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ekrami--aliakbar
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Mechanical Properties of TLP bonded SS304 by Two Steps Heating
, M.Sc. Thesis Sharif University of Technology ; Ekrami, Aliakbar (Supervisor)
Abstract
Austenitic stainless steels are the most common kinds of stainless steels. Although these alloys are generally very weldable, there are some problems in join- ing of them using fusion welding. Solidification and liquation cracking or corrosion at grain bound- aries in the heat-affected zone are examples of these problems. Transient liquid phase (TLP) bonding is an important variation of diffusion bonding that has the potential to overcome this problems. Two-step TLP bonding is an ingenious development to form non-planar interface. This method consists of a short-time high temperature heating to melt interlayer followed by isothermal solidification of liquid phase at a lower temperature. In...
Microstructure and Mechanical Properties of Two-step TLP Bonded 304 Stainless Steel with a Cobalt base Interlayer
, M.Sc. Thesis Sharif University of Technology ; Pouranvari, Majid (Supervisor) ; Ekrami, Aliakbar (Supervisor)
Abstract
Considering the wide applications of 304 stainless steel in various industries and the existing literature on transient liquid phase bonding of stainless steels with a variety of interlayers, the present work aimed to reduce the bonding time by using a two step bonding method. Faster bonding reduces both energy consumption during bonding and the base metal grain growth. It also leads to a lower reduction in the base metal and joint strength.Due to the melting point of the interlayer, different durations and a temperature of 1200°C were selected for the first step. This temperature was maintained for a specified period of time before it sharply dropped to and remained at 1180°C (the...
Designing and Fabrication of a Wearable Colorimetric Biosensor Based on Polyvinyl Alcohol Hydrogel with the Help of Machine Learning to Detect Glucose Concentration and PH Level of Body Sweat
, M.Sc. Thesis Sharif University of Technology ; Simchi, Abdolreza (Supervisor) ; Ekrami, Aliakbar (Supervisor)
Abstract
Simultaneous detection of pH and glucose levels in sweat is a promising tool for early skin disease detection and diabetes diagnosis. Hydrogels have attracted a lot of attention in the field of wearable biosensors due to sweat absorption capability, biocompatibility, and the ability to store enzymes and reagents in their cavities. In this research, we have presented an innovative wearable colorimetric biosensor based on polyvinyl alcohol (PVA) hydrogel, which can simultaneously measure pH level (in the range of 3-9) and glucose concentration (in the range of 0.025-0.5 mM) of sweat with the help of machine learning (ML). This wearable sensor consists of two main parts: sensors and a patch, in...
Spot Resistance Welding of St12 and HSLA Steels in Different Thicknesses
, M.Sc. Thesis Sharif University of Technology ; Kokabi, Amirhosein (Supervisor) ; Ekrami, Aliakbar (Supervisor)
Abstract
High-strength low alloy (HSLA) E275 developed specifically for automotive application. Also St12 Steel is used in autobodies. On the other hand the resistance spot weld of dissimilar materials is generally more challenging than that of similar materials due to differences in the physical, chemical and mechanical properties of the base metals. The influence of the primary welding parameters affecting the heat input such as; current and time on the morphology, fracture mode, microhardness, and tensile shear load bearing capacity of dissimilar welds between HSLA E275 steel and St12 steel in two different thicknesses (1,2 mm) has been investigated in this study which consisted six group. The...
High temperature mechanical properties of dual phase steels
, Article Materials Letters ; Volume 59, Issue 16 , 2005 , Pages 2070-2074 ; 0167577X (ISSN) ; Sharif University of Technology
2005
Abstract
Dual phase steels with different martensite volume fraction and morphology were tensile tested at temperature range of 25-550 °C. Stress-strain curves of all steels showed serration flow at temperature range of 250-450 °C and smooth flow at the other temperatures. Both yield and ultimate tensile strengths increased with increasing testing temperature up to about 450 °C and then decreased at higher temperatures. At a given temperature, yield stress, tensile strength, and work hardening increased with increasing volume fraction of martensite. Similar behavior was observed by changing martensite morphology from network to fibrous martensite. The change in mechanical properties was related to...
