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Investigation of mechanical properties, antibacterial features, and water vapor permeability of polyvinyl alcohol thin films reinforced by glutaraldehyde and multiwalled carbon nanotube
, Article Polymer Composites ; Vol. 35,Issue. 9 , 2014 , pp. 1736-1743 ; ISSN: 1548-0569 ; Kavoosi, G ; Mohammad Ali Dadfar, S ; Sharif University of Technology
2014
Abstract
Polyvinyl alcohol (PVA) thin films were reinforced by glutaraldehyde and multiwalled carbon nanotubes (MWCNTs) and then mechanical, water solubility, water swelling, water uptake, water vapor permeability, and antibacterial properties of the films were examined. Cross-linking by glutaraldehyde or incorporation of MWCNT caused a significant increase in tensile strength, decrease in elongation at break, and increase in Young's modulus of the PVA films, while MWCNTs were more effective rather than that of glutaraldehyde. Cross-linking by glutaraldehyde or incorporation of MWCNT caused a significant decrease in water solubility, water swelling and water uptake, with a similar manner....
Investigation of oxygen barrier properties of organoclay/HDPE/EVA nanocomposite films prepared using a two-step solution method
, Article Polymer Composites ; Volume 30, Issue 6 , 2009 , Pages 812-819 ; 02728397 (ISSN) ; Ramezani Saadat Abadi, A ; Dadfar, M. A ; Sharif University of Technology
2009
Abstract
In this article, oxygen barrier properties of nanocomposite films composed of organoclay (OC), high-density polyethylene (HDPE), and ethylene vinyl acetate (EVA) copolymer have been investigated. The nanocomposite films whose EVA forms a dominant fraction were prepared using the solution method. The dispersion of the OC in the HDPE/EVA blend was improved through taking two-step procedure in the preparation of nanocomposite. First, the OC and EVA were dissolved in chloroform. Then, the resulting product, after evaporating most of the solvent, along with HDPE was dissolved in xylene. The obtained nanocomposite films underwent a number of tests in order to examine their barrier properties...
Antioxidant, antifungal, water binding, and mechanical properties of poly(vinyl alcohol) film incorporated with essential oil as a potential wound dressing material
, Article Journal of Applied Polymer Science ; Vol. 131, issue. 20 , 2014 ; Nateghpoor, B ; Dadfar, S. M. M ; Dadfar, S. M. A ; Sharif University of Technology
2014
Abstract
In this study, the properties of poly (vinyl alcohol)(PVA) films incorporated with Zataria multiflora essential oil (ZMO) as a potential antioxidant/antibacterial material was investigated. PVA films were prepared from PVA solutions (2% w/v) containing different concentrations of ZMO. Water solubility, moisture absorption, water swelling, and water vapor permeability for pure PVA films were 57 ± 1.1, 99 ± 3.2%, 337 ± 8%, and 0.453 ± 0.015 g mm/m2 h, respectively. Incorporation of ZMO into PVA films caused a significant decrease in water swelling and moisture absorption and increase in solubility and water vapor permeability. Tensile strength, elastic modulus, and elongation at break for pure...
Studies on the oxygen barrier and mechanical properties of low density polyethylene/organoclay nanocomposite films in the presence of ethylene vinyl acetate copolymer as a new type of compatibilizer
, Article Materials and Design ; Volume 32, Issue 4 , 2011 , Pages 1806-1813 ; 02641275 (ISSN) ; Alemzadeh, I ; Reza Dadfar, S. M ; Vosoughi, M ; Sharif University of Technology
2011
Abstract
Nanocomposite films based on low density polyethylene (LDPE), containing of 2, 3, and 4. wt.% organoclay (OC) and ethylene vinyl acetate (EVA) copolymer as a new compatibilizer were prepared and characterized using rheological tests, X-ray diffraction, differential scanning calorimetry, oxygen permeation measurements, and tensile tests. There was no exfoliation or intercalation of the clay layers in the absence of EVA, while an obvious increase in d-spacing was observed when the samples were prepared with EVA present. This issue was reflected in the properties of nanocomposites. The oxygen barrier properties of the LDPE/EVA/OC film were significantly better than those of the LDPE/OC film....
