Sharif Digital Repository

For the first time, a new platform based on electrochemical growth of Au nanoparticles on aligned multi-walled carbon nanotubes (A-MWCNT) was developed for sensitive lable-free DNA detection of the TP53 gene mutation, one of the most popular genes in cancer research. Electrochemical impedance spectroscopy (EIS) was used to monitor the sequence-specific DNA hybridization events related to TP53 gene. Compared to the bare Ta or MWCNT/Ta electrodes, the synergistic interactions of vertically aligned MWCNT array and gold nanoparticles at modified electrode could improve the density of the probe DNA attachment and resulting the sensitivity of the DNA sensor greatly. Using EIS, over the extended... 

Carbon nanotube/nanoparticle hybrid materials have been proven to exhibit high electrocatalytic activity suggesting broad potential applications in the field of electroanalysis. For the first time, modification of Ta electrode with aligned multi-walled carbon nanotubes/Au nanoparticles introduced for the sensitive determination of the antibiotic drug, cefazolin (CFZ). The electrochemical response characteristics of the modified electrode toward CFZ were investigated by means of cyclic and linear sweep voltammetry. The modified electrode showed an efficient catalytic activity for the reduction of CFZ, leading to a remarkable decrease in reduction overpotential and a significant increase of... 

An efficient method has been developed to synthesize well-aligned multi-walled carbon nanotubes (MWCNTs) on a conductive Ta substrate by chemical vapor deposition. Free-standing MWCNTs arrays were functionalized through electrochemical oxidation with the formation of hydroxyl and carboxyl functional groups. Facile template-free electrochemical routes were then developed for the shape-selective synthesis of less-common Au nanostructures, including flower, sphere, dendrite, rod, sheet, and cabbage onto the aligned MWCNTs at room temperature. Especially, among all the synthesis methods for Au nanocrystals, this is the first report using electrochemical technique to synthesize wide variety... 

The microstructural characteristic of HSLA welds containing different amounts of titanium were evaluated carefully. It was observed that the microstructure of welds consisted of ferrite with mixed morphologies, and small amounts of pearlite and martensite-austenite micro-constituents. Because of insufficient time for diffusion of carbon, formation of pearlite lamellae could not be completed in the weld region. Martensite was formed from carbon enrichment of austenite during nucleation and growth of acicular ferrite and bainitic ferrite. While coarse manganese sulfide particles had weak interface strength with matrix and formed some micro-fissures; increasing titanium amount of welds... 

In this study, TiO 2-SiO 2 nanocomposite films with different amounts of SiO 2 were prepared by sol-gel process and were coated onto stainless steel 316L. The effect of addition of various amount of SiO 2 in the precursor solution on the photocatalysis, photo-generated hydrophilicity and self-cleaning property of TiO 2 thin films was investigated by X-ray diffraction, Fourier transform infrared spectroscopy, water contact angle measurements and UV spectroscopy. In the tested ranges of SiO 2 content and sintering temperature, the highest photocatalytic activity and self-cleaning property were observed in the 15 mol% SiO 2 sample sintered at 750 °C. Addition of less than 30 mol% SiO 2 had a... 

The effect of titanium addition on the SAW weld metal microstructure of API 5L-X70 pipeline steel was investigated. The relationship between microstructure and toughness of the weld deposit was studied by means of full metallographic, longitudinal tensile, Charpy-V notch and HIC tests on the specimens cut transversely to the weld beads. The best combination of microstructure and impact properties was obtained in the range of 0.02-0.05% titanium. By further increasing of titanium content, the microstructure was changed from a mixture of acicular ferrite, grain-boundary ferrite and Widmanstätten ferrite to a mixture of acicular ferrite, grain-boundary ferrite, bainite and ferrite with M/A... 

The Co nanowires were electrodeposited in polycarbonate membrane (PCT). SEM, TEM and XPS techniques were used to characterize the morphology, structure and size of nanowires as well as chemical composition. The influence of different mediums was studied on the optical absorption of dispersed cobalt nanowires. The absorption spectrum of cobalt nanowires in water showed a broad shoulder at 290 nm, but in ethanol solution it was not observed in the visible region of the spectra up to 200 nm. Cobalt nanowires dispersed in methanol presented a peak at 236 nm. We attribute the data to oxidation of cobalt in water and low dielectric constant of methanol relative to ethanol and water. We found... 