Comparison of gas phase intrinsic properties of cytosine and thymine nucleobases with their O-alkyl adducts: Different hydrogen bonding preferences for thymine versus O-alkyl thymine
, Article Journal of Molecular Modeling ; Volume 19, Issue 8 , 2013 , Pages 2993-3005 ; 16102940 (ISSN) ; Fattahi, A ; Sharif University of Technology
2013
Abstract
In recent years, there has been increasing interest in damaged DNA and RNA nucleobases. These damaged nucleobases can cause DNA mutation, resulting in various diseases such as cancer. Alkylating agents are mutagenic and carcinogenic in a variety of prokaryotic and eukaryotic organisms. The present study employs density functional theory (DFT/B3LYP) with the 6-311++G(d,p) basis set to investigate the effect of chemical damage in O-alkyl pyrimidines such as O4-methylthymine, O2-methylcytosine and O 2-methylthymine. We compared the intrinsic properties, such as proton affinities, gas phase acidities, equilibrium tautomerization and nucleobase pair's hydrogen bonding properties, of these...
Conformational aspects of glutathione tripeptide: Electron density topological & natural bond orbital analyses
, Article Structural Chemistry ; Volume 24, Issue 1 , 2013 , Pages 147-158 ; 10400400 (ISSN) ; Fattahi, A ; Sharif University of Technology
2013
Abstract
Glutathione tripeptide (γ-glutamyl-cysteinyl-glycine) is a flexible molecule and its conformational energy landscape is strongly influenced by forming intramolecular hydrogen bond, its charge and the environment. This study employs DFT-B3LYP method with the 6-31+G (d,p) basis set to carry out conformational analysis of neutral, zwitterionic, cationic, and anionic forms of glutathione. In analyzing the structural characteristics of these structures, intramolecular hydrogen bonds were identified and characterized in details by topological parameters such as electron density ρ(r) and Laplacian of electron density Δ2 ρ(r) from Bader's atom in molecules theory. Charge transfer energies based on...
Dynamical Systems Approach to Interacting Dark Energy Models
, M.Sc. Thesis Sharif University of Technology ; Abolhassani, Aliakbar (Supervisor)
Abstract
This thesis studies the possible solution to the H0 tension via a dynamical systems approach. The early dark energy (IDE) scenario can somewhat alleviate the Hubble constant tension. On the other hand, postulating a new subdominant EDE in the pre – recombination Universe can also resolve the H0 tension. We introduce a novel model to interweave the early dark energy(EDE) and interacting dark energy-dark matter (IDE) scenarios. In this scenario, the early dark energy emerges naturally by changing the topological class of the phase portrait of the universe dynamics. In particular, an EDE component contributing only 10% of the matter density of the Universe—preferably in the vicinity of the...
Influence of metal complexation on acidity of cytosine nucleosides: Part I, Li +, Na + and K + cation
, Article Scientia Iranica ; Volume 19, Issue 3 , June , 2012 , Pages 535-545 ; 10263098 (ISSN) ; Fattahi, A ; Pourjavadi, A ; Sharif University of Technology
2012
Abstract
Gas-phase acidities of nucleosides, combined with the knowledge of deprotonation sites, could improve our understanding of chemical reactions to biological systems. In this paper, we mainly focus our attention on the influence of cation coordination on acidities of multiple sites in cytosine nucleosides. The acidities of multiple sites in M +-L (where L represents cytosine nucleosides and M + is an alkali metal ion, including Li +, Na + and K +) complexes have been investigated theoretically, employing B3LY P6-311++G(d,p) basis sets. The geometrical characters, gas-phase acidities, sugar puckering and electronic properties of non-deprotonated and/or deprotonated complexes have been...
Conformational behavior and potential energy profile of gaseous histidine
, Article Journal of Molecular Structure: THEOCHEM ; Volume 960, Issue 1-3 , November , 2010 , Pages 73-85 ; 01661280 (ISSN) ; Tavasoli, E ; Fattahi, A ; Sharif University of Technology
2010
Abstract
Histidine as a natural amino acid is found to be biologically important and is known to function as a nucleophile or enzyme co-factor, or in proton transfer process. The properties of gaseous aromatic amino acid histidine depend on the structural forms it may take in gas-phase. Ab initio method has been used to characterize the gas-phase conformer/tautomers of histidine. Wide range of possible structures for histidine was surveyed at the MM level, and then the geometries of the unique conformers were refined at the B3LYP/6-311++G (d,p) levels. At this theoretical level, 25 conformers were located for both tautomers of histidine i.e., His [NπH] and His [NτH]. The MM level provides a poor...
