Loading...
Search for: esmailpour--reza
0.15 seconds

    Synthesis and Characterization of Tungsten (VI)Complex with Oxazine Ligand and its Catalytic Application in Oxidation of Sulfides to Sulfoxides

    , M.Sc. Thesis Sharif University of Technology Esmailpour Firoozsalary, Parvin (Author) ; Bagherzadeh, Mojtaba (Supervisor)
    Abstract
    In this study a novel oxo-diperoxo tungsten(VI) complex [WO(O2)2(phox)] was prepared by reaction of WO3 in H2O2 with oxazine-type ligand, 2-(2′-hydroxyphenyl)-5,6-dihydro-1,3-oxazine (Hphox). The complex was characterized by FTIR, 1H NMR and elemental analysis. The single-crystal X-ray diffraction studies revealed a seven coordinate tungsten center with a distorted octahedral geometry. The [WO(O2)2(phox)] complex was applied as a catalyst in efficient, and selective oxidation of sulfide to sulfoxide using 30% H2O2 or UHP as oxidants. This catalyst showed excellent catalytic activities and high selectivities in producing a variety of aryl and alkyl sulfoxides under mild conditions. To get... 

    Endurance time analysis of skewed slab-on-girder bridges: the significance of the excitation angle

    , Article Scientia Iranica ; Volume 26, Issue 4A , 2019 , Pages 2276-2285 ; 10263098 (ISSN) Esmailpour Estekanchi, H ; Ghaffari, E ; Haghani Baei, A ; Sharif University of Technology
    Sharif University of Technology  2019
    Abstract
    In this paper, the influence of the excitation angle on the Endurance Time (TCT) analysis of skewed slab-on-girdcr bridges is studied. The excitation of the structure due to the critical angle produces maximum seismic responses that are sometimes significantly higher than the average. The modeled bridges are of slab-on-girder type that are typically used as highway bridges. The bridge models have skew angles of 0, 15, 30, 45, and CO degrees. The ET excitations exerted on structures cover a broad range of hazard levels. The results provide some insight with regard to choosing multiple excitation angles so as to balance computational costs and retain acceptable accuracy for practical design... 

    Metal-insulator transition in a ternary model with long range correlated disorder

    , Article Journal of Statistical Mechanics: Theory and Experiment ; Issue 9 , 2007 ; 17425468 (ISSN) Esmailpour, A ; Cheraghchi, H ; Carpena, P ; Rahimi Tabar, M. R ; Sharif University of Technology
    2007
    Abstract
    We study the metal-insulator transition of the one-dimensional diagonal Anderson ternary model with long range correlated disorder. The starting point of the model corresponds to a ternary alloy (i.e. with three possible on-site energies), and shows a metal-insulator transition when the random distribution of site energies is assumed to have a power spectrum S(k) ∝ 1/k (2α-1). In this paper, we define a purity parameter for the ternary alloy which adjusts the occupancy probability of site potentials, and for any given α we calculate the critical purity parameter for which extended states are obtained. In this way, we show that the ternary alloy requires weaker correlations than the binary... 

    Oxazine containing molybdenum(VI)–oxodiperoxo complex immobilized on SBA-15 as highly active and selective catalyst in the oxidation of alkenes to epoxides under solvent-free conditions

    , Article Microporous and Mesoporous Materials ; Volume 251 , 2017 , Pages 173-180 ; 13871811 (ISSN) Zare, M ; Moradi Shoeili, Z ; Esmailpour, P ; Akbayrak, S ; Özkar, S ; Sharif University of Technology
    Elsevier B.V  2017
    Abstract
    Molybdenum(VI)–oxodiperoxo complex containing an oxazine ligand, ([MoO(O2)2(phox)], phox: 2-(2′-hydroxyphenyl)-5,6-dihydro-1,3-oxazine) was conveniently synthesized and immobilized onto chloro-functionalized mesoporous silica SBA-15 by covalent bonding between the chloropropyl group on the internal surface of the pores and the nitrogen atom of oxazine ligand yielding [MoO(O2)2(phox)]/SBA-15. The resulting material was characterized by FT-IR, TGA, XRD, SEM, TEM, EDX, ICP-AES, BET and UV–vis spectroscopy. The heterogeneous catalyst [MoO(O2)2(phox)]/SBA-15 was employed in the epoxidation of alkenes, exhibiting high catalytic performance and selectivity for epoxide similar to that of homogeneous... 

