Sharif Digital Repository

A novel, magnetic nanocarrier was successfully synthesized through a facile and economical producer in which Fe3O4 magnetic nanoparticles were coated by starch-g-poly (methyl methacrylate-co-PEG-acrylamide). The surface of nanocarrier was then modified by hydrazine to preparation of a pH-responsive carrier. The resulted nanocarrier was applied for delivery of doxorubicin (DOX) as an effective anti-cancer drug. DOX was reacted with hydrazine linkage on the surface of nanocarrier to form hydrazone bond. Due to the presence of numerous hydrazine groups on the surface of magnetic nanocarrier large amounts of DOX was loaded onto the carrier (327 mg g−1). © 2016 The Korean Society of Industrial... 

With the advent of small-scale heat and electricity producers in distribution energy systems, the interdependencies between energy carriers have been increased. Moreover, the rapid deployment of micro CHP, electric heat pumps, electricity-to-heat appliances etc., calls for new local market frameworks to be employed in distribution energy systems. In response, this paper presents a new energy market framework based on the concept of peer-to-peer negotiations to facilitate energy transactions between agents at the distribution level while addressing the interdependencies between different energy carriers. Moreover, linear optimization problems are proposed to investigate the optimal strategies... 

A novel heterogeneous catalyst has been synthesized based on the distillation-precipitation-polymerization of methyl acrylate onto modified magnetic nanoparticles followed by the amidation of the methyl ester groups using N,N-dimethylethylenediamine. The resulting poly(dimethylaminoethyl acrylamide) coated magnetic nanoparticles (MNP@PDMA) catalyst was characterized using an array of sophisticated analytical techniques, including FT-IR, TGA, SEM, TEM, CHN, vibrating sample magnetometer (VSM), and XRD analysis. The resulting heterogeneous base catalyst allowed the performance of a domino Knoevenagel condensation/Michael addition/cycloaddition reaction toward the synthesis of... 

Anchoring of copper sulfate in layered poly(imidazole-imidazolium) coated magnetic nanoparticles provided a highly stable, active, reusable, high loading, and green catalyst for the click synthesis of 1,2,3-triazoles via a one-pot cycloaddition of alkyl halide, azide, and alkyne (Cu-A3C). The catalyst was characterized by FTIR, TGA, TEM, SEM, XRD, EDAX, VSM and AAS. High selectivity, broad diversity of alkyl/benzyl bromide/chloride and alkyl/aryl terminal alkynes, and good to excellent yields of products were obtained using 0.7 mol% catalyst. The catalyst was readily recovered and reused up to 6 times without significant loss of activity  

Space constraint is a limiting factor for the widespread commercial adaptation of switched reluctance generators (SRGs). Maximizing the output power and minimizing the dc bus filter size are thus highly desired. The output power profiles of a typical SRG are determined by applying various excitation angles. Excitation for maximum output power is obtained while limiting the rms value of the phase currents. The dc bus current of an SRG drive, operating in single pulse mode, is highly distorted by low-frequency ripples. Introducing a freewheeling angle in the excitation pattern can lower the current ripple factor. A novel transform is proposed to establish a relationship between the... 

A heterogeneous magnetic copper catalyst was prepared via anchoring of copper sulfate onto multi-layered poly(2-dimethylaminoethyl acrylamide)-coated magnetic nanoparticles and was characterized using various techniques. The catalyst was found to be active, effective and selective for one-pot three-component reaction of alkyl halide, sodium azide and alkyne, known as copper-catalyzed click synthesis of 1,2,3-triazoles. As little as 0.3 mol% of catalyst was found to be effective under the optimum conditions. The catalyst could also be recycled and reused up to seven times without significant loss of activity. Thermal stability, high loading level of copper on catalyst, broad diversity of... 

A magnetic nanocomposite was prepared by entrapment of Fe3O4 nanoparticles into the cross-linked ionic liquid/epoxy type polymer. The resulting support was used for covalent immobilization of cellulase through the reaction with epoxy groups. The ionic surface of the support improved the adsorption of enzyme, and a large amount of enzyme (106.1 mg/g) was loaded onto the support surface. The effect of the presence of ionic monomer and covalent binding of enzyme was also investigated. The structure of support was characterized by various instruments such as FT-IR, TGA, VSM, XRD, TEM, SEM, and DLS. The activity and stability of immobilized cellulase were investigated in the prepared support. The... 

The rapid deployment of district heating systems in local energy markets and increasing the number of small-scale heat producers along with the expansion of local electricity markets increase the need for a transaction framework to manage the transactions between local participants in both heat and electricity markets. This paper presents a peer-to-peer thermal energy transaction framework to manage the transactions between small-scale heat prosumers. This framework enables small-scale thermal energy producers and consumers to participate in the market as price maker agents. Moreover, the optimal strategy of heat market participants is determined by proposing a linear profit function for... 

Proliferation of Plug-in Hybrid Electric Vehicles (PHEVs) and integration of various distributed generation (DG) technologies have been recognized to play an undeniable role in modern power systems of the future. In order to effectively model the interactions of these two technologies, this paper develops a multi-criteria framework to coordinate the charging behaviors of PHEVs within an energy hub platform. In this regard, the desirable charging profiles from the viewpoint of both PHEV owners and hub manager are first captured and reported to the PHEVs Coordinator Entity (PCE). The PCE, then, runs an optimization framework in which several criteria including the PHEV owners’ convenience,... 

Reinforcement learning (RL) is a subset of artificial intelligence in which a decision-making agent tries to act optimally in an environment by controlling different parameters. There is no need to identify and mathematically formulate the environmental constraints in such a method. Moreover, the RL agent does not need prior information about future outcomes to act optimally in the current situation. However, its performance is adversely affected by the environmental complexity, which increases the agent's effort to choose the optimal action in a particular condition. Integrating RL and linear programming (LP) methods is beneficial to tackle this problem as it reduces the state-action space... 

A heterogeneous tungstate-based catalyst has been prepared for selective oxidation of sulfides to sulfoxides in the presence of 30% H2O2. The catalyst was prepared via immobilization of high amounts of WO4 2− onto the cross-linked poly(ammonium ethyl acrylamide) coated magnetic nanoparticles (MNP). FT-IR, TEM, TGA, VSM, XRD, EDX, and CHN analysis were used for characterization of catalyst. Variety of sulfides successfully converted to the related sulfoxides using 1 mol% of catalyst at room temperature in high yields. The catalyst was easily recovered and reused up to 6 times without loss of activity  

A novel bi-functional polymeric catalyst was synthesized by immobilization of tungstate anions onto the nitrogen rich poly(ionic liquid)/magnetic nanocomposite. The resulting catalyst has two types of catalytic sites: (i) immobilized WO4 anions with bis-imidazolium ionic liquid cation for selective oxidation of alcohols and (ii) basic amine groups for Knoevenagel condensation between produced aldehyde and malononitrile. Due to the polymeric nature of the catalyst, large amounts of tungstate and basic nitrogen groups were presented on the solid surface which led to a decrease in the applied catalyst mass for catalytic reaction. High catalytic activity and excellent selectivity of catalyst in... 

This paper proposes a new experimental procedure for magnetic characterization of switched reluctance machines. In the existing methods, phase voltage and current data are captured and further processed to find the flux linkage. Conventionally, assuming zero initial flux value, the flux linkage can be found by integrating the corresponding voltage term. However, the initial flux value is usually unknown, e.g., it can be nonzero when the current is zero due to the residual flux effect, and, thus, imposes error in magnetic characterization. The proposed method addresses this issue by considering an additional equation in steady state. This method injects a low-frequency sinusoidal current to...