Sharif Digital Repository

Nitinol shape memory alloy is a biocompatible material that is suitable for biomedical applications due to its superelasticity, shape memory effect, good corrosion and fatigue resistance, and sound damping properties. With the selective laser melting (SLM) additive manufacturing process, it is possible to produce customized NiTi implants in the form of porous metamaterials with complex geometries. This paper presents a review of modeling, production, and application of NiTi implants. First, the fundamentals of shape memory alloys and the SLM process are summarized. Then, the effects of the SLM process on the transformation temperatures and the impacts of Heat treatments on these temperatures... 

Laser Powder Bed Fusion (LPBF) technology is a new trend in manufacturing complex geometric structures from metals. This technology allows producing topologically optimized parts for aerospace, medical and industrial sectors where a high performance-to-weight ratio is required. Commonly the feature size for such applications is higher than 300–400 microns. However, for several possible applications of LPBF technology, for example, microfluidic devices, stents for coronary vessels, porous filters, dentistry, etc., a significant increase in the resolution is required. This work is aimed to study the resolution factors of LPBF technology for the manufacturing of superelastic instruments for... 

The combined action of ultraviolet irradiation and microwave heating onto acetonitrile solution of [Re((Formula presented.))(CO)3(NCMe)]OTf ((Formula presented.) =phenantroline and neocuproine) afforded cis,trans-Re((Formula presented.))(CO)2(NCMe)2]+ acetonitrile derivatives. Substitution of relatively labile NCMe with a series of aromatic N-donor ligands (pyridine, pyrazine, 4,4’-bipyridine, N-methyl-4,4’-bipyridine) gave a novel family of the diimine cis,trans-[Re((Formula presented.))(CO)2(L)2]+ complexes. Photophysical studies of the obtained compounds in solution revealed unusually high absorption across the visible region and NIR phosphorescence with emission band maxima ranging from... 

In the present work we obtained a series of NIR luminescent platinum(II) complexes with a pincer N^N^C ligand based on the conjugated {benzoimidazo[1,2-a]pyrazine} system with the [Pt(N^N^C)L]n+ structural motif (L = phosphine, alkynyl or pyridine-type ligands). We have also synthesized two complexes with bidentate phosphines that demonstrate different types of coordination: 1) as chelating ligand (in case of 1,2-bis(diphenylphosphino)benzene), that led to de-coordination of pyridine ring of N^N^C ligand and formation of a [Pt(N^C)dppb]+ complex; 2) as a bridging ligand (in case of bis(diphenylphosphino)methane) between two {Pt(N^N^C)} fragments in a dimeric complex of type... 

This paper presents synthesis and photophysical investigation of a very rare type of the ReI diimine complexes, [Re(diimine)(CO)3(OPR3)]+, R = Ph, Cy; diimine – phenanthroline and neocuproine, containing monodentate (unsupported) phosphine oxide ligands. The obtained compounds have been structurally characterized in solid phase by using XRD crystallography, which revealed unusual distortions in the pseudo octahedral rhenium environment, which may be ascribed to intramolecular interligand (phosphine oxide – diimine) interaction rather than to crystal packing effect. Optimization of the ground state structure of these molecules with the DFT method also confirmed intramolecular origin of the... 

The influence of the addition of the nonionic surfactants C12DMPO, C14DMPO, C10OH, and C10EO5 at concentrations between 10-5 and 10-1 mmol/L to solutions of β-casein (BCS) and β-lactoglobulin (BLG) at a fixed concentration of 10-5 mmol/L on the dilational surface rheology is studied. A maximum in the viscoelasticity modulus |E| occurs at very low surfactant concentrations (10-4 to 10-3 mmol/L) for mixtures of BCS with C12DMPO and C14DMPO and for mixtures of BLG with C10EO5, while for mixture of BCS with C10EO5 the value of |E| only slightly increased. The |E| values... 

Relative permeability curves of two-phase flow in a fracture have been a subject of study in recent years. The importance of these curves have been widely observed in multidisciplines, such as water subsurface resources, geothermal energy and underground hydrocarbon resources, especially fractured oil and gas reservoirs. Extensive experimental studies have been cited alongside the numerical studies in this area. However, simple analytical and practical solutions are still attractive. In the current study, wettability effects and phase interference explicitly were tried to be implemented in a simple analytical formula. The wettability effects are represented by residual saturations which... 

Let G be a graph with n vertices and m edges and assume that f : V ( G ) → N is a function with ∑v ∈ V ( G ) f ( v ) = m + n. We show that, if we can assign to any vertex v of G a list Lv of size f ( v ) such that G has a unique vertex coloring with these lists, then G is f-choosable. This implies that, if ∑v ∈ V ( G ) f ( v ) > m + n, then there is no list assignment L such that | Lv | = f ( v ) for any v ∈ V ( G ) and G is uniquely L-colorable. Finally, we prove that if G is a connected non-regular multigraph with a list assignment L of edges such that for each edge e = u v, | Le | = max { d ( u ), d ( v ) }, then G is not uniquely L-colorable and we conjecture that this result holds for... 

We construct counterexamples to the conjecture of Xu (1990, J. Combin. Theory Ser. B50, 319-320) that every uniquely r-colorable graph of order n with exactly (r-1)n-(r2) edges must contain a Kr. © 2001 Academic Press  

A series of bis-metalated phosphorescent [(N^C)2Ir(bipyridine)]+ complexes with systematic variations in the structure and electronic characteristics of the N^C ligands were synthesized and characterized by using elemental analysis, mass spectrometry, NMR spectroscopy and X-ray crystallography. Investigation of the complexes’ spectroscopic properties together with DFT and TD DFT calculations revealed that metal-to-ligand charge transfer (MLCT) and intraligand (LC) transition play key roles in the generation of emissive triplet states. According to the results of theoretical studies, the 3LC excited state is more accurate to consider as an intraligand charge transfer process (ILCT) between N-... 