    Experimental Study on Hydrodynamic Behavior of Drilling Fluid by Fluidizing Granular Materials in an Annulus

    , M.Sc. Thesis Sharif University of Technology Esmailpour, Reza (Author) ; Jamshidi, Saeed (Supervisor) ; Molaei Dehkordi, Asghar (Supervisor)
    Abstract
    During the drilling process, cutting concentration in vertical and inclined wells is a common problem and major issue in designing hydraulic parameters. This is becoming more important in near bit area. Cutting transport usually is affected by several parameters such as mud rheology, flow rate, nozzle size, rotation speed, and mud weight.
    In this work it was aimed to design a new set-up to test all the factors on hole cleaning phenomenon especially in near bit area. The set-up consists of a 16 feet long flow loop, 3.28 feet height of the test section, and 3.33 inches inner diameter of the test section. Each parameter which has an impact on hole cleaning could be varied. The cutting... 

    Localization in the Anderson model with long-range correlated hopping and on-site disorders

    , Article Waves in Random and Complex Media ; Volume 25, Issue 1 , 2014 , Pages 9-17 ; ISSN: 17455030 Lotfallahzadeh, S ; Anvari, M ; Ekhtiary, N ; Esmailpour, A ; Tabar, M. R. R ; Sharif University of Technology
    2014
    Abstract
    We study the metal–insulator transition in one-dimensional Anderson binary alloy with long-range disordered hopping integrals and on-site energies using the transfer matrix method. In this model, the on-site energies and hopping integrals are distributed randomly with long-range correlations characterized by power spectrum of the type (Formula presented.), with different exponents (Formula presented.) and (Formula presented.), respectively. We determine the critical value of long-range correlation exponent of hopping integral (Formula presented.) in the presence of only off-diagonal disorder in which the transition from localized to extended states occurs in thermodynamic limit. When both of... 

    Metal-insulator transition in three-dimensional Anderson superlattice with rough interfaces

    , Article Physical Review B - Condensed Matter and Materials Physics ; Volume 85, Issue 22 , 2012 ; 10980121 (ISSN) Jafari, S ; Sheikhan, A ; Esmailpour, A ; Anvari, M ; Tabar, M. R. R ; Sharif University of Technology
    2012
    Abstract
    We study the electronic properties of superlattice with rough interfaces in two and three dimensions using the transfer-matrix method and direct diagonalization of the Anderson Hamiltonian. The system consists of layers with an average constant width, but with stochastic roughness added to the interfaces between the layers. The numerical results indicate that, in the thermodynamic limit, the two-dimensional superlattice is an insulator in the presence of even small roughness. In three-dimensional systems, however, the superlattice exhibits a metal-insulator transition with a well-defined mobility edge located at an energy E c that we compute numerically. For three-dimensional superlattice,... 

    Localization in the Anderson model with long-range correlated hopping and on-site disorders

    , Article Waves in Random and Complex Media ; Volume 25, Issue 1 , Sep , 2015 , Pages 9-17 ; 17455030 (ISSN) Lotfallahzadeh, S ; Anvari, M ; Ekhtiary, N ; Esmailpour, A ; Tabar, M. R. R ; Sharif University of Technology
    Taylor and Francis Ltd  2015
    Abstract
    We study the metal-insulator transition in one-dimensional Anderson binary alloy with long-range disordered hopping integrals and on-site energies using the transfer matrix method. In this model, the on-site energies and hopping integrals are distributed randomly with long-range correlations characterized by power spectrum of the type S(k)∝1/k(2α-1), with different exponents αε and αt, respectively. We determine the critical value of long-range correlation exponent of hopping integral in the presence of only off-diagonal disorder in which the transition from localized to extended states occurs in thermodynamic limit. When both of the on-site energies and hopping... 

    Effect of a gap opening on the conductance of graphene superlattices

    , Article Solid State Communications ; Volume 150, Issue 13-14 , 2010 , Pages 655-659 ; 00381098 (ISSN) Esmailpour, M ; Esmailpour, A ; Asgari, R ; Elahi, M ; Rahimi Tabar, M. R ; Sharif University of Technology
    2010
    Abstract
    The electronic transmission and conductance of a gapped graphene superlattice were calculated by means of the transfer-matrix method. The system that we study consists of a sequence of electron-doped graphene as wells and hole-doped graphene as barriers. We show that the transmission probability approaches unity at some critical value of the gap. We also find that there is a domain around the critical gap value for which the conductance of the system attains its maximum value  

    Metal-insulator transition in random Kronig-Penney superlattices with long-range correlated disorder

    , Article Physical Review B - Condensed Matter and Materials Physics ; Volume 74, Issue 2 , 2006 ; 10980121 (ISSN) Esmailpour, A ; Esmaeilzadeh, M ; Faizabadi, E ; Carpena, P ; Rahimi Tabar, M. R ; Sharif University of Technology
    2006
    Abstract
    We study the electronic properties of disordered GaAs- Alx Ga1-x As semiconductor superlattices with structural long-range correlations. The system consists of quantum barriers and wells with different thicknesses and heights which fluctuate around their mean values randomly, following a long-range correlated pattern of fractal type characterized by a power spectrum of the type S (k) 1 k (2α-1), where the exponent α quantifies the strength of the long-range correlations. For a given system size, we find a critical value of the exponent α (αc) for which a metal-insulator transition appears: for α< αc all the states are localized, and for α> αc, we find a continuous band of extended states. We... 

