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Synthesis and application of diethanolamine-functionalized polystyrene as a new sorbent for the removal of p-toluenesulfonic acid from aqueous solution
, Article Journal of Industrial and Engineering Chemistry ; Volume 30 , October , 2015 , Pages 281-288 ; 1226086X (ISSN) ; Ahmadpour, A ; Rohani Bastami, T ; Dabir, H ; Sharif University of Technology
Korean Society of Industrial Engineering Chemistry
2015
Abstract
Polystyrene resin was functionalized by diethanolamine for the efficient removal of p-toluenesulfonic acid (p-TSA) from aqueous solution. Functionalized adsorbent (DEA-PS) was characterized by elemental analysis, Fourier transform infrared spectroscopy, point of zero charge measurement and field-emission scanning electron microscopy. According to the results, maximum removal of p-TSA was observed at the pH range of 2.5-5. The adsorption kinetics of p-TSA onto DEA-PS was represented by pseudo-first-order model and the equilibrium data followed Langmuir model well. The adsorption process was endothermic and spontaneous, along with the positive change of entropy. The regeneration of DEA-PS was...
Continuous Synthesis of Silver Chloride Nanoparticles Using a Spinning Disk Reactor
, M.Sc. Thesis Sharif University of Technology ; Molaei Dehkordi, Asghar (Supervisor)
Abstract
Silver chloride nanoparticles (AgCl NPs) have been widely used in various areas such as medicine industry, photographic materials, catalytic materials, pigments, and photochromic materials. Therefore, various studies were conducted for their synthesizes. In the present work, precipitation or reactive crystallization method was used for the synthesis of AgCl NPs. In this regard, silver nitrate and sodium chloride as reactants and gelatin as a surfactant were used in a continuous spinning disk reactor (SDR) at the ambient temperature and pressure. The influences of various parameters such as initial supersaturation , free ion ratio, dilution with water , disk diameter , disk rotation speed,...
Effects of different operating parameters on the particle size of silver chloride nanoparticles prepared in a spinning disk reactor
, Article Applied Physics A: Materials Science and Processing ; Volume 120, Issue 1 , July , 2015 , Pages 105-113 ; 09478396 (ISSN) ; Davarpanah, M ; Ahmadpour, A ; Sharif University of Technology
Springer Verlag
2015
Abstract
The aim of this research was to present an experimental method for large-scale production of silver chloride nanoparticles using spinning disk reactor. Silver nitrate and sodium chloride were used as the reactants, and the protecting agent was gelatin. The experiments were carried out in a continuous mode by injecting the reactants onto the surface of the spinning disk, where a chemical precipitation reaction took place to form AgCl particles. The effects of various operating variables, including supersaturation, disk rotational speed, reactants flow rate, disk diameter, and excess ions, on the particle size of products were investigated. In addition, the AgCl nanoparticles were...
Hydroxy Apatite/Titania Nanostructure Biocoating on Ti-6Al-4V Alloy by Sol-Gel Dip-Coating
, M.Sc. Thesis Sharif University of Technology ; Faghihi Sani, Mohammad Ali (Supervisor)
Abstract
Ceramic coatings on metallic substrates are used in many different applications. In biomaterials science, hydroxyapatite coating due to its similarity to the mineral part of bone structure is used to modification of implants surface. In this research, the HA/TiO2 double layer was coated on Ti-6Al-4V by sol- gel dip-coating method. After preparation of stable TiO2 sol, the Ti-6Al-4V substrate was dipped into the TiO2 sol. The speed of dipping was 10cm/min. After drying at 80°C, the TiO2 layer heat-treated at different temperature (350-500°C) for 1h. The HA outer layer was coated by dipping of Ti-6Al-4V substrate with TiO2 layer into HA sol, followed by heat-treatment at different temperatures...
Hydrogen, nitrogen and carbon dioxide production through chemical looping using iron-based oxygen carrier - A Green plant for H2 and N 2 production
, Article International Journal of Hydrogen Energy ; Vol. 39, issue. 20 , 2014 , pp. 10380-10391 ; ISSN: 03603199 ; Mansoori, Z ; Dabir, B ; Shahnazari, A ; Sharif University of Technology
2014
Abstract
In order to simulate the performance of pure methane in chemical looping using iron-based oxygen carrier, simultaneously production of three pure streams of hydrogen, nitrogen and carbon dioxide has been investigated. For this purpose, proper operating conditions have been discussed for maximum production of hydrogen, complete consumption of oxygen of inlet air and complete combustion of methane. Professional software is used to simulate the chemical looping reactors and optimize their output streams. Results show that in this process each mole of methane fuel can produce 2.533, 2.65 and 0.99 mol of pure N 2, H2 and CO2, respectively which contributes 80.2% energy conversion of CH4 to H2....
