Sharif Digital Repository

The perovskite oxide BaTiO3, doped with Ge oxides oxidized methane to C2 coupled hydrocarbons. The pure barium titanate exhibited an ultraviolet absorption effect. The addition of GeO2 resulted in an increase in absorption of wavelength. Small amount of Ge decreased band gap energy. For promoted BaTiO3 catalysts with stable cation valance, electron donation ability of lattice oxygen was parallel to its ability of adsorb and active oxygen, and decreased the chance of deep oxidation of methyl radicals and C2 hydrocarbons and thus will result in an increase of C2 yield. This is an abstract of a paper presented at the 42nd Loss Prevention Symposium (New Orleans, LA 4/6-10/2008)  

The perovskite oxide BaTiO3, doped with Ge oxides oxidized methane to C2 coupled hydrocarbons. The ultraviolet-visible spectra of pure barium titanate and Ge doped BaTi(1-x)GexO3(x=0.05,0.1) were compared. The pure barium titanate exhibited an ultraviolet absorption effect. The addition of GeO2 resulted in an increase in absorption of wavelength. Therefore, small amount of Ge decreased band gap energy. Oxygen is inserted by nucleophilic attack which may be considered as an acid-base process. For promoted BaTiO3catalysts with stable cation valance, electron donation ability of lattice oxygen is parallels to its ability of adsorb and active oxygen, and decrease the chance of deep oxidation of... 

The perovskite oxide BaTiO3, doped with Ge oxides oxidized methane to C2 coupled hydrocarbons. The ultraviolet-visible spectra of pure barium titanate and Ge doped BaTi(1-x) GexO3 (x=0.05 ,0.1) were compared. The pure barium titanate exhibited an ultraviolet absorption effect. The addition of GeO2 resulted in an increase in absorption of wavelength. Therefore, small amount of Ge decreased band gap energy. Oxygen is inserted by nucleophilic attack which may be considered as an acid-base process. For promoted BaTiO3 catalysts with stable cation valance, electron donation ability of lattice oxygen is parallels to its ability of adsorb and active oxygen, and decrease the chance of deep oxidation... 

Direct Simulation Monte Carlo (DSMC) method is applied to evaluate the performance of a new micro gas sensor (MIKRA) for mass analysis of ammonia in the rarefied gas. In order to simulate a rarefied gas inside the micro gas detector, Boltzmann equation is applied to obtain high precision results. This study performed comprehensive studies to reveal the main mechanism of force generation and applied this for the analysis of the gas mixture. Our findings show that value of generated Knudsen force significantly varies when the percentage of the NH3 varies in the mixture. According to obtained results, the maximum Knudsen force increases when the fraction of the ammonia decreases. Our findings... 

Much research has been conducted and published on the examination of the behavior of reinforced steel and concrete structures with a FRP system. Nevertheless, the performance of FRP differs from that of FRCM, particularly at high temperature and ultimate strength. The present study provides a review of previous research on structural elements (viz. beams, columns, arches, slabs, and walls) retrofitted with FRCM systems, taking account of various parameters, such as layers, composite types, configurations, and anchors for controlling or delaying failure modes (FMs). Additionally, this paper discussed the details of different FMs observed during experimental tests, such as crushed concrete or... 

A typical process in many industrial applications is rising bubble dynamic in viscous liquids like two-phase reactors. Examining the physical behavior of bubbles may improve the understanding of systems regarding design and operation. This study focused on the splitting of bubbles resulting from their impact on solid obstacles. Fragmentation of the bubbles appears in many applications such as lab on a chip in small scale or slug bubbly flow moving upward in a tube in large scales. Using a new index-function model in Lattice Boltzmann technique proposed by “He”, we simulated the deformation and motion of a bubble in different regimes, through which, we accurately captured a sharp interface... 

