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es’haghi-gorji--zahra
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Preparation and Evaluation of Hydrophobic Pt Catalyst on Alumina and CNT to Produce Heavy Water Isotope
, M.Sc. Thesis Sharif University of Technology ; Kazemeini, Mohammad (Supervisor)
Abstract
Liquide phase catalytic exchange (LPCE) between liquid water and hydrogen is an important reaction for separation of the hydrogen isotope from liquid water. One of the application of this reaction is heavy water production. This method is mainly used hydrophobic catalysts with Pt active metal. The use of hydrophobic catalyst is necessary, because liquid water in the LPCE reaction, resulted in block the catalyst pores and loss of catalyst activity. Design of experiment has been done by using of Design Expert 7.0.0 for determination of number of tests and optimization of Pt weight percent. Alumina and carbon (included graphene, single-walled and multi-walled carbon nanotube) supported 5% wt Pt...
Investigation of bed Stability in Downstream for the Diversion dam under Scour (Mill & Moghan case study)
, M.Sc. Thesis Sharif University of Technology ; Shamsai, Abolfazl (Supervisor)
Abstract
Numerical simulations and large eddy simulations (LES) of turbulent flow downstream of diversion dam , pool-riffle bedform in different geometrical ratios (different lengths of riffle and pool) with flow Reynolds number of 3.0 E+04 to 3.3E+04, downstream of special case study "Mill and Moghan diversion dam" with Froude number of 0.5 are presented The calculations are performed using a computational fluid dynamics model, FLOW-3D, which solves the Navier-Stokes equations in three dimensions with finite volume method. Numerical simulations are validated by comparing the numerical results of time-averaged flow patterns downstream of pool-riffle sequence with that of the experimental...
The Effect of Heat Treatment on Microsructure, Hot Tensile Properties and Creep Bihavior of Nickel-based Superalloy CM88Y
, M.Sc. Thesis Sharif University of Technology ; Asgari, Sirous (Supervisor)
Abstract
The Ni-base superalloy CM88Y has good hot corrosion resistance, high stability and strength at elevated temperature; accordingly, the alloy is used in manufacturing of gas turbine hot components. In most applications, heat treatment is required in order to achieve the desired mechanical properties and corrosion resistance of the working conditions; often three stages of heat treatment is designed for precipitation hardening nickel-base superalloy. In general, the effective parameters of heat treatment cycles includes temperature, time, heating rate and the cooling rate. In this study, the effect of cooling rate from partial solution temperature (second stage of heat treatment) on the...
Optimum kinetic and gas hold up distribution study in an NDMA hydrogenation reactor
, Article 18th International Congress of Chemical and Process Engineering, CHISA 2008, Prague, 24 August 2008 through 28 August 2008 ; 2008 ; Kazemeini, M ; Sharif University of Technology
2008
Abstract
Unsymmetrical Dimethyl hydrazine (UDMH) is used as stabilizer, fuel promoter, chemical in photography, and liquid fuel for fighter jet engines. Catalytic liquid phase hydrogenation of nitrosodimethylamine (NDMA) is one of the most efficient methods for the production of UDMH. Hydrogenation of NDMA to UDMH using a commercial 5% Pd/C catalyst in aqueous solution of NDMA was studied under constant temperature at 40°-70°C, ≤ 15 bar, and NDMA concentrations of 40-70 wt %. The effects of temperature, pressure, and NDMA concentration on NDMA conversion and yield of UDMH product in presence of undesired Dimethylamine (DMA) were studied. At NDMA concentration of > 50 wt %, the UDMH yield was < 0.89,...
X-Band Receiver Design in 0.15um GaAs
, M.Sc. Thesis Sharif University of Technology ; Medi, Ali (Supervisor)
Abstract
RF Receivers are one of the main components of telecommunication systems, which can be composed of many parts and circuits according to their working frequency and application.In this thesis, the design and simulation of an X-band Receiver in 0.15um GaAs technology has been discussed. The receiver chain, in the order of receiving the signal, includes the main blocks of limiter, attenuator, low noise amplifier and mixer. It also includes a number of filters. The attenuator has two digital bits and the receiving chain filters are implemented in such a way to provide more than 20dB attenuation in the frequency band of the image signal. In this research, the limiter is implemented with a...
Analysis of Group Formation in Social Networks Using Evolutionary Game Theory
, M.Sc. Thesis Sharif University of Technology ; Ramezanian, Rasoul (Supervisor)
Abstract
Evolutionary game theory is a relatively new branch of game theory (in contrast to the classical game theory) which has overcome some of the common problems of the classical version such as highly rational agents assumption. Because of this, it has gained popularity among different sciences. On the other hand, social network as one of the branches of complex networks is a pretty novel research area and has application in several fields. Networks are everywhere and most real-world networks are complex ones. Group formation and evolution are among important subjects in studying social networks and some works has been done in analyzing and modeling them. In this thesis we have presented a...