COD and ammonia removal from landfill leachate by UV/PMS/Fe2+ process: ANN/RSM modeling and optimization
, Article Process Safety and Environmental Protection ; Volume 159 , 2022 , Pages 716-726 ; 09575820 (ISSN) ; Mozaffarian, M ; Dabir, B ; Ramezani, S. F ; Sharif University of Technology
Institution of Chemical Engineers
2022
Abstract
Landfill leachate is a highly contaminated liquid generated in municipal solid waste landfills. The application of sulfate radical-based advanced oxidation processes (SR-AOP) in landfill leachate treatments is emerging due to their ability to degrade both organic refractory matters and ammonia nitrogen. In this paper, application of peroxymonosulfate (PMS), activated by Fe2+ and UV was used as an economical and environmentally friendly approach for treatment of landfill leachate. Chemical oxygen demand (COD) and ammonia removals were measured as the two primary responses of landfill leachate to UV/PMS/Fe2+ treatment system. The main parameters (pH, PMS/Fe2+ mass ratio, Fe2+ dosage) affecting...
Investigation of asphaltene precipitation in miscible gas injection processes: Experimental study and modeling
, Article Brazilian Journal of Chemical Engineering ; Volume 29, Issue 3 , 2012 , Pages 665-676 ; 01046632 (ISSN) ; Dabiri, M ; Dabir, B ; Rashtchian, D ; Emadi, M. A ; Sharif University of Technology
2012
Abstract
Asphaltene precipitation during natural depletion and miscible gas injection is a common problem in oilfields throughout the world. In this work, static precipitation tests are conducted to investigate the effects of pressure, temperature and gas type and concentration on asphaltene instability. Three different oil samples have been studied under reservoir conditions with/without nitrogen and methane injection. Besides applying common thermodynamic models, a new scaling equation is presented to predict asphaltene precipitation under HPHT gas injection. Extensive published data from the literature are also used in model development. The scaling approach is attractive because it is simple and...
Application of population balance equation in modeling of asphaltene particle size distribution and characterization of aggregation mechanisms under miscible gas Injection
, Article Journal of Molecular Liquids ; Volume 232 , 2017 , Pages 207-213 ; 01677322 (ISSN) ; Hamed Mahvelati, E ; Ameli, F ; Dabir, B ; Rashtchian, D ; Sharif University of Technology
Elsevier B.V
2017
Abstract
Particle size distribution (PSD) is an important factor that determines how asphaltene instability can damage porous media during natural depletion and enhanced oil recovery processes. In this work, aggregate size distribution under natural depletion and miscible nitrogen injection processes are determined via image analysis techniques and the results are modelled by population balance equation. Unimodal distribution curves in natural depletion show the dominance of particle-particle aggregation mechanism and the clustering is detected only around crude oil bubble point pressure. It is also observed that miscible nitrogen injection considerably increases the number and size of asphaltene...
An integrated approach for predicting asphaltenes precipitation and deposition along wellbores
, Article Journal of Petroleum Science and Engineering ; Volume 203 , 2021 ; 09204105 (ISSN) ; Husein, M. M ; Ghotbi, C ; Taghikhani, V ; Dabir, B ; Sharif University of Technology
Elsevier B.V
2021
Abstract
Deposition of asphaltenes upon precipitation is a main flow assurance concern, which propelled the development of various experimental and modeling techniques to accurately predict its occurrence. This work develops an integrated approach combining thermodynamic and deposition modules with a multiphase flow simulator to simultaneously model asphaltenes precipitation and deposition in wellbores. The Peng-Robinson equation of state and the modified Miller-Flory-Huggins theory are used to calculate the thermodynamic properties of the oil and asphaltenes precipitation, respectively. The deposition module is based on conservation laws for asphaltenes transport and is linked to the flow simulator...
In-depth characterization of light, medium and heavy oil asphaltenes as well as asphaltenes subfractions
, Article Fuel ; Volume 324 , 2022 ; 00162361 (ISSN) ; Husein, M. M ; Ghotbi, C ; Dabir, B ; Taghikhani, V ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
Asphaltenes, and their related issues, have been the focus of many literature investigations. However, in-depth analysis of asphaltenes structure and its relation to asphaltenes stability has been considered by fewer studies. In this research, extensive analysis of the structure of asphaltenes extracted from light, medium, and heavy oils is provided, together with analysis of three subfractions of the medium oil asphaltene having the least, intermediate, and highest solubilities. To this end, elemental analysis, EDX, mass spectroscopy, FTIR, NMR, XRD, and SEM results were collected. Higher hydrogen content and hydrogen/carbon atomic ratio, lower aromatic nature and olefinic entities were...
