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    High-performance/low-temperature-processed dye solar cell counter electrodes based on chromium substrates with cube-like morphology

    , Article Journal of Power Sources ; Vol. 260 , 2014 , Pages 299-306 ; ISSN: 03787753 Behrouznejad, F ; Taghavinia, N ; Sharif University of Technology
    2014
    Abstract
    There is still an open question of how to prepare high-performance counter electrodes for dye solar cells (DSCs) at room temperature; a requirement for flexible DSCs. Here, we introduce Pt deposited cube-like chromium coating as a low-temperature highly-efficient counter electrode for DSCs. Cr is a chemically stable metal and can be easily electroplated on conductive substrates with high roughness (here ∼160 nm) and cube-like appearance. A cyclic electrochemical deposition method with optimized temperature and number of cycles is used to grow Pt nanoparticles on this surface and charge transfer resistance as low as 0.54 Ω cm2 and 0.27 Ω cm2 were obtained at 40 °C and 55 °C solution... 

    Monolithic Solar Cells with Dye or Perovskite Light Absorbent

    , Ph.D. Dissertation Sharif University of Technology Behrouznejad, Fatemeh (Author) ; Taghavinia, Nima (Supervisor)
    Abstract
    According to Iran's proper location to take advantage of solar energy and the ability of nanostructured solar cells fabrication in the country, in this study, the manufacturing problems and complexities of nanostructured solar cells such as dye solar cells and perovskite-based solar cells are investigated. The chromium metal as an alternative to the transparent conductive substrates in order to reduce the manufacturing cost of dye solar cells (DSCs) and reducing series resistance is introduced in this study. In case of utilizing chromium as a substrate for photoanode, the thickness of CrxOy layer is controlled by depositing TiO2 compact layer and the efficiency of DSC is increased from 2.6%... 

    ChemInform abstract: microwave-assisted rapid ketalization/acetalization of aromatic aldehydes and ketones in aqueous media [electronic resource]

    , Article Journal of Chemical Research ; September 1999, Volume -, Number 9; Page(s) 562 to 563 Pourdjavadi, A. (Ali) ; Mirjalili, Bibi Fatemeh ; Sharif University of Technology
    Abstract
    Aromatic aldehydes and ketones are readily acetalized or ketalized under microwave irradiation in the presence of water as a solvent  

    Synthesis and characterization of poly(methacrylates) containing spiroacetal and norbornene moieties in side chain [electronic resource]

    , Article Journal of Applied Polymer Science ; Volume 77, Issue 1, pages 30–38, 5 July 2000 Pourdjavadi, A. (Ali) ; Mirjalili, Bibi Fatemeh ; Sharif University of Technology
    Abstract
    A four-step synthetic strategy was applied to achieve novel methacrylic monomers. 5-Norbornene-2,2-dimethanol was prepared from a Diels–Alder reaction of cyclopentadiene and acrolein, followed by the treatment of the adduct with an HCHO/KOH/MeOH solution. The resulting 1,3-diol (1) was then acetalized with different aromatic aldehydes having OH groups on the ring to produce four spiroacetal derivatives. The reaction of methacryloyl chloride with the phenolic derivatives led to four new methacrylic monomers that were identified spectrochemically (mass, FTIR, 1H-NMR, and 13C-NMR spectroscopy). Free radical solution polymerization was used to prepare novel spiroacetal–norbornene containing... 

    Monolithic dye sensitized solar cell with metal foil counter electrode

    , Article Organic Electronics ; Volume 57 , June , 2018 , Pages 194-200 ; 15661199 (ISSN) Behrouznejad, F ; Taghavinia, N ; Ghazyani, N ; Sharif University of Technology
    Elsevier B.V  2018
    Abstract
    Monolithic dye-sensitized solar cells are conventionally fabricated using carbon composite layer as the counter electrode. In the current research, the brittle carbon composite layer is replaced with a metal foil, aiming to decrease the device series resistance and using less catalyst material in counter electrode. This metallic structure has also an advantage of mechanical strength and decreases the fabrication complexity. The counter electrode is prepared by electrodepositing Cr film followed by electrodepositing Pt nanoparticles on a metal foil. As the porous spacer layer, different composite layers of SiO2, TiO2, and Al2O3 are investigated and the best results are obtained for TiO2... 