An experimental kinetic optimization of NDMA hydrogenation to UDMH and DMA on a Pd/C catalyst
, Article CHISA 2006 - 17th International Congress of Chemical and Process Engineering, Prague, 27 August 2006 through 31 August 2006 ; 2006 ; 8086059456 (ISBN); 9788086059457 (ISBN) ; Kazememi, M ; Bozorgmehri, R ; Sharif University of Technology
2006
Abstract
The Unsymmetrical dimethyl hydrazine (UDMH) apart from its use as a versatile rocket fuel, finds numerous industrial applications. Interest in UDMH for various applications in the missile and rocket industry has prompted the study of this member of hydrazine family to greater extent. It can be prepared in several ways but one of the most efficient ones which results in higher yields is the catalytic hydrogenation of Nitroso Dimethylamine (NDMA). In this work the kinetic of NDMA to UDMH hydrogenation on a 5% Pd/C in aqueous solution of NDMA was studied experimentally and optimum conditions of the reaction for maximum yield of UDMH in the presence of undesired dimethyl amine (DMA) product was...
Kinetic investigation of NDMA to UDMH hydrogenation on a pd/C catalyst
, Article Iranian Journal of Science and Technology, Transaction B: Engineering ; Volume 30, Issue 5 , 2006 , Pages 581-593 ; 03601307 (ISSN) ; Kazemeini, M ; Bozorgmehri, R ; Sharif University of Technology
2006
Abstract
Unsymmetrical dimethyl hydrazine (UDMH) is a strong propellant, which due to its very good physical properties and high power of repellency has been utilized as a liquid fuel for fighter jet engines for so many years. There are different methods for production of this material. One of the more efficient ones which results in higher yields compared to others is the catalytic hydrogenation of Nitroso Dimethylamine (NDMA). In this work hydrogenation of NDMA to UDMH on a 5% Pd/C in aqueous solution of NDMA was studied experimentally. Experiments were carried out in a Semi-batch three phase STR reactor under constant pressure and temperature in the range of 40 to 70°C, pressures of up to 15 bar...
Modeling the instability behavior of thin film devices: Fermi Level Pinning
, Article Superlattices and Microstructures ; Volume 117 , 2018 , Pages 399-405 ; 07496036 (ISSN) ; Ahmadpour, M ; Gorji, N. E ; Sharif University of Technology
Academic Press
2018
Abstract
We investigate the underlying physics of degradation/recovery of a metal/n-CdTe Schottcky junction under reverse or forward bias stressing conditions. We used Sah-Noyce-Shockley (SNS) theory to investigate if the swept of Fermi level pinning at different levels (under forward/reverse bias) is the origin of change in current-voltage characteristics of the device. This theory is based on Shockley-Read-Hall recombination within the depletion width and takes into account the interface defect levels. Fermi Level Pinning theory was primarily introduced by Ponpon and developed to thin film solar cells by Dharmadasa's group in Sheffield University-UK. The theory suggests that Fermi level pinning at...
CFD modeling of gas-liquid hydrodynamics in a stirred tank reactor
, Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 26, Issue 2 , 2007 , Pages 85-96 ; 10219986 (ISSN) ; Bozorgmehry Bozzarjomehry, R ; Kazemeini, M ; Sharif University of Technology
2007
Abstract
Multiphase impeller stirred tank reactors enhance mixing of reacting species used in a variety of chemical industries. These reactors have been studied based on Computational Fluid Dynamics (CFD) that can be used in the analysis, design and scale up of these reactors. Most of the researches done in this area are limited to single phase reactors, and a few remaining two phase flow investigations have been done based on MRF (Multi Reference Frame) and Snapshot approach. However, the MRF and snapshot approaches cannot be used in rigorous simulation of unsteady state problems. In order to simulate the unsteady state behavior of the multiphase stirred tank reactors we have used sliding mesh...
A three dimensional CFD modeling of hydrodynamics and mass transfer in a gas-liquid impeller stirred tank reactor
, Article CHISA 2006 - 17th International Congress of Chemical and Process Engineering, Prague, 27 August 2006 through 31 August 2006 ; 2006 ; 8086059456 (ISBN); 9788086059457 (ISBN) ; Bozorgmehry Boozarjomehry, R ; Kazemeini, M ; Sharif University of Technology
2006
Abstract
Multiphase impeller stirred tank reactors enhance mixing of reacting species used in a variety of chemical industries. Gas-liquid mixing and mass transfer between these phases is an important application in reactor design. One such an example is hydrogenation reaction of aqueous NDMA (Nitroso dimethyl amine) solution in which one of the parameters having a significant effect on the reaction rate is mass transfer. This parameter in turn is a function of impeller shape and rotational speed, gas flow rate and reactor scale. Computational Fluid Dynamics (CFD) is a useful tool in the analysis, design and scale up of stirred tank reactors via investigating hydrodynamics of gas and liquid flow,...
Design and Implementation of Bio-impedance Sensor Circuits
, M.Sc. Thesis Sharif University of Technology ; Sharifkhani, Mohammad (Supervisor)
Abstract
Heart failure is a chronic and significant disease that affects millions of people worldwide. Despite advances in medical technology and treatment options, heart failure remains a leading cause of death globally. This has led to a growing interest in developing new diagnostic tools and therapeutic strategies that can improve the control of this disease. One promising field is bioimpedance spectroscopy, which is a non-invasive method for measuring the electrical properties of biological tissues in the body. Monitoring the condition of fluid accumulation in the lungs of heart failure patients is effective in reducing the death rate caused by this disease. In this thesis, a portable device for...
