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    Silica-supported DABCO-tribromide: A recoverable reagent for oxidation of alcohols to the corresponding carbonyl compounds

    , Article Scientia Iranica ; Volume 20, Issue 3 , 2013 , Pages 598-602 ; 10263098 (ISSN) Moghaddam, F. M ; Masoud, N ; Foroushani, B. K ; Saryazdi, S ; Ghonouei, N ; Daemi, E ; Sharif University of Technology
    2013
    Abstract
    In this study, 1,4-diazabicy lo[2.2.2] octane (DABCO) tribromide was immobilized on silica support by using 3-chloro propyl trimethoxy silane to obtain a silica-supported DABCO tribromide reagent. The synthesized reagent was characterized with elemental analysis, FT-IR spectroscopy, and thermo-gravimetric analysis (TGA). This reagent has been applied in the conversion of alcohol to corresponding carbonyl compounds. Alcohol oxidation reactions yield in 52-95%, and the reagent may be recycled five times with further bromine treatment  

    A Finite Element Study on Seismic Behavior of Various Concrete Column Retrofitting Methods

    , M.Sc. Thesis Sharif University of Technology Daemi, Atieh (Author) ; Khaloo, Alireza (Supervisor)
    Abstract
    In recent years, in order to investigate the structural performance in seismic zones, concrete column reinforcement and observing their behavior under cyclic loading have attracted considerable attentions. The ductility and energy absorption capability of structure play an important role in structural performance against earthquake and consequently its failure patterns. A new chapter of these investigations has begun by the reinforcement of the concrete members, a major part of which is concerned with the confinement of concrete members in order to increase their ductility and energy absorption against the forces induced by earthquake. In this study, three prominent methods of concrete... 

    Synthesis and Characterization of a Metal-Organic Molecular Cage with Anthracene Derivative Linkers and the Study of its Host-Guest Chemistry

    , M.Sc. Thesis Sharif University of Technology Daemi, Zohreh (Author) ; Jamali, Sirous (Supervisor)
    Abstract
    Through the bromination reaction of anthracene, the compound 9,10-dibromoanthracene (1) was synthesized. Subsequently, using a Suzuki coupling mechanism and the pinacol ester of 4-pyridineboronic acid, the ligand 9,10-bis(4-pyridyl)anthracene (2) was obtained. A cubic molecular cage [(PtMe3)8(9,10-bis(4-pyridyl)anthracene)12][OTf]8 (5) with trimethylplatinum(IV) (PtMe3) vertices and anthracene-based linkers was synthesized from the reaction of [PtMe3I]4 (3) with 9,10-bis (4-pyridyl)anthracene(2) linker in the presence of AgOTF (OTf = trifluoromethanesulfonate) in a 1:6 molar ratio. The structure of 5 was characterized by NMR spectroscopy in solution state. The ratio of aromatic to aliphatic... 

    Constructing the Bayesian network for components reliability importance ranking in composite power systems

    , Article International Journal of Electrical Power and Energy Systems ; Volume 43, Issue 1 , 2012 , Pages 474-480 ; 01420615 (ISSN) Daemi, T ; Ebrahimi, A ; Fotuhi Firuzabad, M ; Sharif University of Technology
    2012
    Abstract
    In this paper, Bayesian Network (BN) is used for reliability assessment of composite power systems with emphasis on the importance of system components. A simple approach is presented to construct the BN associated with a given power system. The approach is based on the capability of the BN to learn from data which makes it possible to be applied to large power systems. The required training data is provided by state sampling using the Monte Carlo simulation. The constructed BN is then used to perform different probabilistic assessments such as ranking the criticality and importance of system components from reliability perspective. The BN is also used to compute the frequency and... 

    Study of acoustic bubble cluster dynamics using a lattice Boltzmann model

    , Article Chinese Physics B ; Volume 24, Issue 2 , 2015 ; 16741056 (ISSN) Daemi, M ; Taeibi-Rahni, M ; Massah, H ; Sharif University of Technology
    Institute of Physics Publishing  2015
    Abstract
    The search for the development of a reliable mathematical model for understanding bubble dynamics behavior is an ongoing endeavor. A long list of complex phenomena underlies the physics of this problem. In the past decades, the lattice Boltzmann method has emerged as a promising tool to address such complexities. In this regard, we have applied a 121-velocity multiphase lattice Boltzmann model to an asymmetric cluster of bubbles in an acoustic field. A problem as a benchmark is studied to check the consistency and applicability of the model. The problem of interest is to study the deformation and coalescence phenomena in bubble cluster dynamics, as well as the screening effect on an acoustic... 