    Localization properties of acoustic waves in the random-dimer media

    , Article Physical Review B - Condensed Matter and Materials Physics ; Volume 78, Issue 13 , 2008 ; 10980121 (ISSN) Esmailpour, A ; Esmailpour, M ; Sheikhan, A ; Elahi, M ; Rahimi Tabar, M. R ; Sahimi, M ; Sharif University of Technology
    2008
    Abstract
    Propagation of acoustic waves in the one-dimensional (1D) random-dimer (RD) medium is studied by three distinct methods. First, using the transfer-matrix method, we calculate numerically the localization length ξ of acoustic waves in a binary chain (one in which the elastic constants take on one of two values). We show that when there exists short-range correlation in the medium-which corresponds to the RD model-the localization-delocalization transition occurs at a resonance frequency ωc. The divergence of ξ near ωc is studied, and the critical exponents that characterize the power-law behavior of ξ near ωc are estimated for the regimes ω> ωc and ω< ωc. Second, an exact analytical analysis... 

    A misbehavior‐tolerant multipath routing protocol for wireless Ad hoc networks [electronic resource]

    , Article International Journal of Research in Wireless Systems (IJRWS) ; Vol. 2, Issue 9, pp. , Sep. 2013 Sedghi, H. (Haniyeh) ; Pakravan, Mohammad Reza ; Aref, Mohammad Reza ; Sharif University of Technology
    Abstract
    Secure routing is a major key to service maintenance in ad hoc networks. Ad hoc nature exposes the network to several types of node misbehavior or attacks. As a result of the resource limitations in such networks nodes may have a tendency to behave selfishly. Selfish behavior can have drastic impacts on network performance. We have proposed a Misbehavior-Tolerant Multipath Routing protocol (MTMR) which detects and punishes all types of misbehavior such as selfish behavior, wormhole, sinkhole and grey-hole attacks. The protocol utilizes a proactive approach to enforce cooperation. In addition, it uses a novel data redirection method to mitigate the impact of node misbehavior on network... 

    Analysis and data-based reconstruction of complex nonlinear dynamical systems : using the methods of stochastic processes

    , Book Rahimi Tabar, M. Reza
    Springer International Publishing  2019
    Abstract
    This book focuses on a central question in the field of complex systems: Given a fluctuating (in time or space), uni- or multi-variant sequentially measured set of experimental data (even noisy data), how should one analyse non-parametrically the data, assess underlying trends, uncover characteristics of the fluctuations (including diffusion and jump contributions), and construct a stochastic evolution equation?
    Here, the term "non-parametrically" exemplifies that all the functions and parameters of the constructed stochastic evolution equation can be determined directly from the measured data.
    The book provides an overview of methods that have been developed for the analysis of... 

    Fabrication and Study of Mechanical Behavior of in Situ Microfibrillar- Reinforced Composites of Polypropylene/Recycled Poly (Ethylene Terephthalate)Toughened with Rubber Particles

    , M.Sc. Thesis Sharif University of Technology Motahari, Tayebeh (Author) ; Bagheri, Reza (Supervisor) ; Alizadeh, Reza (Supervisor)
    Abstract
    The use of polymers is increasing day by day due to low density, reasonable price and ability to produce different products. On the other hand, the accumulation of polymer wastes in nature is one of the environmental concerns in today's world, which is mainly due to the widespread use of polymers in the packaging industry and disposable applications. In order to solve this problem, recycling is recommended as the most appropriate and economical solution. Because in addition to consuming polymer waste, it also saves energy and reduces carbon footprint.Polyethylene terephthalate (PET) is one of the polymeric materials which; It has a special place in the packaging industry and is widely used... 

    Characterization of Mechanical Properties of Polymer Nanocomposites with Spherical Inhomogeneities

    , M.Sc. Thesis Sharif University of Technology Goudarzi, Taha (Author) ; Naghdabadi, Reza (Supervisor) ; Bagheri, Reza (Supervisor)
    Abstract
    The improved properties of nanocomposites are not achievable with conventional composites. Scale effect is one the most important parameters in the physical and mechanical properties of polymeric nanocomposites. One of the physical phenomena, which can be related to the scale effect, is the very large interface between the nanoparticles and the polymeric matrices. Motional behavior and conformation of polymeric chains change near the nanoparticles surfaces. Due to high interface of the nanoparticles with the polymeric matrices the amount of these types of changes in the polymeric chains are so large that can change the physical and mechanical properties of polymeric nanocomposites. In this... 

