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daemi--zohreh
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A Finite Element Study on Seismic Behavior of Various Concrete Column Retrofitting Methods
, M.Sc. Thesis Sharif University of Technology ; Khaloo, Alireza (Supervisor)
Abstract
In recent years, in order to investigate the structural performance in seismic zones, concrete column reinforcement and observing their behavior under cyclic loading have attracted considerable attentions. The ductility and energy absorption capability of structure play an important role in structural performance against earthquake and consequently its failure patterns. A new chapter of these investigations has begun by the reinforcement of the concrete members, a major part of which is concerned with the confinement of concrete members in order to increase their ductility and energy absorption against the forces induced by earthquake. In this study, three prominent methods of concrete...
Synthesis and Characterization of a Metal-Organic Molecular Cage with Anthracene Derivative Linkers and the Study of its Host-Guest Chemistry
, M.Sc. Thesis Sharif University of Technology ; Jamali, Sirous (Supervisor)
Abstract
Through the bromination reaction of anthracene, the compound 9,10-dibromoanthracene (1) was synthesized. Subsequently, using a Suzuki coupling mechanism and the pinacol ester of 4-pyridineboronic acid, the ligand 9,10-bis(4-pyridyl)anthracene (2) was obtained. A cubic molecular cage [(PtMe3)8(9,10-bis(4-pyridyl)anthracene)12][OTf]8 (5) with trimethylplatinum(IV) (PtMe3) vertices and anthracene-based linkers was synthesized from the reaction of [PtMe3I]4 (3) with 9,10-bis (4-pyridyl)anthracene(2) linker in the presence of AgOTF (OTf = trifluoromethanesulfonate) in a 1:6 molar ratio. The structure of 5 was characterized by NMR spectroscopy in solution state. The ratio of aromatic to aliphatic...
Hydrazine-modified starch coated magnetic nanoparticles as an effective pH-responsive nanocarrier for doxorubicin delivery
, Article Journal of Industrial and Engineering Chemistry ; Volume 39 , 2016 , Pages 203-209 ; 1226086X (ISSN) ; Hosseini, S. H ; Pourjavadi, A ; Sharif University of Technology
Korean Society of Industrial Engineering Chemistry
2016
Abstract
A novel, magnetic nanocarrier was successfully synthesized through a facile and economical producer in which Fe3O4 magnetic nanoparticles were coated by starch-g-poly (methyl methacrylate-co-PEG-acrylamide). The surface of nanocarrier was then modified by hydrazine to preparation of a pH-responsive carrier. The resulted nanocarrier was applied for delivery of doxorubicin (DOX) as an effective anti-cancer drug. DOX was reacted with hydrazine linkage on the surface of nanocarrier to form hydrazone bond. Due to the presence of numerous hydrazine groups on the surface of magnetic nanocarrier large amounts of DOX was loaded onto the carrier (327 mg g−1). © 2016 The Korean Society of Industrial...
Constructing the Bayesian network for components reliability importance ranking in composite power systems
, Article International Journal of Electrical Power and Energy Systems ; Volume 43, Issue 1 , 2012 , Pages 474-480 ; 01420615 (ISSN) ; Ebrahimi, A ; Fotuhi Firuzabad, M ; Sharif University of Technology
2012
Abstract
In this paper, Bayesian Network (BN) is used for reliability assessment of composite power systems with emphasis on the importance of system components. A simple approach is presented to construct the BN associated with a given power system. The approach is based on the capability of the BN to learn from data which makes it possible to be applied to large power systems. The required training data is provided by state sampling using the Monte Carlo simulation. The constructed BN is then used to perform different probabilistic assessments such as ranking the criticality and importance of system components from reliability perspective. The BN is also used to compute the frequency and...