Production and Investigation of Properties of a Nanocomposite for Food Packaging
, M.Sc. Thesis Sharif University of Technology ; Alemzadeh, Iran (Supervisor) ; Vossoughi, Manuchehr (Supervisor)
Abstract
Nanocomposite films based on low density polyethylene (LDPE), containing of 2, 3, and 4 wt% organoclay (OC) and ethylene vinyl acetate (EVA) copolymer as a new compatibilizer were prepared and characterized using X-ray diffraction, tensile tests, and oxygen permeation measurements. There was no exfoliation or intercalation of the clay layers in the absence of EVA, while an obvious increase in d-spacing was observed when the samples were prepared with EVA present. This issue was reflected in the properties of nanocomposites. The oxygen barrier properties of the OC/EVA/LDPE film were significantly better than those of the OC/LDPE film. The average aspect ratio of clay platelets in...
Effect of different configurations on 3-D analysis of flow through stay vanes And guide vanes of a francis turbine
, Article Scientia Iranica ; Volume 17, Issue 6 B , NOVEMBER-DECEMBER , 2010 , Pages 419-432 ; 10263098 (ISSN) ; Firoozabadi, B ; Ahmadi, G ; Sharif University of Technology
2010
Abstract
Stay and guide vanes (distributor) are essential parts of a turbine. They are used to control the flow rate and to appropriately transfer the flow momentum to the runner. In this work, flow through the distributor is analyzed. For various Boundary Conditions (BC) and different configurations, threedimensional flows in the distributor of a Francis turbine are evaluated and compared with each other. The numerical simulations were carried out using Fluent software and the results were validated with a GAMM Francis turbine, where the geometry and detailed best efficiency measurements were publically available. In these simulations, the flow was assumed to be steady and the effect of turbulence...
Modification of carbohydrate polymers via grafting in air. 1. Ceric-Induced synthesis of starch-g-polyacrylonitrile in presence and absence of oxygen [electronic resource]
, Article Starch - Starke ; Volume 54, Issue 3-4, pages 140–147, April 2002 ; Zohurian Mehr, Mohammad J
Abstract
Monomer grafting, a unique technique for polysaccharide modification, is always performed under inert (e.g., N2) atmosphere. This work is the first report related to evaluating the possibility and efficiency of the grafting of acrylonitrile (AN) onto starch in presence of oxygen. Thus, corn starch (in both granular and gelatinized states) as well as soluble starch were grafted by AN using a ceric-carbohydrate redox initiating system. Graft copolymerizations were performed under nitrogen, air, and oxygen atmospheres at similar conditions. Grafting occurrence was verified using chemical and spectral proofs. The polymerization mechanism and kinetics were investigated by recording the...
Modification of carbohydrate polymers via grafting in Air. 2. Ceric-Initiated graft copolymerization of acrylonitrile onto natural and modified polysaccharides [electronic resource]
, Article Starch - Stärke ; Volume 54, Issue 10, pages 482–488, October 2002 ; Zohuriaan-Mehr, Mohammad J
Abstract
Acrylonitrile (AN) was grafted onto various natural and modified polysaccharides (i.e., gum arabic, gum tragacanth, xanthan gum, sodium alginate, chitosan, sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose) by using ceric-carbohydrate redox initiating system. After overcoming practical problems, mainly from the high viscosity of the aqueous solutions of the different substrates, the graft copolymerization reactions were run either in air or in N2 atmosphere under similar conditions. Grafting was confirmed using chemical and spectral (FTIR) proofs. The reactions were kinetically investigated using semi-empirical expressions and time-temperature profiles. An anomalous...