The interfacial tension (IFT) of a crude oil/CO2 system is recognized as the main property affecting the efficiency of CO2 flooding during an enhanced oil recovery (EOR) process. The addition of a paraffin group hydrocarbon to asphaltenic crude oils as an asphaltene precipitant component is aimed to mimic the asphaltene precipitation process during crude oil production and transportation. Asphaltene precipitation would critically affect the interfacial behavior of crude oil/CO2 systems. In the first part of this study, the equilibrium densities of oil samples which contain n-heptane at different ratios were measured over varying pressures at 323 K. Then, the equilibrium IFT between CO2 and... 

Interfacial tension (IFT) is known as the critical parameter affecting the efficiency of CO2 flooding during the enhanced oil recovery (EOR) process. Besides, the asphaltene precipitation phenomenon is reported as the most significant problem during CO2 injection into asphaltenic oil reservoirs. Accordingly, it is important to examine the effect of asphaltene precipitation on the IFT behavior of the oil-CO2 system at reservoir conditions. The main objective of this research work is to study of the effect of asphaltene and its type on the IFT behavior of the oil-CO2 system. The IFT between pure CO2 and a model oil both with and without asphaltene was measured using an axisymmetric drop shape... 

The stability of the topological order phase induced by the Z3 Kitaev model, which is a candidate for fault-tolerant quantum computation, against the local order phase induced by the three-state Potts model is studied. We show that the low-energy sector of the Kitaev-Potts model is mapped to the Potts model in the presence of transverse magnetic field. Our study relies on two high-order series expansions based on continuous unitary transformations in the limits of small and large Potts couplings as well as mean-field approximation. Our analysis reveals that the topological phase of the Z3 Kitaev model breaks down to the Potts model through a first-order phase transition. We capture the phase... 

Interfacial tension (IFT) is known as the critical parameter affecting the efficiency of CO2 flooding during the enhanced oil recovery (EOR) process. Besides, the asphaltene precipitation phenomenon is reported as the most significant problem during CO2 injection into asphaltenic oil reservoirs. Accordingly, it is important to examine the effect of asphaltene precipitation on the IFT behavior of the oil-CO2 system at reservoir conditions. The main objective of this research work is to study of the effect of asphaltene and its type on the IFT behavior of the oil-CO2 system. The IFT between pure CO2 and a model oil both with and without asphaltene was measured using an axisymmetric drop shape... 

In this research, the IFT behavior of two different specimens of W/O emulsion with distinctive soluble ingredients of water in contact with CO2 and N2 was examined. The Minimum Miscibility Pressure (MMP) of the mentioned gases with emulsion specimens were measured and compared with the case of the original crude oil with no water content. This study focuses on the quantity of water in the W/O emulsion specimens and its effects on IFT and MMP values. The IFT behavior of W/O emulsions was surveyed for two different cases of distinctive water soluble ingredients, i.e. sea water and reservoir brine. The tests were performed under high pressure-high temperature (HPHT) conditions utilizing... 

Purpose: The purpose of this paper is to present and evaluate the performance of innovation systems by considering two indicators of efficiency and effectiveness. The scope of the evaluation is globally and due to the situation of each country, the suggested strategies are proposed to maintain the status quo or move toward the desired situation for countries. Design/methodology/approach: The approach is to compare and benchmark the countries in terms of the efficiency and effectiveness of their innovation system. The Global Innovation Index report’s input-to-output ratio and the global competitiveness report are used for the assessment. Findings: The findings indicate that countries such as... 

Purpose: The purpose of this paper is to present and evaluate the performance of innovation systems by considering two indicators of efficiency and effectiveness. The scope of the evaluation is globally and due to the situation of each country, the suggested strategies are proposed to maintain the status quo or move toward the desired situation for countries. Design/methodology/approach: The approach is to compare and benchmark the countries in terms of the efficiency and effectiveness of their innovation system. The Global Innovation Index report’s input-to-output ratio and the global competitiveness report are used for the assessment. Findings: The findings indicate that countries such as... 

Perovskite solar cells have been constructed under the standard procedure by employing soluble tetratriphenylamine-substituted Zn phthalocyanine as hole transporting material. Solution processed device construction was carried out under ambient conditions of 50–60% ambient humidity. Triphenylamine substitution played the double role of imparting solubility to the core metal phthalocyanine as well as to introduce electron-rich ligands, which could enhance the role of Zn phthalocyanine as hole transporter. Indeed, the obtained material was functional. The present data highlight tetratriphenylamine-substituted Zn phthalocyanine as hole transporting material but also highlight the importance of... 

Considerable portion of energy losses in a vehicle traced to tire. Energy losses in a tire are due to tire longitudinal slip as well as rolling resistance. Hence, both of aforementioned factors must take into the consideration to study the tire energy loss. Present paper aims to investigate the power losses in tires and to examine influence of road conditions and tire inflation pressure on them. To cover the real-world conditions, experiments were done on a gasoline-fueled passenger vehicle on an urban highway along two routes with same length and opposite gradients to comprise the change of road conditions. Then, by use of engine performance model which is prepared in dynamometer... 

An efficient method to automatically recognize basic human actions is proposed to improve the communication between a human and a computer. Human actions are considered as patterns generated by complex non-linear dynamical models. A non-linear dynamical model is used to represent human actions. Gaussian process dynamical models are used to capture the spatial and temporal behaviors of actions. To make the process more efficient a 7-dimensional feature is extracted for each action. Although the extracted feature vector is compact compared to a high-dimensional temporal pattern, it can efficiently discriminate among different actions. The tests run on CMU MoCap database with SVM show promising...