The first usage of dihexadecyl hydrogen phosphate (DHP)-modified highly oriented multi-walled carbon nanotube (MWCNTs) forests in a sensor configuration was developed to investigate the electrochemical oxidation and determination of simvastatin (SV) in pharmaceutical dosage forms. Synthesis of well-aligned MWCNTs on a conductive Ta substrate by catalytic vapor deposition technique using a common chemical, ethylenediamine, and without being plasma-aided was reported. The electrochemical behavior and oxidation of SV at the aligned MWCNTs/DHP/Ta electrode were discussed in detail through cyclic voltammetry and differential pulse voltammetry. This modified electrode showed considerably higher... 

This work studies the influence of surface modification of silica nanoparticles by mercaptopropyl trimethoxysilane on silica weight percent in Ni coating during electrodeposition. Results showed SiO2(CH2)3SH particles were embedded in the Ni coating up to 11%. Also, modified Guglielmi’s model and mechanicsm of nucleation of Ni-SiO2(CH2)3SH composite were studied. © 2017 The Electrochemical Society. All rights reserved  

Ruthenium oxide was coated on multiwalled carbon nanotubes (MWCNTs) to obtain nanocomposite electrode which has a good response to the pH. To synthesize this electrode, gold and cobalt were coated on a stainless steel 304 substrates, respectively, and then, vertically aligned carbon nanotubes were grown on the prepared substrates by chemical vapor deposition. Gold reduced activity of the stainless steel, while cobalt served as a catalyst for growth of the carbon nanotube. Ruthenium oxide was then coated on MWCNTs via sol-gel method. At last, different techniques were used to characterize the properties of synthesized electrode including scanning electron microscopy (SEM), transmission... 

In this research, anatase TiO2 nano-particles were electrophoretically deposited on the FTO glass. This investigation was focused on the self-cleaning property of TiO2 coatings and the effects of different parameters on this characteristic such as: applied voltages during electrophoretic depositions and durations of UV irradiation. Electrophoretic depositions of suspensions were performed in different voltages of 10, 30 and 60 V (for 10 s) at room temperature. TiO2 coatings were sintered in 450oC for 1 hr. The phase transformation of TiO2 films was considered using XRD. Morphology, average particle size and the thickness of TiO2 films was analyzed using FESEM microscope. The photocatalytic... 

In the present study, the electrodeposition of Fe, Pd and Fe-Pd alloys, in alkaline solutions, has been investigated. Using ammonium hydroxide and trisodium citrate as the complexing agents, it has been shown that the co-deposition of Fe and Pd is achieved due to diminishing the difference between the reduction potentials of these two metals. Cyclic voltammetry results clearly show that the electrodeposition processes are diffusion-controlled and the diffusion coefficients of Fe2+ and Pd2+ are 1.11 × 10-6 and 2.19 × 10-5 cm2 s -1, respectively. The step potential experiments reveal that nucleation mechanism is instantaneous with a typical three-dimensional (3D) growth. At low overpotentials,... 

Steel box girders have two webs and two flanges on top that are usually connected with shear connectors to the concrete deck and are also known as tub girders. The end diaphragms of such bridges comprise of a stiffened steel plate welded to the inside of the girder at each end. The diaphragms play a major role in transferring vertical and lateral loads to the bearings and substructure. A review of literature shows that the cyclic behavior of diaphragms under earthquake loading has not been studied previously. This paper uses a nonlinear finite element model to study the behavior of the end diaphragms under gravity and seismic loads. Different bearing device and stiffener configurations have... 