    Single Sided Dye Sensitized Solar Cell

    , M.Sc. Thesis Sharif University of Technology Behrouznejad, Fatemeh (Author) ; Taghavinia, Nima (Supervisor)
    Abstract
    In this project single sided dye sensitized solar cell is introduced as a new design that has both of electrodes in one side. These electrodes can be separated vertically by a thin insulator layer such as SiO2 or horizontally by lithographic method. First a metallic thin film is patterned by lithography, and then thickened by electrochemical deposition of Chromium. Platinum is electrodeposited on the substrate of counter electrode and a thin spacer layer is deposited on Platinum layer to separate it from Titanium dioxide layer.
    In Chapters 1, 2 & 3 basic science and methods which are needed for doing this project is introduced. In chapter 1 material for making a standard dye sensitized... 

    Prediction of DNA/RNA Sequence Binding Site to Protein with the Ability to Implement on GPU

    , M.Sc. Thesis Sharif University of Technology Fatemeh Tabatabaei (Author) ; Koohi, Sommaye (Supervisor)
    Abstract
    Based on the importance of DNA/RNA binding proteins in different cellular processes, finding binding sites of them play crucial role in many applications, like designing drug/vaccine, designing protein, and cancer control. Many studies target this issue and try to improve the prediction accuracy with three strategies: complex neural-network structures, various types of inputs, and ML methods to extract input features. But due to the growing volume of sequences, these methods face serious processing challenges. So, this paper presents KDeep, based on CNN-LSTM and the primary form of DNA/RNA sequences as input. As the key feature improving the prediction accuracy, we propose a new encoding... 

    Metal-based bracken-like single-sided dye-sensitized solar cells with horizontal separation

    , Article Physical Chemistry Chemical Physics ; Volume 18, Issue 7 , 2016 , Pages 5244-5252 ; 14639076 (ISSN) Behrouznejad, F ; Taghavinia, N ; Pazoki, M ; Tajabadi, F ; Sharif University of Technology
    Royal Society of Chemistry  2016
    Abstract
    One of the drawbacks of typical dye-sensitized solar cells (DSCs) is their high cost and the high electrical resistance of the transparent conducting substrate. In conventional sandwich-type DSCs, only one of the FTO substrates can be replaced by a metal substrate. We investigated an all-metal-electrode single-sided DSC in which interpenetrated bracken-like Cr electrodes were created using photolithography; mesoporous TiO2 and Pt films were deposited on the laterally separated electrodes. Thermal Pt deposition and electrodeposition methods were investigated and it was found that a cyclic electrodeposition method resulted in selective Pt deposition at room temperature with a higher device... 

    Cross-Lingual Speaker Adaptation for Statistical Parametric Speech Synthesis

    , M.Sc. Thesis Sharif University of Technology Saleh, Fatemeh Sadat (Author) ; Sameti, Hossein (Supervisor)
    Abstract
    Speech synthesis and its applications have been very attractive recently. The main purpose of this technique is to produce a speech signal with natural characteristics of human speech like prosody and emotion. Among all existing methods for speech synthesis, statistical parametric speech synthesis methods are more promising because ofhigher flexibility in comparison to other methods. One of the applications of speech synthesis is speech to speech translation. In these systems, the generated voice in target language should have the same characteristics as the input voice in source language. The main purpose of this research is to review and evaluate the cross lingual speaker adaptation... 

    Hydroelastic Analysis of Surface Piercing Propeller

    , M.Sc. Thesis Sharif University of Technology Fatemeh, Shahreki (Author) ; Seif, Mohamad Saeed (Supervisor)
    Abstract
    Surface piercing propellers are particular type of supercavitating propellers that are commonly used for High-speed vessels. Most studies on this type of propellers has been investigating the hydrodynamic forces. But in recent years with increase in SPPs diameter used in vessels, structural analysis of this type of propellers is considered. For this purpose, studies on the stresses exerted on the propeller structures under load is done with the help of Hydro elastic methods. In this type of analysis, structura of propeller is intended to be flexible and Displacements under pressure checked and Tensions resulting from it are studied.
    The present Thesis using ANSYS software to analyze a... 

