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A Novel Fe3O4/Poly (Aniline-Naphthylamine)-Based Nanocomposite for Magnetic Solid Phase Extraction of Rhodamine B from Aquatic Samples
, M.Sc. Thesis Sharif University of Technology ; Bagheri, Habib (Supervisor)
Abstract
A novel Fe3O4/poly (aniline-naphthylamine) (ANI-NA)-based nanocomposite was synthesized by chemical oxidative polymerization process as a magnetic sorbent for magnetic solid phase extraction. The extraction efficiency of this sorbent was examined by isolation of rhodamine B (RhB), a mutagenic and carcinogenic dye from aquatic media in dispersion mode. The efficiency of the synthesized Fe3O4/copolymer composite was examined and compared with Fe3O4/polyaniline (PANI) and Fe3O4/polynaphthylamine (PNA) by quantification of RhB using spectrofluorimetry. Among them, Fe3O4/poly (ANI-NA) nanocomposite showed a prominent efficiency. The scaning electron microscopy (SEM) image of the synthesized...
A Heuristic Framework with Mathematical Modeling for Inherently Safe Design of Chemical Process with Sustainability Assessment of Case Study
, M.Sc. Thesis Sharif University of Technology ; Rashtchian, Davoud (Supervisor)
Abstract
Inherently safer design is the new approach to maximize the overall safety of a process plant. This approach suggests some risk reduction strategies to be implemented in the early stages of design. There are different well-established strategies for making a process plant inherently safer. The benefits of applying these strategies on reducing the overall risk inside a plant are obvious. However, some of these changes are rejected many times because they appear to be too costly. But if the effects of applying inherently safer design strategies are investigated not only on the processing costs of a plant but also on the potential accident costs, the decision would in fact be different. In this...
Design for Optimal Assembly of Complex Mechanical Assembles with Large Number of Components
, M.Sc. Thesis Sharif University of Technology ; Khodygan, Saeed (Supervisor)
Abstract
In the current status of the world production business, any action that can improve quality or decrease the price of products is very important to manufactures. Therefore, many studies had been conducted to do this. In production stages, the assembly stage includes 30% of production cost and up to 40% of production time. Therefore, optimization and design of the Production sequence of this stage are very important. This matter is more important in complicated and multi-segmental productions such as car manufacturing, the Aviation industry, and the shipbuilding industry. Also, optimization of the Production sequence could improve product quality. In this study, an algorithm has been purposed...
Performance Evaluation and Improvement of Duplicate Question Detection in Developers’ Online Q&A Community
, M.Sc. Thesis Sharif University of Technology ; Habibi, Jafar (Supervisor)
Abstract
In this research, we study one of the challenges in the field of software engineering, namely the detection of diplicate questions in Stackoverflow, the Q&A community of programmers. The works done in this area has problems such as complexity and reduced performance over time. The proposed solution is based on machine learning and modern representation learning methods. Representation is done with two approaches, domain specific learning and transfer learning. Fasttext and GloVe, the two word embeddings used in domain specific learning, and in transfer learning, the embedding of the universal sentence encoder has been used. Support vector machine and multilayer perceptron used as...
Enhancement of Alkaline Protease Production Using Process Factors
, M.Sc. Thesis Sharif University of Technology ; Roostaazad, Reza (Supervisor)
Abstract
In this research, we have studied optimization of culture medium and process factors for high alkaline protease production from Bacillus subtilis ATCC 6633 for detergent usage. Five parameter soy bean meal, initial pH, agitation rate, MgSO4, CaCl2 were selected for more studies. At first, one-factor-at-a-time method was applied to investigate effect of each factor separately. Then, optimum condition for maximum protease production was achieved using Minitab software Box-benhnken procedure. According to results, high protease production was seen in soy bean meal, 35 (g/L); MgSO4, 1 (g/L); CaCl2 , 1.5 (g/L); initial pH, 7; agitation rate, 150; inoculum ratio, 12% (v/v). The activity of the...