A statistical inference approach for the identification of dominant parameters in immiscible nitrogen injection
, Article Energy Sources, Part A: Recovery, Utilization and Environmental Effects ; Vol. 36, Issue. 12 , 2014 , Pages 1285-1295 ; ISSN: 15567036 ; Ghazvini, M. G ; Dabir, B ; Emadi, M. A ; Rashtchian, D ; Sharif University of Technology
2014
Abstract
Screening analysis is a useful guideline that helps us with proper field selection for different enhanced oil recovery processes. In this work, reservoir simulation is combined with experimental design to estimate the effect of reservoir rock and fluid properties on performance of immiscible nitrogen injection. Reservoir dip, thickness, and horizontal permeability are found to be the most influential parameters. Possible interactions of parameters are also discussed to increase reliability and robustness of screening results. Finally, significance of both main effects and interactions are evaluated by employing a statistical inference approach (hypothesis testing) and results are compared to...
Experimental investigation and modeling of asphaltene precipitation due to Gas Injection
, Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 31, Issue 1 , 2012 , Pages 89-98 ; 10219986 (ISSN) ; Rashtchian, D ; Ganjeh Ghazvini, M ; Emadi, M. A ; Dabir, B ; Sharif University of Technology
2012
Abstract
Asphaltene instability is one of the major problems in gas injection projects throughout the world. Numerous models have been developed to predict asphaltene precipitation; The scaling equation is an attractive tool because of its simplicity and not involving complex properties of asphaltene. In this work, a new scaling model is presented to account for asphaltene precipitation due to gas injection at reservoir conditions. Extensive published data from literature have been used in model preparation. To check predictive capability of the equation, miscible gas injection experiments are conducted for a southwest Iranian oil reservoir. Experimental results show that methane injection has...
Investigating the Effect of Asphaltene Flocculation Size on Deposition
, M.Sc. Thesis Sharif University of Technology ; Ghotbi, Siros (Supervisor) ; Ayatollahi, Shahabodin (Supervisor) ; Dabir, Bahram (Co-Advisor)
Abstract
Asphaltene precipitation and deposition are sources of a number of problems for petroleum industry. Thus, solving the problem of precipitation and deposition is very important. In order to measure deposition level, study of other asphaltene flocculation is vital; since there is a time interval between precipitation and deposition. Use of chemical inhibitors is one of the best methods for prevention of asphaltene precipitation that could postpone precipitation point and prevent formation of huge flocculations. In this study, effects of asphaltene flocculation size on deposition with or without using inhibitors were investigated. In this regard, QCM was used for measuring the amount of...
Comprehensive study of asphaltene precipitation due to gas injection: Experimental investigation and modeling
, Article Society of Petroleum Engineers - SPE Enhanced Oil Recovery Conference 2011, EORC 2011, 19 July 2011 through 21 July 2011 ; Volume 1 , July , 2011 , Pages 208-219 ; 9781618390929 (ISBN) ; Moradi, S ; Dabir, B ; Emadi, M. A ; Rashtchian, D ; Sharif University of Technology
2011
Abstract
Asphaltene precipitation during natural depletion and miscible gas injection is a common problem in oilfields throughout the world. In this work, static precipitation tests are conducted to investigate effect of pressure, temperature and gas type and concentration on asphaltene instability. Three different oil samples are studied under reservoir conditions with/without nitrogen and methane injection. Besides applying common thermodynamic models, a new scaling equation is presented to predict asphaltene precipitation under HPHT gas injection. Published data from literature are also used in model development. The scaling approach is attractive because it is simple and complex asphaltene...
Effect of Nitrogen Injection on Phase Behavior and Asphaltene Instability
, Ph.D. Dissertation Sharif University of Technology ; Rashtchian, Davood (Supervisor) ; Dabir, Bahram (Supervisor) ; Emadi, Mohammad Ali (Supervisor)
Abstract
Nitrogen injection is a promising enhanced oil recovery process. Asphaltene precipitation during miscible gas injection is a common problem in oilfields throughout the world. In this work, a comprehensive study is conducted on effect of gas injection on phase behavior and asphaltene instability of live oil samples. Effects of oil API, gas type and concentration, pressure and temperature are studied under natural depletion and nitrogen injection processes by means of high pressure filtration and a photographic procedure coupled with image analysis. Filtration results show that nitrogen destabilizes asphaltenes more compared to methane and the problem is more severe for heavier crude samples....