    Data-Driven Pricing Based on Demand Prediction Using Machine Learning Methods

    , M.Sc. Thesis Sharif University of Technology Khosroshahi, Fatemeh Zahra (Author) ; Sedghi, Nafiseh (Supervisor)
    Abstract
    Pricing plays an important and essential role in the profit and income of companies. The importance of pricing is not only related to its role in the company's profitability, but it also changes the customer's understanding and loyalty towards the company and can create the company's reputation or destroy it. Determining the right price will increase product sales and increase customer loyalty and create a competitive advantage for the company. One of the most important and influential variables in product pricing is the amount of demand. The main challenge of companies for product pricing is the uncertainty in their demand. In order to deal with this problem, data-driven pricing is used.... 

    Design of Low-Power Zero Temperature Coefficient (ZTC) CMOS Oscillators

    , M.Sc. Thesis Sharif University of Technology Shahidani, Mohammad Aref (Author) ; Akbar, Fatemeh (Supervisor)
    Abstract
    The increasing demand for autonomous vehicles and reliable communication protocols and hardware interfaces, such as CAN bus and USB, underscores the necessity for stable clock sources that maintain a low temperature coefficient (TC) over wide temperature ranges. This demand is particularly emphasized in applications such as wearables, network sensors, downhole devices, WSNs, and IoT, where long-lasting battery life and frequency-stable clock sources over a broad temperature range (e.g. -20 °C to 100 °C) are crucial. Traditionally, variations in frequency caused by temperature have been mitigated by employing off-chip components like crystals or ceramic based oscillators, but this approach... 

    Silica chloride/wet SiO2 as a novel heterogeneous system for the deprotection of acetals under mild conditions [electronic resource]

    , Article Phosphorus, Sulfur, and Silicon and the Related Elements ; Volume 178:2667-2670, Issue 12, 2003 Mirjalili, B. F. (BiBi Fatemeh) ; Pourjavadi, Ali ; Zolfigol, Mohammad Ali ; Bamoniri, Abdolhamid
    Abstract
    A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition  

    The Impact of AV and CAV Vehicles on Capacity and Traffic Flow with Cooperative Lane changing in Mixed Traffic Environment

    , M.Sc. Thesis Sharif University of Technology Zanjani, Fatemeh Sadat (Author) ; Nassiri, Habibollah (Supervisor)
    Abstract
    Autonomous vehicles, as an integral part of intelligent transportation systems, will play a significant role in the future of transportation services. These vehicles have a high potential to improve road traffic capacity and the efficiency of transportation systems. One type of autonomous vehicle is the connected and autonomous vehicle (CAV), which can communicate with each other, roadside units, traffic control signals, and other infrastructures or devices. This study investigates the impact of autonomous vehicles and connected and autonomous vehicles on the traffic flow of the Tehran-Karaj freeway and vice versa, under various penetration rates and in a mixed traffic environment. In this... 

    A Comprehensive Review of Studies Conducted in Entrepreneurship Education in Order to Achieve a Codified Framework

    , M.Sc. Thesis Sharif University of Technology Emamjome, Fatemeh Sadat (Author) ; Feyzbakhsh, Alireza (Supervisor)
    Abstract
    In the current situation and considering the economic conditions, entrepreneurship and self-employment are important factors of business growth. To prepare people in this field, there is a need for effective training that can motivate people. Identifying the effective methods and different dimensions of the entrepreneurship education framework that can lead to setting up a successful program for training people and facilitate the way to achieve the goal of education is one of the important goals of this research. By studying the literature from 2010 onwards, this research systematically examined 96 articles and tried to improve the framework of entrepreneurship education that was stated in... 

    Evaluation of the Damage to Steel MRF Structures Under Near Field Earthquake Pulses Using a Performance-Based Design Approach

    , M.Sc. Thesis Sharif University of Technology Mousavi, Fatemeh Sadat (Author) ; Rahimzadeh Rofooei, Fayaz (Supervisor)
    Abstract
    Research on the characteristics of the near field earthquakes has been very popular in recent years due to the considerable damages they have caused to the structures located within the vicinity of seismic sources. The incapability of response spectra for structural damage assessment has been revealed through recent investigations. The recorded data show that the near field earthquakes are often accompanied by a large energy pulse in the beginning of the records caused by the so-called directivity phenomenon. That has encouraged many researchers to study the possibility of using the velocity pulse of these records to evaluate the imposed seismic demands on structures. Thus, investigating the... 