Study of acoustic bubble cluster dynamics using a lattice Boltzmann model
, Article Chinese Physics B ; Volume 24, Issue 2 , 2015 ; 16741056 (ISSN) ; Taeibi-Rahni, M ; Massah, H ; Sharif University of Technology
Institute of Physics Publishing
2015
Abstract
The search for the development of a reliable mathematical model for understanding bubble dynamics behavior is an ongoing endeavor. A long list of complex phenomena underlies the physics of this problem. In the past decades, the lattice Boltzmann method has emerged as a promising tool to address such complexities. In this regard, we have applied a 121-velocity multiphase lattice Boltzmann model to an asymmetric cluster of bubbles in an acoustic field. A problem as a benchmark is studied to check the consistency and applicability of the model. The problem of interest is to study the deformation and coalescence phenomena in bubble cluster dynamics, as well as the screening effect on an acoustic...
Cross-linked poly (dimethylaminoethyl acrylamide) coated magnetic nanoparticles: a high loaded, retrievable, and stable basic catalyst for the synthesis of benzopyranes in water
, Article RSC Advances ; Vol. 4, issue. 91 , 2014 , p. 50047-50055 ; Hosseini, S. H ; Pourjavadi, A ; Bennett, C ; Sharif University of Technology
2014
Abstract
A novel heterogeneous catalyst has been synthesized based on the distillation-precipitation-polymerization of methyl acrylate onto modified magnetic nanoparticles followed by the amidation of the methyl ester groups using N,N-dimethylethylenediamine. The resulting poly(dimethylaminoethyl acrylamide) coated magnetic nanoparticles (MNP@PDMA) catalyst was characterized using an array of sophisticated analytical techniques, including FT-IR, TGA, SEM, TEM, CHN, vibrating sample magnetometer (VSM), and XRD analysis. The resulting heterogeneous base catalyst allowed the performance of a domino Knoevenagel condensation/Michael addition/cycloaddition reaction toward the synthesis of...
Magnetic nanoparticles entrapped in the cross-linked poly(imidazole/imidazolium) immobilized Cu(ii): An effective heterogeneous copper catalyst
, Article RSC Advances ; Volume 4, Issue 87 , 2014 , Pages 46418-46426 ; ISSN: 20462069 ; Hosseini, S. H ; Zohreh, N ; Bennett, C ; Sharif University of Technology
2014
Abstract
Anchoring of copper sulfate in layered poly(imidazole-imidazolium) coated magnetic nanoparticles provided a highly stable, active, reusable, high loading, and green catalyst for the click synthesis of 1,2,3-triazoles via a one-pot cycloaddition of alkyl halide, azide, and alkyne (Cu-A3C). The catalyst was characterized by FTIR, TGA, TEM, SEM, XRD, EDAX, VSM and AAS. High selectivity, broad diversity of alkyl/benzyl bromide/chloride and alkyl/aryl terminal alkynes, and good to excellent yields of products were obtained using 0.7 mol% catalyst. The catalyst was readily recovered and reused up to 6 times without significant loss of activity
Synthesis & Properties of Nd-doped Glass-ceramics in the SiO2-CaO-MgO System from Sol-gel Method Used as Solid Lasers
,
M.Sc. Thesis
Sharif University of Technology
;
Hamnabard, Zohreh
(Supervisor)
;
Nemati, Ali
(Supervisor)
Abstract
In this study, SiO2-CaO-MgO galsses and glass-ceramic powder doped with Nd3+ were synthesized with sol-gel method. Tetraethylorthosilicate (TEOS), Ca(NO3)2.4H2O, Mg(NO3)2.6H2O, Nd(NO3)3.6H2O, ethanol, distilled water, and HNO3 were used as starting materials. The synthesized powder’s properties were examined with STA, XRD, DRS, PL, FTIR and SEM analysis. From XRD patterns of glass samples, the role of dopant was introduced as intermediate oxide in glass matrix. The XRD patterns of glass-ceramic samples indicated that the bredigite and akermanite crystals were formed in glass matrix. The band gap energy of samples were calculated from DRS analysis and were seen with increasing the dopant...