    Energy Efficient Software Defined Networks

    , M.Sc. Thesis Sharif University of Technology Daemi, Nafiseh (Author) ; Hemmatyar, Ali Mohammad Afshin (Supervisor)
    Abstract
    With a growing concern on the considerable energy consumed by data centers, research efforts are targeting toward green data centers with higher energy efficiency. Networks are essential to today’s highly instrumented and connected society. Currently responsible for a fraction of the energy the IT sector consumes, networks rely on equipments that often use a constant amount of power regardless of their utilization; a worsening scenario as traffic is expected to increase by a factor of three in the next few years. Datacenter networks, for instance, employ devices that consume several kilowatts of power even when idle. This work aims to improve the energy efficiency of datacenter networks by... 

    Effects of liquid second viscosity in high-amplitude sonoluminescence

    , Article Chinese Physics Letters ; Volume 21, Issue 2 , 2004 , Pages 356-359 ; 0256307X (ISSN) Moshaii, A ; Sadighi Bonabi, R ; Taeibi Rahni, M ; Daemi, M ; Sharif University of Technology
    Allerton Press Inc  2004
    Abstract
    The well-known Rayleigh-Plesset (RP) equation is the base of nearly all hydrodynamical descriptions of the sonoluminescence phenomenon. A major deficiency of this equation is that it accounts for viscosity of an incompressible liquid and compressibility, separately. By removing this approximation, we have modified the RP equation, considering effects of liquid second viscosity. This modification exhibits its importance at the end of an intense collapse, so that the new model predicts the appearance of a new picosecond bouncing during high-amplitude sonoluminescence radiation. This new bouncing produces very sharp (sub-picosecond) peaks on the top of the sonoluminescence pulse. These new... 

    Numerical Simulation of Bubble Cluster Dynamics, Using Lattice Boltzmann Method

    , Ph.D. Dissertation Sharif University of Technology Daemi, Mahdi (Author) ; Tayyebi Rahni, Mohammad (Supervisor) ; Massah, Hamid Reza (Co-Advisor)
    Abstract
    Bubble cluster has attracted the interests of many researches since the early twentieth century. Despite its easy generation and numerous occurrences, its study is extremely complex. Describing the dynamical behavior of bubble clusters is possible when quite a few simplifying assumptions are utilized. In other words, one can observe that with current approaches, the relevant theoretical researches are not very valuable. In this research, however, lattice Boltzmann method, a rather recent mesoscopic approach, was used to study the behavior of bubbles in a bubble cluster. Of course, this is only the beginning and there is a long way before getting close to experimental results. However, there... 

    Planning screw insertion trajectory in lumbar spinal fusion using pre-operative CT images

    , Article Proceedings of the Annual International Conference of the IEEE Engineering in Medicine and Biology Society, EMBS, 25 August 2015 through 29 August 2015 ; Volume 2015-November , 2015 , Pages 3639-3642 ; 1557170X (ISSN) ; 9781424492718 (ISBN) Daemi, N ; Ahmadian, A ; Mirbagheri, A ; Ahmadian, A. H ; Saberi, H ; Amidi, F ; Alirezaie, J ; Sharif University of Technology
    Institute of Electrical and Electronics Engineers Inc  2015
    Abstract
    Spinal fusion permanently connects two or more vertebrae in spine to improve stability, correct a deformity or reduce pain by immobilizing the vertebrae through pedicle screw fixation. Pedicle screws should be inserted very carefully to prevent possible irrecoverable damages to the spinal cord. Surgeons use CT/fluoroscopic images to find how to insert the screws safely. However, there is still human error, as determining precise trajectory in 3D space is difficult because of asymmetric structure of pedicle. In this study we attempt to propose a shape based method to help the surgeons to find the more accurate and safe path for screw insertion that minimizes the risk or invasiveness of the... 

    Grid Homology and the Existence of Exotic Structures on R4

    , M.Sc. Thesis Sharif University of Technology Habibi Esfahani, Saman (Author) ; Moghaddasi, Reza (Supervisor) ; Eftekhari, Eaman (Supervisor) ; Daemi, Ali Akbar (Co-Advisor)
    Abstract
    Knot theory is the study of ambient isotopy classes of compact 1–manifolds in a 3-manifold. In classical knot theory this 3-manifold is R3 or S3. This field has experienced a great transformative advances in recent years because of its strong connections with and a number of other mathematical disciplines including topology of 3-manifolds and 4-manifolds, gauge theory, representation theory, categorification, morse theory, symplectic geometry and the theory of pseudo-holomorphic curves. In this thesis we start with classical knot theory, introducing some of its (classical) invariants like unknotting number, Seifert genus and slice genus of a knot, knot group and finally Alexander Polynomial... 

