation of Oxygen from Gas Mixture of Carbon Dioxide and Oxygen with Cyclohexanol and Triethylene Glycol Liquid Membrane in the Presence of Metal Oxide Nanoparticles
, M.Sc. Thesis Sharif University of Technology ; Bastani, Daruoosh (Supervisor)
Abstract
In this research, the effect of feed flow concentration on the separation of gas mixture of carbon dioxide and oxygen was investigated by using supported liquid membrane in the presence of nano particles. In order to achieve this purpose, supported liquid membranes were prepared by impregnating a porous hydrophilic PVDF support with TEG, cyclohexanol, TEG/Fe3O4 nano particles and cyclohexanol/ Fe3O4 nano particles. Permeability and selectivity of mixed gases CO2 and O2 were examined at five different CO2 concentrations in feed flow, constant feed flow rate and constant total pressure difference.
In all tests, the permeance of carbon dioxide through cyclohexanol and TEG membranes was...
In all tests, the permeance of carbon dioxide through cyclohexanol and TEG membranes was...
Oxygen Enrichment of Air by Membrane Technology to Reduce Energy Consumption
, M.Sc. Thesis Sharif University of Technology ; Bastani, Dariush (Supervisor)
Abstract
In various industries, for energy production, fossil fuels are burned. Oxygen needed for combustion, taken directly from the ambient air; So that the inert gas is about 80%. The presence of this inert gas, mainly nitrogen, reduce combustion efficiency and increase the use of combustible material. In this project with the help of membrane technology, was used to remove the amount of nitrogen in the air so that the incoming air into the combustion chamber is enriched with oxygen. For this purpose, several gas separation membrane was applied and evaluated. Then, according to the oxygen enrichment, fuel efficiency and the amount of savings, increasing chamber temperature, reduction manufacturing...
Study and Modeling of CHP Systems in Power Plant
, M.Sc. Thesis Sharif University of Technology ; Bastani, Dariush (Supervisor)
Abstract
In the present study, a heat recovery system for a distributed generation plant (DG) with a 1 MW gas combustion engine has been designed. The purpose of this designing is converting the power plant to a CHP system. For the existing heat recovery system, a shell & tube heat exchanger is designed to recover the thermal energy from exhaust gases and a plate heat exchanger is designed to recover the thermal energy from the engine jacket cooling fluid. The heat exchanger design has been calculated manually and also by use of software. In the software calculation, the heat exchanger design has been done by use of the Aspen HTFS +2006.5 software. In the manual one, the Kern equation (1950) was...
Study of the effect of fluid flow on corrosion rate for simple carbon steel in aqueous solution using rotating disk electrode
, Article 18th International Congress of Chemical and Process Engineering, CHISA 2008, Prague, 24 August 2008 through 28 August 2008 ; 2008 ; Mohagheghi, A ; Sharif University of Technology
2008
Abstract
The influence of fluid flow on the corrosion of simple carbon steel ST37 (AISI 1020) in aqueous solution of Bandar-Abbas gas well was studied at 25°C under air-saturated condition. The mechanism and kinetic of corrosion in different hydrodynamic conditions were determined using a rotating disk electrode. Increasing the velocity of rotating disk ≤ 1000 rpm caused an augmentation in corrosion rate from 9.89 to 18.95 mill in./yr. Increasing the velocity beyond 1000 rpm changed the corrosion mechanism so that the activation polarization will control the corrosion process, and the variation in corrosion rates was due to various corrosion mechanisms rather than mass transfer of reactant component....
Adaptive neural network tracking control of a hybrid stepper motor in microstep operation, RBF compared to MLP
, Article IEEE International Conference on Mechatronics and Automation, ICMA 2005, Niagara Falls, ON, 29 July 2005 through 1 August 2005 ; 2005 , Pages 1334-1339 ; 0780390458 (ISBN) ; Vossoughi, G ; Sharif University of Technology
2005
Abstract
In this paper, a radial basis function neural network-based (RBFNN) adaptive inverse controller for real-time position tracking control of a two phase hybrid stepper motor in microstep mode is presented and compared with a conventional fixed gain stand-alone PID controller. Also it is compared to the same neuro-controller using feed forward backpropagation neural networks (FFBP) presented by the same author showing superior performance of RBFNN to FFBP neural networks. A radial basis neural network is used as a controller in the adaptive inverse control method combining with a closed loop PID controller to ensure system's initial robustness and closed loop stability and improves the...
Investigation of Mass Transfer in Liquid-Liquid System in the Presence of Nanosized Particles
, M.Sc. Thesis Sharif University of Technology ; Bastani, Dariush (Supervisor)
Abstract
The main objective of this project is to study the effect of the presence of nanoparticles on mass transfer in liquid-liquid systems. To do this research, TiO2/water, Al2O3/water, CNTs/water and CNTs/toluene have been used as nanofluids. The experiments of TiO2/water nanofluid were been carried out in water-acetone-toluene system at two weigh percents of TiO2 nanoparticles. The result showed that mass transfer decreased in 0.5wt% of TiO2, compared to base fluid, and it increase in 1 %wt. Also in 0.5%wt the decrease in interfacial tension decreased diameter of drops and as a result mass transfer decreased too. In 1%wt the increase in viscosity increased the diameter of drops and then the...