Dynamic Modeling and Experimental Study of Asphaltene Deposition in Wellbore Considering Mechanism of Precipitation, Aggregation and Deposition
,
Ph.D. Dissertation
Sharif University of Technology
;
Ghotbi, Cyrus
(Supervisor)
;
Dabir, Bahram
(Co-Supervisor)
;
Taghikhani, Vahid
(Co-Supervisor)
Abstract
Efforts to identify, predict, and resolve problems linked to asphaltenes and flow assurance have resulted in the development of numerous laboratory and modelling techniques. However, there has been little research on the molecular structure of asphaltenes and how it relates to solubility, stability, aggregation, and deposition behavior. Not only was a thorough structural analysis of asphaltene extracted from three samples of light, medium, and heavy oil performed in this study, but medium oil asphaltene was also fractionated into three sub-fractions based on solubility, with minimum, medium, and maximum solubility, and each subfraction was subjected to a structural analysis. All asphaltene...
Photoelectrochemical water-splitting using CuO-Based electrodes for hydrogen production: a review
, Article Advanced Materials ; Volume 33, Issue 33 , 2021 ; 09359648 (ISSN) ; Hosseini Hosseinabad, S. M ; Masudy Panah, S ; Seza, A ; Jalali, M ; Fallah Arani, H ; Dabir, F ; Gholipour, S ; Abdi, Y ; Bagheri Hariri, M ; Riahi Noori, N ; Lim, Y. F ; Hagfeldt, A ; Saliba, M ; Sharif University of Technology
John Wiley and Sons Inc
2021
Abstract
The cost-effective, robust, and efficient electrocatalysts for photoelectrochemical (PEC) water-splitting has been extensively studied over the past decade to address a solution for the energy crisis. The interesting physicochemical properties of CuO have introduced this promising photocathodic material among the few photocatalysts with a narrow bandgap. This photocatalyst has a high activity for the PEC hydrogen evolution reaction (HER) under simulated sunlight irradiation. Here, the recent advancements of CuO-based photoelectrodes, including undoped CuO, doped CuO, and CuO composites, in the PEC water-splitting field, are comprehensively studied. Moreover, the synthesis methods,...
Nonlinear interstory drift contours for idealized forward directivity pulses using "modified fish-bone" models
, Article Advances in Structural Engineering ; Volume 18, Issue 5 , May , 2015 , Pages 603-627 ; 13694332 (ISSN) ; Khosravi, H ; Jamnani, H. H ; Sharif University of Technology
Multi-Science Publishing Co. Ltd
2015
Abstract
Four 5-, 10-, 20- and 30-story moment frames, representing low-, mid-, and two high-rise structures, were subjected to a great number of idealized directivity pulses. The amplitudes and periods of pulses vary from 0.02 g to 1.0 g and 0.5 to 12 sec, respectively. Over 1400 nonlinear dynamic analyses of low- to high-rise moment frames were performed which were feasible through using modified fish-bone model. The distribution of interstory drift along the height was studied and two applied contours were proposed: (i) the maximum interstory drift contour, and (ii) the critical story contour. These contours were demonstrated versus the ratio of natural period of the structure to the pulse period...
Analysis of singularities of a 3DOF parallel manipulator based on a novel geometrical method
, Article 8th Biennial ASME Conference on Engineering Systems Design and Analysis, ESDA2006, Torino, 4 July 2006 through 7 July 2006 ; Volume 2006 , 2006 ; 0791837793 (ISBN); 9780791837795 (ISBN) ; Sadeghian, H ; Roozbehani, H ; Zohoor, H ; Sharif University of Technology
2006
Abstract
In this article singular points of a parallel manipulator are obtained based on a novel geometrical method. Here we introduce the constrained plain method (CPM) and some of its application in parallel mechanism. Given the definition of constraint plane (CP) and infinite constraint plane (ICP) the dependency conditions of constraints is achieved with the use of a new theorem based on the Ceva geometrical theorem. The direction of angular velocity of a body is achieved by having three ICPs with the use of another theorem. Finally, with the use of the above two novel theorems singularities of the 3UPF_PU mechanism are obtained. It should be emphasized that this method is completely geometrical,...
Melting enthalpy and entropy of freestanding metallic nanoparticles based on cohesive energy and average coordination number
, Article Journal of Physical Chemistry C ; Volume 115, Issue 35 , August , 2011 , Pages 17310-17313 ; 19327447 (ISSN) ; Delavari H., H ; Madaah Hosseini, H. R ; Sharif University of Technology
2011
Abstract
An analytical model is proposed to study the effect of particle size on melting enthalpy and entropy of metallic nanoparticles (NPs). The Mott's and Regel's equations for melting entropy in the combination of core average coordination number (CAC) and surface average coordination number (SAC) of freestanding NPs are considered. Clusters of icosahedral (IC), body centered cubic (BCC), and body centered tetragonal (BCT) structure without any vacancies and defects are modeled. Using the variable coordination number made this model to be in good agreement with experimental and molecular dynamic (MD) results of different crystal structures. The model predicts melting entropy and enthalpy of...