Sharif Digital Repository

In this study different kinds of solid phase microextraction fibers based on sol-gel technology were employed for extraction and pre-concentration of phenol in occupational air and oxadiargyl in plant and environmental samples. In the first work, a SPME method followed by on-fiber derivatization and gas chromatography-mass spectrometry detection (GC-MS) was developed for the analysis of phenol in the air. The application and feasibility of three different sol-gel based SPME fibers with different polarities, polar and non-polar poly (dimethylsiloxane) (PDMS) and polyethylene glycol (PEG), have been studied. Influential parameters such as fiber coating type, type of derivatization reagent,... 

Thiomersal is an organomercury compound. This compound is a well established antiseptic and antifungal agent. It has been used as a preservative in vaccines, immuno-globulin preparations, skin test antigens, antivenins, ophthalmic and nasal products, and tattoo inks. Thiomersal is very toxic by inhalation, ingestion, and in contact with skin, with a danger of cumulative effects. It is also very toxic to aquatic organisms and may cause long-term adverse effects in aquatic environments.
Thiomersal's main use is as an antiseptic and antifungal agent in vaccines. In multidose injectable drug delivery systems, it prevents serious adverse effects such as the Staphylococcus infection that,... 

Novel high-throughput device and their applications as the microextraction systems for pesticide multiresidue determination is the centre of this research. 96 extracting unit based on solid phase microextraction and micro-Solid phase extraction were constructed and applied for high-throughput extraction.
In the first work, a high-throughput SPME on 96-well plate together with gas chromatography-mass spectrometry was developed for the determination of pesticide residues in cucumber samples. A home-made Teflon block consisting ninety-six holes was constructed to 96 SPME fibers being positioned in. SPME fibers consisted of stainless steel rods with a 1.0 cm polydimethylsiloxane tubing... 

The purpose of the presented work entailed the development of a simple, high throughput sample preparation method for determination of a wide range of veterinary drugs at regulatory levels in milk, chicken meat and egg. pretreating the veterinary drugs include SPE pretreatment was combined with sample homogenization, acetonitrile and sodium sulphate salt extract and precipitate protein, n-hexane removal of fats, centrifugation and filtration. To proceed this goal, titania / octavinyl POSS (TiO2 / OVP) nanocomposite was prepared by sol – gel method and it was used to coat the surface of commercial cotton fabric. POSS supplies numerous organic and inorganic groups, facilitating the... 

Veterinary medicines are extensively applied in food producing animals for the treatment of various bacterial infections, so the risk of occurrence of unwanted residues in animal-derived food exists, which may have adverse effects on human health by directly causing disease via low-dose exposure and indirect harm via antibiotic resistance. The major challenges in determination of these residues stem from the complexity of matrix, as well as polar differences and low concentrations of them. This work aimed to develop a screening and quantification method for benzimidazoles, quinolones and tetracyclines residues in egg, milk and chicken muscle. For this, the sample was extracted with... 

During the recent years, manufactures and industries have paid attention to occupational health and safety of their employees. Formaldehyde is known as a probable carcinogenic agent and its large consumption made industries to consider it as a risk factor for occupational health. At vaccine production industries, Formaldehyde is used as disinfectant and stabilizer. In this study, a solid-phase microextraction (SPME) method based on kinetic and equilibrium calibration strategies was developed for monitoring of formaldehyde in the biologics production areas. The application and feasibility of three different sol-gel based SPME fibers with different polarities have been investigated. Two... 

Magnetic bearings have been introduced in recent decades to overcome the problem of energy loses due to friction in bearings of rotating machinery. In magnetic bearings, the rotor is suspended by magnetic forces without any friction. These bearings are of the two types of passive and active. In Passive Magnetic Bearings (PMB), magnetic forces are generated by permanent magnets and have the ability to tolerate a small distribution. In Active Magnetic Bearings (AMB) magnetic forces are generated by electromagnets and have the ability to tolerate larger distributions than the PMB can. Since AMB is inherently unstable, it is necessary to use controllers to stabilize it. Due to the nonlinear... 

Electricity distribution companies always strive to operate the power network efficiently and reliably so that their network be able to satisfy the growing needs for electricity. To achieve these goals in a power network, a comprehensive asset management plan with a sound policy for inspection, periodic maintenance, replacement, and disposal of depreciated equipment is required. One of the high-risk sectors of the electricity grid is the insulation section of distribution and transmission lines. In recent years, composite insulators have been used more widely because of their desirable characteristics such as: hydrophobicity, lower price, and lower weight if compared with the another... 

Alzheimer's disease is the most common type of dementia, which has been recognized as the seventh most common fatal disease in the elderly over 65 years of age. Despite all the research done to recognize and treat this disease, so far there is no cure for this disease, and even most of the chemical treatments that are prescribed for Alzheimer's patients are only effective towards reducing the symptoms of this disease and lose their effectiveness as it progresses. Therefore, in the last two decades, in order to find a way to better understand and even treat AD, scientists have reached a concept called brain frequency stimulation, which can improve people's cognitive performance without the... 

The main goal of this thesis is the design and development of a rehabilitation device for helping patients “to improve blood circulation” & retain and recover their abilities if possible that were lost during the stroke or a accident like that (my research in karaj/iran shows that it is possible by just movement of the specific body part). The focus is on hand in this thesis because Injuries to the hand are common and can be very debilitating since our hands are our primary means for interacting with our world. For rehabilitation in case of human hand there are several practices that should be done for patients either in home or in a rehabilitation center, time and money that is supposed to... 

In the past few decades, shaking tables are widely used to evaluate system response of structures under seismic excitations. These devices are used without any fundamental research performed on a shaking table system as an entity model. In most of these studies for simplicity, it is assumed that there exist no considerable vibration and displacement around the shaking tables, and no attention is paid to the peripheral substances such as soil settled under the foundation.
In this thesis, result of ambient vibration test on shaking table system (solid deck, concrete foundation and soil layer) has been presented. Precise sensors known as low frequency and high accuracy accelerometers have...