Energy Efficient Software Defined Networks
, M.Sc. Thesis Sharif University of Technology ; Hemmatyar, Ali Mohammad Afshin (Supervisor)
Abstract
With a growing concern on the considerable energy consumed by data centers, research efforts are targeting toward green data centers with higher energy efficiency. Networks are essential to today’s highly instrumented and connected society. Currently responsible for a fraction of the energy the IT sector consumes, networks rely on equipments that often use a constant amount of power regardless of their utilization; a worsening scenario as traffic is expected to increase by a factor of three in the next few years. Datacenter networks, for instance, employ devices that consume several kilowatts of power even when idle. This work aims to improve the energy efficiency of datacenter networks by...
Immobilized copper(II) on nitrogen-rich polymer-entrapped Fe3O4 nanoparticles: A highly loaded and magnetically recoverable catalyst for aqueous click chemistry
, Article Applied Organometallic Chemistry ; Volume 30, Issue 2 , 2016 , Pages 73-80 ; 02682605 (ISSN) ; Hosseini, S. H ; Pour Javadi, A ; Bennett, C ; Sharif University of Technology
John Wiley and Sons Ltd
2016
Abstract
A heterogeneous magnetic copper catalyst was prepared via anchoring of copper sulfate onto multi-layered poly(2-dimethylaminoethyl acrylamide)-coated magnetic nanoparticles and was characterized using various techniques. The catalyst was found to be active, effective and selective for one-pot three-component reaction of alkyl halide, sodium azide and alkyne, known as copper-catalyzed click synthesis of 1,2,3-triazoles. As little as 0.3 mol% of catalyst was found to be effective under the optimum conditions. The catalyst could also be recycled and reused up to seven times without significant loss of activity. Thermal stability, high loading level of copper on catalyst, broad diversity of...
Covalent immobilization of cellulase using magnetic poly(ionic liquid) support: improvement of the enzyme activity and stability
, Article Journal of Agricultural and Food Chemistry ; Volume 66, Issue 4 , 2018 , Pages 789-798 ; 00218561 (ISSN) ; Hosseini, A ; Zohreh, N ; Yaghoubi, M ; Pourjavadi, A ; Sharif University of Technology
American Chemical Society
2018
Abstract
A magnetic nanocomposite was prepared by entrapment of Fe3O4 nanoparticles into the cross-linked ionic liquid/epoxy type polymer. The resulting support was used for covalent immobilization of cellulase through the reaction with epoxy groups. The ionic surface of the support improved the adsorption of enzyme, and a large amount of enzyme (106.1 mg/g) was loaded onto the support surface. The effect of the presence of ionic monomer and covalent binding of enzyme was also investigated. The structure of support was characterized by various instruments such as FT-IR, TGA, VSM, XRD, TEM, SEM, and DLS. The activity and stability of immobilized cellulase were investigated in the prepared support. The...
Rating EFL Learner's Interlanguag Pragmatic Competence by Native and Non-native English Speaking Teachers
, M.Sc. Thesis Sharif University of Technology ; Alemi, Minoo (Supervisor) ; Eslami Rasekh, Zohreh (Co-Advisor)
Abstract
Pragmatic assessment and consistency in rating are among the subject matters which are still in need of more in-depth investigations. The significance of the issue is highlighted when remembering that inconsistency in ratings would surely damage the test fairness issue in assessment and lead to much diversity in ratings. The purpose of this study was investigating the criteria that native (American) and non-native (Iranian) English speaking teachers considered while rating the pragmatic productions of Iranian EFL learners regarding the two speech acts of compliment and compliment response. Overall, a hundred and twenty teachers (sixty native and sixty non-native raters) participated in this...