An electrospun magnetic nanocomposite for a facile micro-scaled analysis approach
, Article Analytical Methods ; Vol. 6, issue. 15 , 2014 , Pages 5838-5846 ; ISSN: 17599660 ; Roostaie, A ; Daliri, R ; Sharif University of Technology
2014
Abstract
A magnetic polyurethane (PU) nanocomposite was synthesized by an electrospinning technique and applied for isolation and preconcentration of fluoxetine from aquatic and biological samples. The nanocomposite was electrospun using a PU polymer solution containing the dispersed magnetic nanoparticles. The magnetic properties of iron nanoparticles, along with the use of an electrospinning technique, led to the formation of a suitable sorbent toward isolation of fluoxetine. The magnetic PU nanofibers could be subsequently removed from the sample solution by applying a permanent magnet. The scanning electron microscopy (SEM) image of the magnetic PU nanofibers confirms that their diameters are in...
Experimental Study of the Effect of Bleed Location on Performance and Stability of an Axisymmetric Supersonic Mixed-Compression Inlet
, M.Sc. Thesis Sharif University of Technology ; Soltani, Mohammad Reza (Supervisor)
Abstract
For supersonic inlets with reduction of mass flow ratio to a specified value self-induced oscillations know as Buzz would occure. Study and suppression of these oscillations are categorized in the field of inlet stability. In this work performance and stability of a supersonic inlet is studied experimentaly. Also a flow control mean is examined for stability and performance improvement. Investigation of the effect of bleed location as a key parameter for this flow control method is the main goal of this study. The model used is an axisymmetric mixed compression inlet. Experiments were done in 3 freestream Mach Numbers of 1.8, 2.0 and 2.2 with application of bleed and in no-bleed condition....
Synthesis and Characterization of the Improved Nanocomposites Based on Graphene and Their Mechanism and Kinetic Investigation in the Environmental Pollutant Degradation
, M.Sc. Thesis Sharif University of Technology ; Gholami, Mohammad Reza (Supervisor)
Abstract
In this project the RGO/Ag2O/g-C3N4 nanocomposite was synthesized, and characterized by different technique such as SEM, XRD, and FT-IR. Then its photocatalytic activity was investigated. The degradation percent for Acid-Blue 92 by this photocatalyst was estimated 81 in 45 minutes. Afterward, the photocatalyst activity was determined in different pH including 4, 7, 10. The best result was for pH=7. Then, the increasing concentration of dye were investigated and the results show that by increasing the concentration of 10 to 30 ppm, the photocatlytic activity decreased. Photocatalytic degradation process of AB92 were also carried out at different amount of photocatalyst. The mechanism of...
A latency-tolerant MAC protocol for underwater acoustic sensor networks
, Article ICCAS 2010 - International Conference on Control, Automation and Systems, 27 October 2010 through 30 October 2010, Gyeonggi-do ; 2010 , Pages 849-854 ; 9781424474530 (ISBN) ; Manzuri, M. T ; Sharif University of Technology
2010
Abstract
Wireless networks with the shared media require Medium Access Control (MAC) protocol that provides contention resolution mechanism. The design of MAC protocol in underwater sensor networks is a challenging issue because of limited energy source and high propagation delay. The most important goal of the MAC design for underwater sensor networks is to resolve data packet collision efficiently with respect to energy consumption. So, selection of MAC protocol is an important task because it has significant impact on the system efficiency. A suitable MAC protocol must consider some factors such as fairness, energy consumption, latency and throughput based on various applications. The bandwidth in...
Semi-empirical modelling of hydraulic conductivity of clayey soils exposed to deionized and saline environments
, Article Journal of Contaminant Hydrology ; Volume 249 , 2022 ; 01697722 (ISSN) ; Sadeghi, H ; Sharif University of Technology
Elsevier B.V
2022
Abstract
Clay liners are widely used as porous membrane barriers to control solute transport and to prevent the leakage of leachate both in horizontal and vertical flow scenarios, such as the isolated base and ramps of sanitary landfills. Despite the primary importance of saturated hydraulic conductivity in a reliable simulation of fluid flow through clay barriers, there is no model to predict hydraulic conductivity of clayey soils permeated with saline aqueous solutions because most of the current models were developed for pure water. Therefore, the main motivation behind this study is to derive semi-empirical models for simulating the hydraulic conductivity of clayey soils in the presence of...