Source Enumeration and Identification in Array Processing Systems
, Ph.D. Dissertation Sharif University of Technology ; Bastani, Mohammad Hasan (Supervisor)
Abstract
Employing array of antennas in amny signal processing application has received considerable attention in recent years due to major advances in design and implementation of large dimentional antennas. In many applications we deal with such large dimentional antennas which challenge the traditional signal processing algorithms. Since most of traditional signal processing algorithms assume that the number of samples is much more than the number of array elements while it is not possible to collect so many samples due to hardware and time constraints.
In this thesis we exploit new results in random matrix theory to charachterize and describe the properties of Sample Covariance Matrices...
In this thesis we exploit new results in random matrix theory to charachterize and describe the properties of Sample Covariance Matrices...
Statistical Modeling of Spatial and Temporal Characteristics of Target Range Profiles for Radar Target Recognition
, M.Sc. Thesis Sharif University of Technology ; Bastani, Mohammad Hassan (Supervisor)
Abstract
Range Profile (RP) is known as one of the most important tools for radar target recognition. The main problem with range profile for radar target recognition is its sensitivity to aspect angle. To overcome this problem, range profiles are assumed to have the same statistical characteristics in small frames of aspect angles or context dependent models such as HMM may be used. All methods presented, seems to have some shortcomings to offer a model based on physical circumstances of target maneuver. For example in such models, consecutive samples of RPs in an aspect frame are assumed to be statistically independent with the same distribution (IID). Here we propose dynamic system (DS) for...
Strong convergence of split-step backward Euler method for stochastic differential equations with non-smooth drift
, Article Journal of Computational and Applied Mathematics ; Volume 236, Issue 7 , 2012 , Pages 1903-1918 ; 03770427 (ISSN) ; Tahmasebi, M ; Sharif University of Technology
2012
Abstract
In this paper, we are concerned with the numerical approximation of stochastic differential equations with discontinuous/nondifferentiable drifts. We show that under one-sided Lipschitz and general growth conditions on the drift and global Lipschitz condition on the diffusion, a variant of the implicit Euler method known as the split-step backward Euler (SSBE) method converges with strong order of one half to the true solution. Our analysis relies on the framework developed in [D. J. Higham, X. Mao and A. M. Stuart, Strong convergence of Euler-type methods for nonlinear stochastic differential equations, SIAM Journal on Numerical Analysis, 40 (2002) 10411063] and exploits the relationship...
New approach in the prediction of RDC liquid-liquid extraction column parameters
, Article Chemical Engineering and Technology ; Volume 31, Issue 7 , 2008 , Pages 971-977 ; 09307516 (ISSN) ; Shahalami, S. M ; Sharif University of Technology
2008
Abstract
The liquid-liquid extraction process is well-known for its complexity and often entails intensive modeling and computational efforts to simulate its dynamic behavior. This paper presents a new application of the Genetic Algorithm (GA) to predict the modeling parameters of a chemical pilot plant involving a rotating disc liquid-liquid extraction contactor (RDC). In this process, the droplet behavior of the dispersed phase has a strong influence on the mass transfer performance of the column. The mass transfer mechanism inside the drops of the dispersed phase was modeled by the Handlos-Baron circulating drop model with consideration of the effect of forward mixing. Using the Genetic Algorithm...
Compressed Sensing Application in Radar Field (SAR)
, M.Sc. Thesis Sharif University of Technology ; Bastani, Mohammad Hassan (Supervisor)
Abstract
Although up to now different processing algorithms have been proposed for Synthetic Aperture Radar (SAR) raw data, all of them suffer from one common problem and that is huge amount of data to be processed. So because of current system limitations, efficient compression algorithms for processing, saving, or transmitting data are needed. Up to now many algorithms have been proposed for SAR raw data compression, but each of them has some defects that should be payed attention to. The most important reason of these defects is the special characteristics of SAR images. With the aid of “Compressed Sensing (CS)”, the new field which has emerged recently, a special characteristic of the scene...
Experimental and CFD Study of Physical Properties Effect on Hydrodynamic and Mass Transfer Coefficient of Single Drops
, M.Sc. Thesis Sharif University of Technology ; Bastani, Daruoosh (Supervisor)
Abstract
In present study, it is tried to investigate the effect of physical properties on hydrodynamic and overall mass transfer coefficient of single drops using different experiments and then simulation of drop motion with OpenFOAM software version 1.7.1. the systems were choosen are toluene/acetone/water and n-butanol/succinic acid/water which their interfacial tensions are 36 and 1.6 mN/m respectively. Various type of nozzles have been used for produce of 1.5, 2, 3 and 4 millimeter drops. The results show that in absence of solute component, the rising velocity of toluene drops in each size is higher than rising velocity of butanol drops inside the water between 25 to 75 percent. But with...
PSE Mass Transfer Modeling Using Axial Mixing For Continues and Forward Mixing Model For Dispersed Phase
, M.Sc. Thesis Sharif University of Technology ; Bastani, Daruoosh (Supervisor)
Abstract
Mass transfer and axial dispersion coefficients for continues phase were calculated by axial mixing model for continues phase and forward mixing model for dispersed phase simultaneously. Experimental data was achieved in pulsed sieve plate column with 22 cm diameter. Toluene –water-acetone and Butanol-Succinic acid- water were used in this experiment. In these systems continues phase is water and mass transfer takes place from continues phase to dispersed phase. Experimental data involves drop size distributions and operating conditions andconcentration in both phases.For calculating overall mass transfer coefficient for drops the handlos and Baron Model was used. The axial dispersion...