Effects of liquid second viscosity in high-amplitude sonoluminescence
, Article Chinese Physics Letters ; Volume 21, Issue 2 , 2004 , Pages 356-359 ; 0256307X (ISSN) ; Sadighi Bonabi, R ; Taeibi Rahni, M ; Daemi, M ; Sharif University of Technology
Allerton Press Inc
2004
Abstract
The well-known Rayleigh-Plesset (RP) equation is the base of nearly all hydrodynamical descriptions of the sonoluminescence phenomenon. A major deficiency of this equation is that it accounts for viscosity of an incompressible liquid and compressibility, separately. By removing this approximation, we have modified the RP equation, considering effects of liquid second viscosity. This modification exhibits its importance at the end of an intense collapse, so that the new model predicts the appearance of a new picosecond bouncing during high-amplitude sonoluminescence radiation. This new bouncing produces very sharp (sub-picosecond) peaks on the top of the sonoluminescence pulse. These new...
Immobilized tungstate on magnetic poly(2-ammonium ethyl acrylamide): A high loaded heterogeneous catalyst for selective oxidation of sulfides using H2O2
, Article Journal of Industrial and Engineering Chemistry ; Volume 44 , 2016 , Pages 73-81 ; 1226086X (ISSN) ; Hosseini, S. H ; Pourjavadi, A ; Soleyman, R ; Bennett, C ; Sharif University of Technology
Korean Society of Industrial Engineering Chemistry
2016
Abstract
A heterogeneous tungstate-based catalyst has been prepared for selective oxidation of sulfides to sulfoxides in the presence of 30% H2O2. The catalyst was prepared via immobilization of high amounts of WO4 2− onto the cross-linked poly(ammonium ethyl acrylamide) coated magnetic nanoparticles (MNP). FT-IR, TEM, TGA, VSM, XRD, EDX, and CHN analysis were used for characterization of catalyst. Variety of sulfides successfully converted to the related sulfoxides using 1 mol% of catalyst at room temperature in high yields. The catalyst was easily recovered and reused up to 6 times without loss of activity
Tungstate-loaded triazine-based magnetic poly(Bis-imidazolium ionic liquid): An effective bi-functional catalyst for tandem selective oxidation/Knoevenagel condensation in water
, Article Polymer (United Kingdom) ; Volume 112 , 2017 , Pages 342-350 ; 00323861 (ISSN) ; Tavakolizadeh, M ; Hosseini, S. H ; Pourjavadi, A ; Bennett, C ; Sharif University of Technology
Elsevier Ltd
2017
Abstract
A novel bi-functional polymeric catalyst was synthesized by immobilization of tungstate anions onto the nitrogen rich poly(ionic liquid)/magnetic nanocomposite. The resulting catalyst has two types of catalytic sites: (i) immobilized WO4 anions with bis-imidazolium ionic liquid cation for selective oxidation of alcohols and (ii) basic amine groups for Knoevenagel condensation between produced aldehyde and malononitrile. Due to the polymeric nature of the catalyst, large amounts of tungstate and basic nitrogen groups were presented on the solid surface which led to a decrease in the applied catalyst mass for catalytic reaction. High catalytic activity and excellent selectivity of catalyst in...
Numerical Simulation of Bubble Cluster Dynamics, Using Lattice Boltzmann Method
, Ph.D. Dissertation Sharif University of Technology ; Tayyebi Rahni, Mohammad (Supervisor) ; Massah, Hamid Reza (Co-Advisor)
Abstract
Bubble cluster has attracted the interests of many researches since the early twentieth century. Despite its easy generation and numerous occurrences, its study is extremely complex. Describing the dynamical behavior of bubble clusters is possible when quite a few simplifying assumptions are utilized. In other words, one can observe that with current approaches, the relevant theoretical researches are not very valuable. In this research, however, lattice Boltzmann method, a rather recent mesoscopic approach, was used to study the behavior of bubbles in a bubble cluster. Of course, this is only the beginning and there is a long way before getting close to experimental results. However, there...