    On small uniquely vertex-colourable graphs and Xu's conjecture [electronic resource]

    , Article Discrete Mathematics ; Volume 223, Issues 1–3, 28 August 2000, Pages 93–108 Daneshgar, A. (Amir) ; Naserasr, Reza ; Sharif University of Technology
    Abstract
    Consider the parameter Λ(G) = |E(G)| - |V(G)|(k - 1) + (k2) for a k-chromatic graph G, on the set of vertices V(G) and with the set of edges E(G). It is known that Λ(G)≥0 for any k-chromatic uniquely vertex-colourable graph G (k-UCG), and, S.J. Xu has conjectured that for any k-UCG, G, Λ(G) = 0 implies that cl(G) = k; in which cl(G) is the clique number of G. In this paper, first, we introduce the concept of the core of a k-UCG as an induced subgraph without any colour-class of size one, and without any vertex of degree k - 1. Considering (k, n)-cores as k-UCGs on n vertices, we show that edge-minimal (k, 2k)-cores do not exist when k ≥ 3, which shows that for any edge-minimal k-UCG on 2k... 

    Molecular Dynamics Simulation of Nano-Diamond Synthesis by Shock Wave

    , Ph.D. Dissertation Sharif University of Technology Mahnama, Maryam (Author) ; Naghdabadi, Reza (Supervisor) ; Movahhedy, Mohammad Reza (Co-Advisor)
    Abstract
    In the field of high-pressure material science, diverse carbon systems under pressure have been intensively studied with interest in synthesizing new phases. A variety of these synthetic phases which have met various applications in today technology are called the amorphous diamond. The pressure-induced structural transition of carbonaceous material to amorphous diamond is realized by shock compression and rapid quenching. The shock compression and rapid quenching generate the high pressure (several GPa) and the temperature (several hundred K) in a fraction of a microsecond.Since the mechanical and electrical properties of the synthetic diamond are severely sensitive to the atomic structure,... 

    An Experimental Study of the Effects of Sweep Wing on the Boundary Layer of 2D Wing

    , M.Sc. Thesis Sharif University of Technology Tabrizian, Arshia (Author) ; Soltani, Mohammad Reza (Supervisor) ; Davari, Ali Reza (Co-Advisor)
    Abstract
    The behavior of boundary layer under the effect of the sweep angle is considered. The measurements were performed by a pitot tube rake. Three models with various sweep angels at angles of attack -2, 0 and 2 degree were tested. Both tip and root of all wings were closed by flat plates in order to prevent the flow to roll-up. However the flow field on the wing was still three-dimensional because of the sweep angle. The velocity on the wing has two components; longitudinal and lateral. The cross flow emerges due to the non-equilibrium of pressure and centrifugal forces. The velocity profiles showed that the magnitude of cross flow was stronger near the leading edge of the wing. The cross flow... 

    Synthesis of Antibiotic-eluting Chitosan-based Composite Coating by Electrophoretic Deposition for Bone Implants

    , M.Sc. Thesis Sharif University of Technology Bakhshi, Zahra (Author) ; Simchi, Abdol Reza (Supervisor) ; Bagheri, Reza (Supervisor)
    Abstract
    Drug-eluting bone implant coatings is a new era that has gained a lot of attention in recent years. In this matter, drug is loaded in the coating and local and targeted release of the drug results in preventing the side effects of implantation and increasing the healing process of the patient. The aim of this project was to synthesis the antibiotic eluting chitosan-based composite using electrophoretic deposition for bone implant coating. By using electrophoretic deposition chitosan and chitosan-bioglass composite coatings were synthesized. Then the probability of loading of drug into coating by using electrophoretic deposition was evaluated and by using this process chitosan and... 

    Solving High-Dimensional Differential Equations Using Machine Learning

    , M.Sc. Thesis Sharif University of Technology Saffarieh, Pooya (Author) ; Razvan, Mohammad Reza (Supervisor) ; Moghadasi, Reza (Co-Supervisor)
    Abstract
    The numerical solution of differential equations in high dimensions has always been a challenge and has been associated with various computational difficulties. These equations appear naturally in a variety of problems such as financial mathematics, control, and physics, and their optimal solution with high accuracy and speed can open new windows on new applications. Conventional methods such as Finite element and finite difference method in high dimensions lose their efficiency, which is a barrier to fast and accurate calculation of these equations. In this dissertation first, we review some theoretical and practical aspects of deep neural networks and then we try to examine the recent...