Simultaneous extraction of zinc and cadmium by a mixture of di-2-ethyl hexyl phosphoric acid (DEHPA) and mono-2-ethyl hexyl phosphoric acid (MEHPA), and the synergistic effect of MEHPA on co-extraction of zinc and cadmium with DEHPA have been investigated. It was shown that the extraction of zinc and cadmium by DEHPA and/or MEHPA can be increased by an increase of pH. The results also illustrate that the pH0.5 of zinc, by increase in MEHPA from 0.1 to 8 vol%, did not vary significantly while that of cadmium varies from 0.63 to 2.4. In other words MEHPA prevents selective extraction of zinc from aqueous media containing both zinc and cadmium. Studies on the selective separation parameter... 

The steady 2-D boundary layer flow over a flat plate is studied analytically by homotopy perturbation method to analyze the entropy generation inside the boundary layer with constant wall temperature. By the transformations of go-verning equations including continuity, momentum, and energy by similarity va-riables, a dimensionless equation for entropy generation inside the boundary layer is obtained. The effects of important parameters such as Reynolds and Eck-ert numbers are investigated and the physical interpretations of the results are explained in details  

In this paper we study and evaluate the performance of a spectral-phase encoded optical CDMA (SPE-OCDMA) system using advanced receiver structures based on second harmonic generation (SHG) effect imposed in a Thick or Thin crystal. This receiver structure is employed as the nonlinear pre-processor prior to the conventional low-speed photodetector. In our performance evaluation amplified spontaneous emission (ASE) of the optical amplifiers, receiver front end thermal noise and photodetector shot noise which are effective in low power conditions, and multiple access interference (MAI) noise which is the dominant source of noise in high power conditions in any coherent OCDMA communications... 

The present work is concerned with the steady incompressible flow through a parallel plate channel with stretching walls under an externally applied magnetic field. The governing continuity and Navier-Stokes equations are reduced to a fourth order nonlinear differential equation by using vorticity definition and similarity solution transformation. The obtained equations are solved by applying the analytical homotopy perturbation method (HPM). The method is called order of magnitude suggested for simplifying series solution to finite expression that is useful in engineering problems. The results are verified by comparing with numerical solutions and demonstrate a good accuracy of the obtained... 

Development of a new micro gas sensor is essential for the analysis of the outcome of gas separation devices. In this paper, direct simulation Monte Carlo (DSMC) modeling of low-pressure gas sensor was performed to investigate the effect of physical parameters on the performance and main characteristics of this type of actuator in various operating conditions. Extensive parametric studies were done and the effect of ambient pressure, temperature and gap of arms were comprehensively investigated. Our findings showed that gap size significantly influences the flow features and force generation inside the sensor. © 2018 Bulgarian Academy of Sciences, Union of Chemists in Bulgaria  

Oxygen evolution was observed upon mixing solid manganese(III) bidentate Schiff base complexes with aqueous solutions of cerium(IV) ammonium nitrate. However, oxygen evolution was not observed upon mixing solutions of the complexes (in acetonitrile) with Ce(IV). Electron-withdrawing substituents on the Schiff base ligands (NO2, Br) enhanced the reactivity of the manganese complexes toward oxygen evolution. Oxygen evolution was also affected by R groups on the ligands, in the order Me > Et Bz. © 2009 Springer Science+Business Media B.V  

The title complex was synthesized and structurally characterized by single-crystal X-ray diffraction. This complex was solved in the triclinic system, space group P1, with the following unit-cell parameters: a = 8.5657(4)Å, b = 10.9848(5)Å, c = 13.1681(6)Å, α = 112.617(1)°, β = 99.646(1)°, δ = 90.849(1)°, Z = 2, V = 1123.28(9)Å3. The final R value was R1 = 0.0344 for 15675 measured reflections. 2008 © The Japan Society for Analytical Chemistry  