Highly dispersible bis-imidazolium/WO4 2 modified magnetic nanoparticles: a heterogeneous phase transfer catalyst for green and selective oxidations
, Article New Journal of Chemistry ; Volume 40, Issue 12 , 2016 , Pages 10325-10332 ; 11440546 (ISSN) ; Tavakolizadeh, M ; Hosseini, S. H ; Jahani, M ; Pourjavadi, A ; Bennett, C ; Sharif University of Technology
Royal Society of Chemistry
2016
Abstract
A novel magnetically recoverable catalyst was prepared in which magnetic nanoparticles (MNPs) were functionalized by bis-imidazolium tungstate ionic liquid molecules. The resulting catalyst was highly dispersible in water and selectively oxidized a wide range of alcohols and sulfides using H2O2 as a green oxidant. The catalyst was easily recovered and reused at least 5 times under the described reaction conditions without any significant loss of reactivity
Silica-supported DABCO-tribromide: A recoverable reagent for oxidation of alcohols to the corresponding carbonyl compounds
, Article Scientia Iranica ; Volume 20, Issue 3 , 2013 , Pages 598-602 ; 10263098 (ISSN) ; Masoud, N ; Foroushani, B. K ; Saryazdi, S ; Ghonouei, N ; Daemi, E ; Sharif University of Technology
2013
Abstract
In this study, 1,4-diazabicy lo[2.2.2] octane (DABCO) tribromide was immobilized on silica support by using 3-chloro propyl trimethoxy silane to obtain a silica-supported DABCO tribromide reagent. The synthesized reagent was characterized with elemental analysis, FT-IR spectroscopy, and thermo-gravimetric analysis (TGA). This reagent has been applied in the conversion of alcohol to corresponding carbonyl compounds. Alcohol oxidation reactions yield in 52-95%, and the reagent may be recycled five times with further bromine treatment
Planning screw insertion trajectory in lumbar spinal fusion using pre-operative CT images
, Article Proceedings of the Annual International Conference of the IEEE Engineering in Medicine and Biology Society, EMBS, 25 August 2015 through 29 August 2015 ; Volume 2015-November , 2015 , Pages 3639-3642 ; 1557170X (ISSN) ; 9781424492718 (ISBN) ; Ahmadian, A ; Mirbagheri, A ; Ahmadian, A. H ; Saberi, H ; Amidi, F ; Alirezaie, J ; Sharif University of Technology
Institute of Electrical and Electronics Engineers Inc
2015
Abstract
Spinal fusion permanently connects two or more vertebrae in spine to improve stability, correct a deformity or reduce pain by immobilizing the vertebrae through pedicle screw fixation. Pedicle screws should be inserted very carefully to prevent possible irrecoverable damages to the spinal cord. Surgeons use CT/fluoroscopic images to find how to insert the screws safely. However, there is still human error, as determining precise trajectory in 3D space is difficult because of asymmetric structure of pedicle. In this study we attempt to propose a shape based method to help the surgeons to find the more accurate and safe path for screw insertion that minimizes the risk or invasiveness of the...
Grid Homology and the Existence of Exotic Structures on R4
, M.Sc. Thesis Sharif University of Technology ; Moghaddasi, Reza (Supervisor) ; Eftekhari, Eaman (Supervisor) ; Daemi, Ali Akbar (Co-Advisor)
Abstract
Knot theory is the study of ambient isotopy classes of compact 1–manifolds in a 3-manifold. In classical knot theory this 3-manifold is R3 or S3. This field has experienced a great transformative advances in recent years because of its strong connections with and a number of other mathematical disciplines including topology of 3-manifolds and 4-manifolds, gauge theory, representation theory, categorification, morse theory, symplectic geometry and the theory of pseudo-holomorphic curves. In this thesis we start with classical knot theory, introducing some of its (classical) invariants like unknotting number, Seifert genus and slice genus of a knot, knot group and finally Alexander Polynomial...