    Recent activities in science and technology and the progress of women in physics in the last three years in Iran

    , Article AIP Conference Proceedings, Stellenbosch ; Volume 1517 , 2013 , Pages 108-109 ; 0094243X (ISSN); 9780735411388 (ISBN) Izadi, D ; Azad, M. T ; Mahmoudi, N ; Izadipanah, N ; Eshghi, N ; Sharif University of Technology
    2013
    Abstract
    For the 4th IUPAP International Conference of Women in Physics, we report on activities in science and engineering in Iran, and conditions for women in physics, in the three years since the 3rd IUPAP International Conference of Women in Physics was held in 2008. Iran has made prominent advancements and astonishing progress in laser technology, biotechnology, nanotechnology, genetics, computer software and hardware, and robotics. Iranian scientists have been very productive in several experimental fields, such as pharmaceutical, organic, and polymer chemistry. Conditions for women in physics have improved greatly in recent years. A project to improve the environment for learning physics, and... 

    Lead-free MAGeI3 as a suitable alternative for MAPbI3 in nanostructured perovskite solar cells: a simulation study

    , Article Environmental Science and Pollution Research ; Volume 30, Issue 19 , 2023 , Pages 57032-57040 ; 09441344 (ISSN) Mehrabian, M ; Akhavan, O ; Rabiee, N ; Afshar, E. N ; Zare, E. N ; Sharif University of Technology
    Springer Science and Business Media Deutschland GmbH  2023
    Abstract
    The lead is a heavy metal with hazardous impacts on environment and human life. Lead-free perovskite solar cells have attracted much attention in recent years, due to eco-friendly characteristics. Meanwhile, Pb-containing cells showed the highest efficiencies among the various types of cells. Hence, designing novel Pb-free solar cells with comparable or better performance than the Pb-containing ones is highly required. In this work, a lead-free methyl-ammonium-germanium-iodide (MAGeI3)-based perovskite solar cell with ITO/TiO2/MAGeI3/Spiro-OMeTAD/Ag multilayer nanostructure has been proposed and its main characteristics including open-circuit voltage (VOC) and power conversion efficiency (η)... 

    Ab initio study of electronic effects in the ZnO/TiO2 core/shell interface: Application in dye sensitized solar cells

    , Article RSC Advances ; Vol. 4, issue. 1 , April , 2014 , p. 301-307 Pazoki, M ; Nafari, N ; Taghavinia, N ; Sharif University of Technology
    2014
    Abstract
    Core/shell structure of ZnO nanowires coated with a monolayer of TiO 2 is investigated using Density Functional Theory (DFT). The electronic states of the semiconductor is calculated and compared before and after coating of the TiO2 monolayer on a ZnO [101 0] surface. The effect of TiO2 coating induce surface states changes and shifts the conduction and valence band edges to higher energies. Our results, in qualitative agreement with the experimental work of Matt Law et al. (J. Phys. Chem. B, 110, 22652), show an increase in open circuit voltage and a decrease in short circuit current in ZnO/TiO2 core shell dye sensitized solar cells. Regarding the semiconductor density of states (DOS), TiO2... 

    Analyzing factors effective on the development of relationship commitment

    , Article Proceedings of the 2012 International Conference on Artificial Intelligence, ICAI 2012, 16 July 2012 through 19 July 2012 ; Volume 1 , July , 2012 , Pages 398-404 ; 1601322186 (ISBN) ; 9781601322180 (ISBN) Dehdashti, Y ; Lotfi, N ; Karami, N ; Sharif University of Technology
    2012
    Abstract
    Due to the important role of commitment and trust in the relationship marketing, the factors which can directly result in a committed relationship along with the factors which can influence the commitment through influencing trust, according to the model of commitment and trust by (Morgan & Hunt, 1994) have been introduced and their level of importance has been investigated here. The article uses fuzzy cognitive maps (FCMs) in the proposed model to find the most important paths leading to relationship commitment. The FCM analyzes the responses of a group of 30 people including general practitioners in dentistry, managers of dental departments in some of the public clinics and hospitals who... 

    Morphological dependence of light backscattering from metallic back reflector films: Application in dye-sensitized solar cells

    , Article Physica Status Solidi (A) Applications and Materials Science ; Volume 212, Issue 4 , January , 2015 , Pages 785-790 ; 18626300 (ISSN) Sharifi, N ; Ghazyani, N ; Taghavinia, N ; Sharif University of Technology
    Wiley-VCH Verlag  2015
    Abstract
    Conventionally, a film of TiO2 particles of 300 nm size is employed in Dye-sensitized solar cells (DSCs) as the back reflector film to enhance the light harvesting. Perfect reflectance of silver in visible and near infrared motivates to investigate its potential as the material for the light back reflector film in DSCs. In this study, light back reflector films consisting of 300 nm-sized silver particles, as well as vacuum evaporated silver flat film, were fabricated and compared to 300 nm-sized rutile-type TiO2 particulate reflector film to study their optical aspects. Conventional TiO2 rutile-type particulate film demonstrates slightly lower performance... 