Theoretical and numerical study of contaminant transport in clayey barriers using a revised numerical model considering the dependency of membrane efficiency and hydraulic conductivity on solute concentration
, Article Heliyon ; Volume 9, Issue 5 , 2023 ; 24058440 (ISSN) ; Hedayati Azar, A ; Sharif University of Technology
Elsevier Ltd
2023
Abstract
Solid waste is often buried in landfills isolated with a bentonite-based clay barrier to guarantee the high quality of groundwater. As the efficiency of clay barriers is highly dependent on solute concentration, this study aims to modify membrane efficiency, effective diffusion, and hydraulic conductivity of bentonite-based clayey barriers exposed to saline environments for numerical investigation of solute transport in such barriers. Therefore, the theoretical equations were modified as a function of solute concentration instead of constant values. First, a model was extended for membrane efficiency as a function of void ratio and solute concentration. Second, an apparent tortuosity model...
Introducing a comprehensive framework to measure spike-LFP coupling
, Article Frontiers in Computational Neuroscience ; Volume 12 , 2018 ; 16625188 (ISSN) ; Jahed, M ; Daliri, M. R ; Sharif University of Technology
Frontiers Media S.A
2018
Abstract
Measuring the coupling of single neuron's spiking activities to the local field potentials (LFPs) is a method to investigate neuronal synchronization. The most important synchronization measures are phase locking value (PLV), spike field coherence (SFC), pairwise phase consistency (PPC), and spike-triggered correlation matrix synchronization (SCMS). Synchronization is generally quantified using the PLV and SFC. PLV and SFC methods are either biased on the spike rates or the number of trials. To resolve these problems the PPC measure has been introduced. However, there are some shortcomings associated with the PPC measure which is unbiased only for very high spike rates. However evaluating...
Novel method for supersonic inlet buzz measurement in wind tunnel
, Article Journal of Propulsion and Power ; Volume 34, Issue 1 , 2018 , Pages 273-277 ; 07484658 (ISSN) ; Farahani, M ; Sepahi Younsi, J ; Sharif University of Technology
American Institute of Aeronautics and Astronautics Inc
2018
Development of an Integrated Model of Electricity & Methanol Co Production Through Solar Energy and CO2 Capture
, M.Sc. Thesis Sharif University of Technology ; Saboohi, Yadollah (Supervisor)
Abstract
Emission of CO2 and its diffusion into atmosphere is associated with negative effects on the environmental such as Green House Gases effect. Various techniques of CO2 Capture in energy conversion and processing plant are investigated. A method of CO2 Capture could be based on utilization of solar energy for producing methanol. Basic design of such a system and feasibility analysis of developing that system has been considered on the subject of the present research work. Basic design and commercial feasibility of the system producing methanol through capturing CO2 from exhaust gases of a power plant and hydrogen produced by using solar energy have done such an integrated system. The main...
An Improved Latency- Tolerant MAC Protocol for Underwater Acoustic Sensor Networks
, M.Sc. Thesis Sharif University of Technology ; Manzuri, Mohammad Taghi (Supervisor)
Abstract
Wireless networks with the shared media require Medium Access Control (MAC) protocol that provides contention resolution mechanism. The design of MAC protocol is a challenging issue because of limited energy source and high propagation delay in UnderWater Acoustic Sensor Networks (UWASNs). The most important goal of the MAC design for underwater sensor networks is to resolve data packet collision efficiently with respect to energy consumption. So, selection of MAC protocol is an important task because it has significant impact on the system efficiency. A suitable MAC protocol must consider some factors such as fairness, energy consumption, latency and throughput based on various...