The objective of this work was to study the influence of titanium on API 5L-X70 steel weld metal properties at manganese levels of 1.4 and 2%. The best mechanical properties in the weld series were obtained in two compositions, i.e. 1.92%Mn-0.02%Ti and 1.40%Mn-0.08%Ti. In both groups of welds, acicular ferrite in the microstructure was increased with addition of titanium in the range of 0.02-0.08%. Manganese helped to refine and homogenize weld microstructures. Increased hardenability of the weld due to further addition of titanium or manganese encouraged grain boundary nucleation of bainite with greater frequency than intragranular nucleation of acicular ferrite. Also, the amount of... 

The Cu-0.5Co/WC nano-composite coating was synthesized on CP-copper substrate using Direct Current (DC) electrodeposition method. In this work, it was tried to increase the hardness of surface without considerable degradation of copper's particular physical properties such as electrical conductivity. The effect of current density on microstructural homogeneity, hardness, fracture toughness, and electrochemical behavior of coating was investigated. The copper plates with the purity of 99.99% were used as electrodes. The electrolyte consists of tungsten carbide particles (30 g/l), copper sulfate (200 g/l), sulfuric acid (50 g/l), cobalt sulfate (50 g/l), and Sodium Dodecyl Sulfate (SDS) (0.3... 

The electrodeposition of cadmium is studied by electrochemical techniques with the presence of the organic agents. The cyclic voltammetry results clearly show that the electrodeposition of cadmium is a diffusion-controlled process associated with a typical nucleation process. With addition of the thiourea, 3-Picolin and benzyl alcohol organic agents simultaneously in sulfate solution, the redox potential of cadmium is shifted to more negative potentials. In this case, the current transients reveal an instantaneous nucleation with a typical three-dimensional (3D) growth mechanism, while it shows progressive nucleation mechanism without the ternary-species organic agents. In addition, the... 

The binary powder blending technique (BPBT) was employed in production of anisotropic (Nd, MM)2(Fe, Co, Ni)14B-type sintered magnets (MM: denotes a Misch-metal). The composition of the master alloy was close to the stoichiometric Nd2Fe14B compound, while the sintering aid (SA) had a composition of MM38.1Co46.4Ni15.4. The magnets were made by blending different ratios of the master alloy and the sintering aid. The corrosion behavior of these magnets was compared with that of the Nd17Fe75B8 base alloy by potentiodynamic polarization measurements in H2SO4 solution. By decreasing the amount of Nd-rich grain boundary phases and substitution of some Fe atoms by Co and Ni, an improvement in the... 

The objective of this work was to study the influence of titanium variations on the API 5L-X70 steel weld metal properties. The relationship between microstructure and toughness of the weld deposit was studied by means of full metallographic, longitudinal tensile and Charpy-V notch tests on the specimens cut transversely to the weld beads. The best combination of microstructure and impact properties was obtained in the range of 0.02-0.05% titanium. By further increasing of titanium content, the microstructure was changed from a mixture of acicular ferrite, grain-boundary ferrite, Widmanstätten ferrite to a mixture of acicular ferrite, grain-boundary ferrite, bainite and ferrite with M/A... 

Hydrogen diffusion into steel can embrittle the material in H2S environments, but this effect can be offset by suitable hydrogen trapping sites in the microstructure. Fine Ti(C,N) inclusions have been studied as the trapping sites in high strength low alloy (API X-70) welds, with Ti additions ranging from 0.004 to 0.16 wt.%. The trapping sites were investigated by electron microscopy and thermal desorption spectroscopy. Manganese sulphide particles were the main initiation sites for hydrogen induced cracking as expected. The optimum Ti addition was around 0.02% with no evidence of cracking in the weld. The estimated values of trapping activation energy for dislocations, microvoids, MnS and... 

Two-segmented gold-copper nanorods were electrodeposited inside the pores of polycarbonate track-etched membranes from two separate solutions. The PCT membranes were dissolved in dichloromethane (CH2Cl2) and the solvent was replaced by methanol solution. Optical absorption spectra of two-segmented Au-Cu nanorods dispersed in methanol showed two peaks which were related to the transverse mode of copper and the longitudinal mode of gold. By increasing the length of the gold segment, when the total length of both metals was fixed at 1 μm, the copper and gold peaks shifted to the blue and red wavelengths, respectively. We observed that the wavelengths of the extinction peaks are not in good...