    Monolithic dye sensitized solar cell with metal foil counter electrode

    , Article Organic Electronics ; Volume 57 , June , 2018 , Pages 194-200 ; 15661199 (ISSN) Behrouznejad, F ; Taghavinia, N ; Ghazyani, N ; Sharif University of Technology
    Elsevier B.V  2018
    Abstract
    Monolithic dye-sensitized solar cells are conventionally fabricated using carbon composite layer as the counter electrode. In the current research, the brittle carbon composite layer is replaced with a metal foil, aiming to decrease the device series resistance and using less catalyst material in counter electrode. This metallic structure has also an advantage of mechanical strength and decreases the fabrication complexity. The counter electrode is prepared by electrodepositing Cr film followed by electrodepositing Pt nanoparticles on a metal foil. As the porous spacer layer, different composite layers of SiO2, TiO2, and Al2O3 are investigated and the best results are obtained for TiO2... 

    A compact versatile microbial fuel cell from paper

    , Article ASME 2013 11th Int. Conf. on Fuel Cell Science, Eng. and Technology Collocated with the ASME 2013 Heat Transfer Summer Conf. and the ASME 2013 7th Int. Conf. on Energy Sustainability, FUELCELL 2013 ; 2013 ; 9780791855522 (ISBN) Wagner, L. T ; Hashemi, N ; Hashemi, N ; Sharif University of Technology
    2013
    Abstract
    Microbial fuel cells (MFCs) have been a potential green energy source for a long time but one of the problems is that either the technology must be used on a large scale or special equipment have been necessary to keep the fuel cells running such as syringe pumps. Paper-based microbial fuel cells do not need to have a syringe pump to run and can run entirely by themselves when placed in contact with the fluids that are necessary for it to run. Paper-based microbial fuel cells are also more compact than traditional MFCs since the device doesn't need any external equipment to run. The goal of this paper is to develop a microbial fuel cell that does not require a syringe pump to function. This... 

    Decentralized model predictive voltage control of islanded DC microgrids

    , Article 11th Power Electronics, Drive Systems, and Technologies Conference, PEDSTC 2020, 4 February 2020 through 6 February 2020 ; 2020 Abbasi, M ; Mahdian Dehkordi, N ; Sadati, N ; Sharif University of Technology
    Institute of Electrical and Electronics Engineers Inc  2020
    Abstract
    This paper proposes a novel decentralized control approach for islanded direct-current (DC) microgrids (MGs) based on model predictive control (MPC) to regulate the distributed generation unit (DGU) output voltages, i.e. the voltages of the point of common coupling (PCC). A local controller is designed for each DGU, in the presence of uncertainties, disturbances, and unmodeled dynamics. First, a discrete-time state-space model of an MG is derived. Afterward, an MPC algorithm is designed to perform the PCC voltage control. The proposed MPC scheme ensures that the PCC voltages remain within an acceptable range. Several simulation studies have been conducted to illustrate the effectiveness of... 

    Intelligent optimal feed-back torque control of a 6DOF surgical rotary robot

    , Article 11th Power Electronics, Drive Systems, and Technologies Conference, PEDSTC 2020, 4 February 2020 through 6 February 2020 ; 2020 Tajdari, F ; Ebrahimi Toulkani, N ; Zhilakzadeh, N ; Sharif University of Technology
    Institute of Electrical and Electronics Engineers Inc  2020
    Abstract
    Sophisticated surgeons are widely indicating the use of surgical robots in order to reject human error, increase precision, and speed. Among well-known robotic mechanisms, parallel robots are broadly more investigated regarding their special characters as higher acceleration, speed, and accuracy, and less weight. Specific surgical procedures confine, and restrict their workspace, while controlling and validating the robots are complicated regarding to their complex dynamic. To this end, in this paper, a 6-DOF robot, with rotary manipulators, is designed and controlled. Addressing nonlinearity of parallel robots, an innovative methodology is formulated to robustly penalize the error of... 

    Semi-Real evaluation, and adaptive control of a 6DOF surgical robot

    , Article 11th Power Electronics, Drive Systems, and Technologies Conference, PEDSTC 2020, 4 February 2020 through 6 February 2020 ; 2020 Tajdari, F ; Ebrahimi Toulkani, N ; Zhilakzadeh, N ; Sharif University of Technology
    Institute of Electrical and Electronics Engineers Inc  2020
    Abstract
    Sophisticated surgeons are widely indicating the use of surgical robots in order to reject human error, increase precision, and speed. Among well-known robotic mechanisms, parallel robots are broadly more investigated regarding their special characters as higher acceleration, speed, and accuracy, and less weight. Specific surgical procedures confine and restrict their workspace, while controlling and validating the robots are complicated based on their complex dynamic. To this end, in this paper, a 6-DOF robot, with linear manipulators, is designed and controlled. Addressing the inherent nonlinearity of the robot mechanism, an adaptive PID manipulator is employed and validated with nonlinear...