Modeling of in Plane Behavior of Retrofitted Adobe Walls with Finite Element Method under Cyclic Loading
, M.Sc. Thesis Sharif University of Technology ; Bakhshi, Ali (Supervisor) ; Ghannad, Mohammad Ali (Co-Advisor)
Abstract
Statistical studies indicate the fact that in Iran, like many other developing countries, a significant percentage of buildings are made of traditional materials and most of them are adobe buildings especially in rural areas. Furthermore, geological data indicates that Iran is located in alps-Himalayas seismic zone and exposed by destructive earthquakes and adobe buildings suffer the most damages comparing with other type of the structures. According to these explanations, this research deals with adobe buildings behavior and provides solutions for reinforcing them and improving the seismic response of these buildings. These studies include numerical modeling with finite elements methods by...
Silica chloride/wet SiO2 as a novel heterogeneous system for the deprotection of acetals under mild conditions [electronic resource]
, Article Phosphorus, Sulfur, and Silicon and the Related Elements ; Volume 178:2667-2670, Issue 12, 2003 ; Pourjavadi, Ali ; Zolfigol, Mohammad Ali ; Bamoniri, Abdolhamid
Abstract
A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition
Lower extremity kinematic coupling during single and double leg landing and gait in female junior athletes with dynamic knee valgus
, Article BMC Sports Science, Medicine and Rehabilitation ; Volume 13, Issue 1 , 2021 ; 20521847 (ISSN) ; Sheikhhoseini, R ; Jafarian, M ; Esmaeili, A ; Sharif University of Technology
BioMed Central Ltd
2021
Abstract
Background: Dynamic knee valgus (DKV) is a common lower extremity movement disorder among females. This study aimed to investigate kinematic couplings between lower extremity joints in female junior athletes with DKV during single and double-leg landing and gait. Methods: Twenty-six physically active female junior athletes (10–14 years old) with DKV were recruited. Kinematic couplings between rearfoot, tibia, knee, and hip were extracted using eight Vicon motion capture cameras and two force plates. Zero-lag cross-correlation coefficient and vector coding were used to calculate kinematic couplings between joints during physical tasks. Paired t-test and Wilcoxon tests were run to find...
Distributed Fault-tolerant Computation for Massive Data
, M.Sc. Thesis Sharif University of Technology ; Maddah-Ali, Mohammad Ali (Supervisor)
Abstract
In this thesis we consider the problem of distributed computation by many processors.We mainly concentrate on matrix multiplication problem in this thesis because of its importance. A distributed system consists of N worker processors and one master processor. The master processor should distribute the computation between workers and after computation in each of them, collect the results. In this thesis, we are going to mitigate the effect of straggler processors by using coding methods. Straggler processors can cause delays in the computation time.In this thesis, we firstly introduce a method to multiply any number of matrices in each other. The proposed method occurred in one shot without...
Incomplete Reduction of Iron Ore in a Fluidized Bed Reactor
, M.Sc. Thesis Sharif University of Technology ; Halali, Mohammad (Supervisor)
Abstract
The main goal of current investigation was partial reduction of Fe2O3 available in Hematite-rich ore to Magnetite by Fludization Bed method. The reductive gas, CO, was produced by incomplete combustion of Acetylene and Airmixed in inappropriate ratio. X-Ray Diffraction and X-Ray Florescence analyses were implemented in order to conducting qualitative analysis of present phases before and after reduction of the ore. Quantitative analysis of the same phases was also conducted by Titration. The latter analysis revealed the precise magnitude of available iron in each of the oxide containing phases. The chemical composition of the reactor gas was also determined before and after reduction...
Sequential Competitive Facility Location In Continuous Geometric Space
, M.Sc. Thesis Sharif University of Technology ; Abam, Mohammad Ali (Supervisor)
Abstract
Abstract The problem of competetive facility location can be defined as follows: There are a number of customers in the form of points in space, and two players arrange a number of facilities in the form of points in space, given some limitations, respectively. Each customer’s connection to each facility has a cost for the customer and an advantage for the facility, and each customer wants to be connected to at most one of the facilities which has the lowest cost for him. The goal is to find the strategy of placing the facilities and determining the cost which the facility receives from the customer, in such a way that the player’s profit is maximised.In this thesis, we first sought to...