The title complex has been synthesized and structurally characterized by single-crystal X-ray diffraction. This complex has a dinuclear structure where two copper(II) ions are bridged by two bent alkoxo groups. The citrate acts as a tetradentate ligand coordinating via three carboxylates and an alkoxo groups in which one of three carboxylates is coordinated weakly. The coordination geometry around the Cu(II) is strongly distorted square pyramidal. The distance between the two copper atoms is 2.8386(3)Å. 2007 © The Japan Society for Analytical Chemistry  

MHD extended flow of second-grade viscoelastic nanofluid is studied in two-dimensional mode on a curve stretching surface. Items like Joule heating and curvature parameter have been applied to inspect the heat transfer and mass transfer rates. To produce the nonlinear ordinary differential system, appropriate transformations are used. The quasi-linearization method is utilized to derive the solutions numerically. The impact of specific variables on the properties of fluid has been studied. Conclusions indicate that the increase in Schmidt number halted the fluid concentration, whereas temperature grew because of an increment in radiation parameter. Viscous fluid velocity and concentration... 

Charge-transfer (CT) complexes formed from the reactions of 4-nitropyrocatechol (4-nCat) as an electron acceptor with four amino alcohols: 2-aminoethanol, 1-amino-2-propanol, 4-aminobutanol and N-(2-hydroxyethyl)-1,3-diaminopropane (NHEDAP) as electron donors, have been studied spectrophotometrically in H2O and H2O/EtOH at 20, 25, 30, 35 and 40 °C. The calculated values of the oscillator strength and transition moment confirm the formation of CT-complexes. The thermodynamic and spectroscopic parameters were also evaluated for the formation of CT-complexes. The equilibrium constants ranged from 9.00 to 2.20 l mol-1 (M-1). These interactions are exothermic and have relatively large standard... 

In the last decade, many potent analytical methods have been utilized to find the approximate solution of nonlinear differential equations. Some of these methods are energy balance method (EBM), homotopy perturbation method (HPM), variational iteration method (VIM), amplitude frequency formulation (AFF), and max-min approach (MMA). Besides the methods mentioned above, the Akbari-Ganji method (AGM) is a highly efficient analytical method to solve a wide range of nonlinear equations, including heat transfer, mass transfer, and vibration problems. In this study, it was constructed the approximate analytic solution for movement of two mechanical oscillators by employing the AGM. In the derived... 

At SCN 2018, Fiore and Pagnin proposed a generic compiler (called “Matrioska”) allowing to transform sufficiently expressive single-key homomorphic signatures (SKHSs) into multi-key homomorphic signatures (MKHSs) under falsifiable assumptions in the standard model. Matrioska is designed for homomorphic signatures that support programs represented as circuits. The MKHS schemes obtained through Matrioska support the evaluation and verification of arbitrary circuits over data signed from multiple users, but they require the underlying SKHS scheme to work with circuits whose size is exponential in the number of users, and thus can only support a constant number of users. In this work, we propose... 

The ride comfort of high-speed trains passing over railway bridges is studied in this paper. A parametric study is carried out using a time domain model. The effects of some design parameters are investigated such as damping and stiffness of the suspension system and also ballast stiffness. The influence of the track irregularity and train speed on two comfort indicators, namely Sperling's comfort index and the maximum acceleration level are also studied. Two types of railway bridges, a simple girder and an elastically supported bridge are considered. Timoshenko beam theory is used for modelling the rail and bridge and two layers of parallel damped springs in conjunction with a layer of mass... 

It is believed that it is going to be a sizeable mismatch between supply and demand when it comes to renewable resources. Lately, researchers are on course to compensate for the unpredictabilityof such resources by the employment of phase change materials (PCMs). Having multiple advantages, PCMs generally suffer from inadequate thermal conductivity which causes prolonged transition procedures. To tackle this issue, this study is fixated on two parameterswhich are linked to fins addition and porous media incorporation in a melting process within a triple concentric tube heat exchanger (TCTHX). The results provided by multiple cases underlined the significance of natural convection in the bare...