Sharif Digital Repository

This work introduces a new gradient fiber coating for microextraction of chlorobenzenes. Nanoclusters of organoclay-Cu(II) on a copper wire were fabricated by wireless electrofunctionalization. The resultant gradient coatings are more robust, and thermally and mechanically stable. Wireless electrofunctionalization was carried out in a bipolar cell under a constant deposition potential and using an ethanolic electrolyte solution containing stearic acid and montmorillonite. Stearic acid acts as an inexpensive and green coating while montmorillonite acts as a modifier to impart thermal stability. The gradient morphology of the nanoclusters was investigated by scanning electron microscopy,... 

The aim of this study is to introduce an extractive phase based on gradient concept by continuous changing in chemical functional groups for non–targeted analysis. For this purpose, three different two–component coatings containing (3–aminopropyl)trimethoxysilane (APTES) as polar and either phenyltriethoxysilane (PTES), octyl–trimethoxysilane (OTMS) or methyltrimethoxysilane (MTMS) as nonpolar precursors were formed on the modified stainless steel wires using controlled rate infusion (CRI) method. The presence of polar and/or non–polar functional groups on the surface of substrate was evaluated by Fourier–transform infrared spectroscopy (FTIR) together with contact angles determined... 

A gradient derived base layer extractive phase was synthesized and applied for the determination of volatile organic compounds (VOCs) in saliva samples using the headspace cooled in–tube microextraction (HS–CITME) method. The base layers from three different sols of phenyltriethoxysilane (PTES), octyltrimethoxysilane (OTMS) and methyltrimethoxysilane (MTMS) as nonpolar precursors were individually dip coated on the stainless steel wires (SSW). Then, the hydrolyzed polar precursor aminopropyltriethoxysilane (APTES) reacted with the silanol groups already formed on the surface of SSWs via controlled rate infusion (CRI) method. The presence of polar and non–polar functional groups on the... 

In this research, three fibers including cellulose acetate (CA), CA–phenyltriethoxysilane (PTES) prepared via sol–gel electrospinning and sol–gel–based CA fibers immersed in PTES solution (dipped–CA–PTES) were prepared. The composition and morphology of the prepared fibers were evaluated by energy dispersive X-ray spectroscopy and field emission scanning electron microscopy. The prepared fibers were implemented in a home–made needle trap device, followed by thermal desorption of the selected chlorobenzenes (CBs) to a gas chromatography–flame ionization detector. Finally, parameters affecting the extraction methodology such as the amount of sorbent, extraction time and temperature, desorption... 

An analytic expression for energy and angular dependence of a secondary charged lepton in the decay of a polarized top quark with anomalous tWb couplings in the presence of all anomalous couplings are derived. The angular distribution of the b-quark is derived as well. It is presented that the charged lepton spin correlation coefficient is not very sensitive to the anomalous couplings. However, the b-quark spin correlation coefficient is sensitive to anomalous couplings and could be used as a powerful tool in the search for non-SM coupling. © 2007 IOP Publishing Ltd  

In this paper we study the noncommutative effects to the lepton spectrum from the decay of a polarized top quark. It is shown that the lowest contribution comes from the quadratic terms of the noncommutative parameter. The deviations from the standard model are significant for small values of the noncommutative characteristic scale. However, the charged lepton spin correlation coefficient has a remarkable deviation from the standard model from very low values of the noncommutative characteristic scale to 1 TeV. © 2006 The American Physical Society  

In this article, two adaptive model predictive controllers (AMPC) are applied to regulate the blood glucose in type 1 diabetic patients. The first controller is constructed based on a linear model, while the second one is designed by using a nonlinear Hammerstein model. The adaptive version of these control schemes is considered to make them more robust against model mismatches and external disturbances. The least squares method with forgetting factor is used to update the model parameters. For simulation study, two well-known mathematical models namely, Puckett and Hovorka which describe the dynamical behavior of patient's body have been selected. The performances and robustness of the... 

The anomalous top quark interactions with gluon (tug, tcg) allow the production of single top quarks at the Large Hadron Collider (LHC). Using the angular distribution of the charged lepton from the W boson in the top decay, we show that with the data of 10 fb-1 of integrated luminosity and in the collisions with the center of mass energy of 14TeV, the anomalous up and charm quarks coupling parameters κu,c/Λ can be measured down to 0.005 and 0.007 TeV-1, respectively  

In this study, a novel type of passive energy dissipation device called a Telescopic Lead Yielding Damper (TLYD) is proposed and analyzed. This device comprises co-axial steel cylinders and lead rings, such that these rings act as shear locks between the steel cylinders. TLYDs dissipate energy through the plastic shear deformation of lead metal. The telescopic mechanism used in TLYDs allows these small-sized dampers to tolerate large axial displacements with low fatigue. For each telescopic level, a yield plateau is added to the hysteresis behavior of TLYD devices. Each yield plateau resists a different performance level, namely design-based and maximum credible earthquakes. Seven...