Distributed Verifiable Computing: Algorithms and Analysis
, M.Sc. Thesis Sharif University of Technology ; Maddah Ali, Mohammad Ali (Supervisor)
Abstract
Zero knowledge proofs allow a person (prover) to convince another person (verifier) that he has performed a specific computation on a secret data correctly, and has obtained a true answer, without having to disclose the secret data. QAP (Quadratic Arithmetic Program) based zkSNARKs (zero knowledge Succinct Non-interactive Argument of Knowledge) are a type of zero knowledge proof. They have several properties that make them attractive in practice, e.g. verifier's work is very easy. So they are used in many areas such as Blockchain and cloud computing. But yet prover's work in QAP based zkSNARKs is heavy, therefore, it may not be possible for a prover with limited processing resource to run...
Privacy Preserving Communication Schemes for Light Clients in Blockchain Networks: Algorithms and Analysis
, M.Sc. Thesis Sharif University of Technology ; Pakravan, Mohammad Reza (Supervisor) ; Maddah Ali, Mohammad Ali (Co-Supervisor)
Abstract
Lightweight clients are a type of blockchain users who do not store all the blocks in the blockchain due to limited resources. These users store only a small part of each block and when needed, request transactions from full nodes that store the entire blockchain. These users have no role in block validation and only want to receive transactions related to their addresses with proof of the inclusion in the block from full nodes.Since light clients rely on full nodes for receiving transactions, their privacy against full nodes is important. The current implementation of Bitcoin uses Bloom filters for privacy, but this offers very little privacy to the users.In this thesis, we study the...
Power System Load Frequency Control Considering Renewable Energy Sources
, M.Sc. Thesis Sharif University of Technology ; Ranjbar, Ali Mohammad (Supervisor)
Abstract
Power system frequency regulation entitled load frequency control (LFC) has been one of the important control problems in electric power system design and operation. Off-normal frequency can directly impact on power system operation and system reliability. A large frequency deviation can damage equipment, degrade load performance, cause the transmission lines to be overloaded and can interfere with system protection schemes, ultimately leading to an unstable condition for the power system . On the other hand, the increasing need for electrical energy in the 21st century, as well as limited fossil fuel reserves and the increasing concerns with environmental issues for the reduction of carbon...
Perusing Metal Perusing Metal Insulator Transistors with in the Dynamical Field Approximation at Finite Temperature
, Ph.D. Dissertation Sharif University of Technology ; Vesaghi, Mohammad ALi (Supervisor)
Abstract
The aim of this work is to investigate some theoretical models developed in recent years for describing electronic correlation and apply them to some special problems and metallicity and insulating behavior of one type of paramagnetic systems. One of the vast‐applied and effective routines for investigating the strongly correlated electron systems is Dynamical Mean Field Theory (DMFT). In the first part, the equations of DMFT are solved on nearly real frequency axis with a effective and more reliable solver a little parameter γ above the real axis. This approach appears fine structures that can’t be captured with the ...
On a Bounded Budget Network Creation Game
, M.Sc. Thesis Sharif University of Technology ; Safari, Mohammad Ali (Supervisor)
Abstract
In this thesis, we consider a network creation game in which, each player (vertex) has a limited budget to establish links to other players. In our model, each link has a unit cost and each agent tries to minimize its cost which is its local diameter or its total distance to other players in the (undirected) underlying graph of the created network. Two variants of the game are studied: in the MAX version, the cost incurred to a vertex is the maximum distance between that vertex and other vertices, and in the SUM version, the cost incurred to a vertex is the sum of distances between that vertex and other vertices. We prove that in both versions pure Nash equilibria exist, but the problem of...
Pushover Analysis for Soil-Structure Systems
, M.Sc. Thesis Sharif University of Technology ; Ghannad, Mohammad Ali (Supervisor)
Abstract
Controlling damage level of structures for an earthquake with certain intensity is the main purpose in seismic performance based design. This is done by estimating and confining the structure displacements and related global and local response parameters. Even though nonlinear time history analysis method is the most exact method for predicting seismic behavior of structures, but its application is limited because of being complex. Nonlinear static analysis procedure (Pushover analysis) which is based on analyzing the structure subjected to the incremental lateral load is an alternative method that has been recommended by recent structural codes. In order to consider the soil-structure...