Warm Inflation Model in Effective Field Theory of Axion Monodromy
, M.Sc. Thesis Sharif University of Technology ; Abolhassani, Aliakbar (Supervisor)
Abstract
Temerature fluctuation of the Cosmic Microwave Background (CMB) is one of the key observebles of the modern cosmology. Today, it is widely believed that quantum fluctuation that are stretched to horizon scales during a period of acceleration expansion -- at the onset of evolution of the universe-- are responsible for these perturbations. In the simplest scenarios of the inflation, a scalar field is responsible for both nearly expansional expansion of the universe and the proimordial fluctuations. In this thesis, we investigate the models of inflation with an additional light degree of freedom. In particular, we employ the method of the Effective Field Theory to study the general structure...
Computational investigation of thermochemical properties of non-natural C-nucloebases: Different hydrogen-bonding preferences for non-natural Watson-Crick base pairs
, Article Structural Chemistry ; Volume 24, Issue 4 , 2013 , Pages 1015-1025 ; 10400400 (ISSN) ; Shakourian Fard, M ; Fattahi, A ; Sharif University of Technology
2013
Abstract
In the present density functional theory study, we have compared intrinsic properties of non-natural nucleobases (acA, acG, acC, and acT nucleobases) such as proton affinities, gas phase acidities, tautomerization, and hydrogen-bonding properties with those in normal Watson-Crick nucleobases (A, G, C, T nucleobases). The hydrogen-bonding interactions in non-natural and Watson-Crick base pairs were studied at B3LYP/6-311++G (d,p) level regarding their geometries, energies, and topological features of the electron density. The quantum theory of atoms-in-molecule (QTAIM) and natural bond orbital (NBO) analyses were employed to elucidate the interaction characteristics in base pairs. The...
DFT study of the interaction of cytidine and 2′-deoxycytidine with Li+, Na+, and K+: effects of metal cationization on sugar puckering and stability of the N-glycosidic bond
, Article Carbohydrate Research ; Volume 344, Issue 6 , 2009 , Pages 771-778 ; 00086215 (ISSN) ; Fattahi, A. R ; Pourjavadi, A ; Sharif University of Technology
2009
Abstract
Density functional theory (DFT) calculations were performed at the B3LYP level with a 6-311++G(d,p) basis set to systematically explore the geometrical multiplicity and binding strength for complexes formed by Li+, Na+, and K+ with cytidine and 2′-deoxycytidine. All computational studies indicate that the metal ion affinity (MIA) decreases from Li+ to Na+ and K+ for cytosine nucleosides. For example, for cytidine the affinity for the above metal ions are 79.5, 55.2, and 41.8 and for 2′-deoxycytidine, 82.8, 57.4, and 42.2 kcal/mol, respectively. It is also interesting to mention that linear correlations between calculated MIA values and the atomic numbers (Z) of the above metal ions were...
Non-linear Effects on "linear point" through Analytical Methods
, M.Sc. Thesis Sharif University of Technology ; Abolhassani, Aliakbar (Supervisor)
Abstract
By studying of simulations, it can be seen that the linear point (LP), a point lies midway between the scales associated with the peak and the dip in the correlation function on BAO scales, is a useful window into cosmology and large scale structures rather than baryonic echo peak. Some fundamental features of the LP, been unaffected by redshift space distortions and gravitational non-linear effects, has made it important. I want to find evidences to stability of the LP by utilizing Standard Perturbation Theory through my thesis
Effect of Martensite Volume Fraction on Fatigue Properties of Ferrite- Bainite- Martensite Triple Phase Steel
, M.Sc. Thesis Sharif University of Technology ; Ekrami, Ali Akbar (Supervisor)
Abstract
The introduction of multi phase steels in recent years resulted in a considerable increase in development of some industries such as automobiles. By inducing soft and hard phases together, these steels could bring better mechanical properties than classical ones. Recent studies on 4340 ferritic- bainitic and ferritic- martensitic dual phase steels, indicate that 34 volume percent ferrite with hard phase, has the best combination of strength, toughness and fatigue properties. In present research, by proper heat treatment on a 4340 steel, it is tried to prepare specimens ferritic- bainitic- martensitic triple phase steels with 34 volume percent of ferrite and different percents of martensite....