    Oxidative Addition of Amines to Aldehydes Catalyzed by Supported Cobalt Nanoparticles on SBA-15

    , M.Sc. Thesis Sharif University of Technology Raeisi, Mojdeh (Author) ; Saidi, Mohamad Reza (Supervisor) ; Rajabi, Fatemeh (Co-Advisor)
    Abstract
    Considering the widespread applications of amides, synthesis of these compounds is of great importance. The one pot oxidative addition of amines to aldehydes is one of the most simple and appealing approaches to synthesis amides. With the aim of developing a mild and convenient approach towards preparation of amides, numerous methods have been reported for this important process over the past few decades. These improvements have been mostly related to the optimization of reaction conditions and the use of more challenging substrates including diverse derivatives of aldehydes, and also design a novel and effective catalytic systems. Due to the various advantages of supported heterogeneous... 

    A study on utilizing different metals as the back contact of CH3NH3PbI3 perovskite solar cells

    , Article Journal of Materials Chemistry A ; Volume 4, Issue 35 , 2016 , Pages 13488-13498 ; 20507488 (ISSN) Behrouznejad, F ; Shahbazi, S ; Taghavinia, N ; Wu, H. P ; Wei Guang Diau, E ; Sharif University of Technology
    Royal Society of Chemistry  2016
    Abstract
    Organic-inorganic halide perovskite solar cells have attracted considerable interest due to their high efficiency and low fabrication cost. Au and Ag are usually used as the back contact metals but have limitations such as Au is too expensive and Ag is unstable. Here, Pt, Au, Ni, Cu, Cr and Ag were studied as the back contact electrodes for perovskite solar cells. We looked at how the work function of metals can affect their photovoltaic characteristics. The compositional and electrical characterizations were studied using X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS). The general trend observed was that the shunt resistance and open-circuit voltage... 

    Interfacial investigation on printable carbon-based mesoscopic perovskite solar cells with niox/c back electrode

    , Article ACS Applied Materials and Interfaces ; Volume 9, Issue 30 , 2017 , Pages 25204-25215 ; 19448244 (ISSN) Behrouznejad, F ; Tsai, C. M ; Narra, S ; Diau, E. W. G ; Taghavinia, N ; Sharif University of Technology
    American Chemical Society  2017
    Abstract
    Solar cells with high efficiency, low cost, and high stability are the target for the new generation of solar cells. A fully printable perovskite (CH3NH3PbI3) solar cell (PSC) with device architecture FTO/TiO2/Al2O3/NiOx/C is fabricated in the current research as a low-cost and relatively stable structure and is investigated to determine how different fabrication factors such as the thickness of the insulating spacer layer (Al2O3) or treatments such as heat and UV-O3 treatments can affect the interfacial properties of this multilayer mesoporous structure. X-ray photoelectron spectra (XPS) show that UV-O3 treatment increases the Ni3+(Ni2O3) phase on the surface of the black nickel oxide layer... 

    Engineering of CIGS nanoparticle inks for colloidal stability, uniform film formation and application as HTL for perovskite solar cells

    , Article Journal of Industrial and Engineering Chemistry ; 2021 ; 1226086X (ISSN) Khosroshahi, R ; Tehrani, N. A ; Forouzandeh, M ; Behrouznejad, F ; Taghavinia, N ; Bagherzadeh, M ; Sharif University of Technology
    Korean Society of Industrial Engineering Chemistry  2021
    Abstract
    In this work, synthesis of CuIn0.75Ga0.25S2 (CIGS) nanoparticles, the formation of stable dispersion, deposition of high-quality films and, fabrication of thin-film Perovskite solar cells are reported. The stability of nanoparticle ink is crucial in the formation of device-quality films. The chalcogenide-based materials are widely used in thin-film solar cells; in particular, Cu(In,Ga)S2 are used as an absorber and hole transporting layer. In the present study, the nanoparticles of about 20 nm size and bandgap of 1.5 eV are synthesized using a heat-up method. A variety of solvents are used as dispersing media and the stability of the inks is evaluated by precise optical monitoring. We...