L-sorbose production by gluconobacter oxydans using submerged fermentation in a bench scale fermenter
, Article Applied Food Biotechnology ; Volume 7, Issue 1 , 2020 , Pages 41-48 ; Alemzadeh, I ; Sharif University of Technology
National Nutrition and Food Technology Research Institute
2020
Abstract
Background and objective: L-Sorbose, as a precursor of ascorbic acid, can be biologically produced using Gluconobacter oxydans. The aim of this study was to optimize production of L-Sorbose by controlling concentration of the substrates and starter cultures. Material and methods: In this study, effects of three various fermentation parameters on the concentration of L-sorbose were assessed using fermenter (28°C, 1.4 vvm) and response surface methodology. These parameters included quantities of D-sorbitol (120-180 g lDw-1) (Deionized water) and yeast extract (6-18 g lDw-1) and inoculum/substrate ratios (5-10%). Results and conclusion: Results showed that the fitted model with high values of...
Robust-fuzzy model for supplier selection under uncertainty: an application to the automobile industry
, Article Scientia Iranica ; Volume 25, Issue 4 , 2018 , Pages 2297-2311 ; 10263098 (ISSN) ; Modarres, M ; Azar, A ; Sharif University of Technology
Sharif University of Technology
2018
Abstract
This paper proposes an innovative robust-fuzzy method for multi-objective, multi-period supplier selection problem under multiple uncertainties. This approach integrates robust optimization and fuzzy programming. Uncertain parameters are modeled as random variables that take value within a symmetrical interval. However, due to the complexity or ambiguity of some real world problems and especially the nature of some of the available input data, the length of interval is also highly uncertain. This ambiguity motivated us to present a new approach, which could be applicable to multiple uncertainties conditions. Thus, in our approach, the half-length of these intervals is also represented by...
A Study on the Impact of Extract of Green Coffee Beans as a Green Corrosion Inhibitor of Mild Steel in Simulated Concrete Pore Solution
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
In this study, the effect of green coffee extract powder, as a green corrosion inhibitor of steel in a concrete simulation environment was investigated. In this study, the green coffee extract was obtained by the Maceration method and its performance was investigated by weight loss method, electrochemical methods including Polarization, Electrochemical Impedance Spectroscopy. Scanning Electron Microscopy images were also used to visualize the corroded areas. The results of the polarization test showed that 450 mg/lit of coffee extract powder at 25 °C has the corrosion inhibiting efficiency of about 82% and the corrosion rate of the bare sample reduced from 6 to 1.16 mpy. The dosage of 550...
Performance investigation of a supersonic air intake in presence of boundary-layer bleed
, Article 32nd AIAA Applied Aerodynamics Conference ; June , 2014 ; Javad Sepahi, Y ; Daliri, A ; Sharif University of Technology
2014
Abstract
The performance of an axisymmetric supersonic mixed-compression air intake has been investigated experimentally. The intake has been designed for free stream Mach number of 2.0. This study has two main goals, firstly to investigate the performance of the intake without boundary-layer bleed in design and off-design conditions and secondly to study the effects of a slot bleed on the intake performance. The intake has been tested at free stream Mach numbers of 1.8, 2.0, and 2.2 and zero degree angle of attack. Total pressure recovery (TPR), mass flow ratio (MFR) and flow distortion (FD) have been selected parameters to assess the intake performance. The bleed slot is located upstream of the...
Synthesis and thermal behavior of Mg-doped calcium phosphate nanopowders via the sol gel method
, Article Scientia Iranica ; Volume 18, Issue 6 , 2011 , Pages 1614-1622 ; 10263098 (ISSN) ; Behnamghader, A ; Daliri, M ; Moshkforoush, A ; Sharif University of Technology
2011
Abstract
The aim of this study was to investigate the thermal behavior of Mg-doped calcium phosphate compounds. Nanocrystalline HA and β-TCP mixtures containing different magnesium contents were synthesized via an alkoxide sol gel method. The ratio of (Ca+Mg)P was kept constant at 1.67, and the Mg content ranged between 0 and 3 mol%. The influence of magnesium on the phase composition, chemical structure, thermal behavior and morphological characteristics of nanopowders was analyzed using X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Simultaneous Thermogravimetry and Differential Thermal Analysis (STA/DTA), Scanning Electron Microscopy (SEM) and Transmission Electron...