Effect of Transient Liquid Phase(TLP)Diffusion Bonding on Fatingue Properties of Al 6061-SiC Composite
, M.Sc. Thesis Sharif University of Technology ; Ekrami, Ali Akbar (Supervisor)
Abstract
In the research transient liquid phase bonding of AL6061-SiC composite was performed using copper as interlayer. The joining praocess was performed in various tetemperatures (560c and 580c and 600c) And times (6 and 8 hours). Optimum Joining condition was determined by using optical and of the joint, micro hardness test was performed from the bonding zone to the bulk of the base composite. The fatigue endurance limit of Al6061-SiC composite was determined by several fatigue tests and TLP bonded samples were loaded under achieved endurance limit stress. Finally fatigue fracture surface of both base composite and TLP bonded samples were studied by using of scanning electronic microscope
Effect of TLP Bonding on Microstructure and Thermal Fatigue Properties of Co-Based FSX-414 Superalloy
, Ph.D. Dissertation Sharif University of Technology ; Ekrami, Ali Akbar (Supervisor)
Abstract
In this research, transient liquid phase (TLP) bonding of FSX-414 superalloy was investigated using MBF-80 interlayer. The bonding was performed at different temperatures (1050-1200oC) for various times (1-120min). Also, different gap sizes were studied using the interlayer with various thicknesses (25-100µm). Homogenizing treatment was performed at different temperatures (1175-1225oC) and times (1-6h) for the samples with complete isothermal solidification. The microstructure of the samples were studied using the optical, scanning electron and transmission electron microscopes. Also, XRD, SEM/EDS, SEM/WDS and TEM/EDS analyses were used to analyse the observed phases at the joints. To...
The Effect of Martensite Volume Fraction on Toughness of Triple-Phase Steels
, M.Sc. Thesis Sharif University of Technology ; Ekrami, Ali Akbar (Supervisor)
Abstract
AISI 4340 steel bars were austenitized at 900°C for 1 hour followed by heating at 740°C (ferrite and austenite region) for 100 min and quenching into a salt bath at 300°C for different times followed by quenching into water to obtain triple phase microstructures with 34 Vol.% ferrite and various martensite (or bainite) contents. Presence of three phases in adjacent of each other confirmed by metallographic analysis and TEM technique. Volume fraction of different phases was measured by image analyser. The results of optical microscopy showed that by increasing VM, morphology of martensite varies from uniform distribution of small spherical network particles to large blocky islands with...
The Effect of Interlayer Composition on Microstructure and Mechanical Properties of Transient Liquid Phase Bonded Dual Phase Steels
, M.Sc. Thesis Sharif University of Technology ; Ekrami, Ali Akbar (Supervisor)
Abstract
Interlayer composition as one of the most important factors of TLP bonding could affect bonding region composition and microstructure that both of them govern the mechanical properties of the joint. Due to the risk of substrate microstructure degradation , welding of dual phase steel needs more cautions. TLP bonding ideally acquires joints having more similar microstructure to substrate. Moreover , using this method could avoid the change of base metal microstructure when heat treatment of carbon steel is postponed until after bonding. Fe-based , Ni-based and commercially pure Cu are three different composition has been studied in this work. The bonded samples were investigated by optic and...
The Effect of Pressure on Microstructure and Mechanical Properties of TLP Bonded Dual Phase Steels
, M.Sc. Thesis Sharif University of Technology ; Ekrami, Ali Akbar (Supervisor)
Abstract
Dual Phase ferritic-martensitic steels are kind of high strength low alloy steels (HASLA) which are widely used in industry because of their strength and formability. Since welding of dual phase steels in conventional welding methods causes structural change and Subsequently alters mechanical properties of both weld zone and heat affected zone(HAZ), additional operations which are not commercially viable is needed to achieve a dual phase structure in structurally changed regions. In this study, transient liquid phase (TLP) bonding method is used during dual phasing process in order to preserve dual phase ferritic-martensitic structure and avoid extra heat treatment. Applied pressure during...