Mesoporous silica nanoparticles (MCM-41) coated PEGylated chitosan as a pH-Responsive nanocarrier for triggered release of erythromycin [electronic resource]
, Article International Journal of Polymeric Materials and Polymeric Biomaterials ; 2014, Volume 63, Issue 13, Pages 692-697 ; Mazaheri Tehrani, Zahra ; Sharif University of Technology
Abstract
A pH-responsive drug delivery system based on core shell structure of mesoporous silica nanoparticle (MSN) and chitosan-PEG copolymer was prepared and characterized by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), scanning electron microscope (SEM), and high-resolution transmission microscope (HR-TEM) techniques. In order to improve compatibility MSN and drug, mesoporous nanosilica was modified by 3-aminopropyl triethoxysilane. The release of erythromycin (a macrolide antibiotic) as a model drug was investigated in two pHs, 7.4 and 5.5
Development of composite silver/nickel nanopastes for low temperature Joining of yttria-stabilized zirconia to stainless steels
, Article Ceramics International ; Volume 41, Issue 1 , January , 2015 , Pages 1815-1822 ; 02728842 (ISSN) ; Simchi, A ; Kokabi, A. H ; Sharif University of Technology
Elsevier Ltd
2015
Abstract
Joining of yttria-stabilized zirconia (YSZ) to stainless steels is considered for various applications such as solid oxide fuel cells, thermal barrier coatings, and medical implants. In the present work, a series of brazing pastes utilizing silver and nickel nanoparticles (∼80 nm) mixed with carboxymethyl cellulose as the organic phase were developed to join 5 mol% YSZ to AISI 420 steel. Effects of processing parameters including time and temperature of brazing and the composition of the nanopastes on the microstructure of joints and their shear rupture strength were studied. Elaboration of the joining mechanism by scanning electron microscopy and electron probe micro-analyzer showed...
Optimizing the materials response in humidity capacitive sensors
, Article Journal of Nano- and Electronic Physics ; Volume 7, Issue 3 , October , 2015 ; 20776772 (ISSN) ; Golnabi, H ; Gorji, N. E ; Sharif University of Technology
Sumy State University
2015
Abstract
The number of humidity outputs on the cap of a cylindrical capacitance sensor is optimized by designing three different probes with direct and indirect windows. The time interval is measured within which 30- 70 % humidity can influence the dielectric constant and conductivity of the capacitance when exposed to a range of relative humidity. It is then compared with a simple set-up including a simplified equivalent circuit. The direct probes had four and double outputs on the window of the cylindrical capacitive sensor while the indirect probe had a thin plastic layer only. We observed that the dielectric constant and its conductivity depend closely to the humidity outgoing pathway and also to...
Modeling of J sc and V oc versus the grain size in CdTe, CZTS and Perovskite thin film solar cells
, Article Superlattices and Microstructures ; Volume 128 , 2019 , Pages 421-427 ; 07496036 (ISSN) ; Pourasiab Dizaj, H ; Gorji, N. E ; Sharif University of Technology
Academic Press
2019
Abstract
A modeling approach is presented for the first time to model the dependence of short-circuit current density (J sc ) and open-circuit voltage (V oc ) on the grain size g in three thin film solar cells including the emerging perovskites. The variation of J sc and V oc with the grain size (g) of three different solar cells with CdTe, CZTS and perovskite absorber layers are modelled and fitted with the experimental dataset collected from relevant literature. The experimental literature suggested that the grain size of absorber layers in solar cells is controlled during the deposition process by adjusting the growth rate, temperature and ambient. The model has been successfully applied to the...
Using Nonlinear Effects of Light for Optical Signal Processing
, M.Sc. Thesis Sharif University of Technology ; Kavehvash, Zahra (Supervisor)
Abstract
Ultrafast signal processing in time-domain with high resolution and reconfigura-bility is a challenging task. This paper, for the first time, introduces a time-varying metasurface consisting of graphene microribbon array for implementing time-lens in the terahertz domain. Given that the surface conductivity of graphene is proportional to the Fermi energy level in the THz regime, it is possible to change the phase property of the incident electromagnetic pulse by changing the Fermi level while the Fermi level itself is a function of voltage. Upon this fact, a quadratic temporal phase modulator, namely time-lens has been realized. This phase modulation is applied to the impinging signal in the...
Theoretical and Computational Investigation of Quantum Plasmonic Properties of Nanocluster Dimers
, M.Sc. Thesis Sharif University of Technology ; Jamshidi, Zahra (Supervisor)
Abstract
In today's era, metal nanoparticles play an important role in technologies emerging from different sciences, such as chemistry, physics, optics, material science, due to their unique characteristics. In the development of nanooptics science, it can be said that metal nanoparticles play an important role. The ability of conductive electrons collective oscillation causes surface charge density fluctuations in nanoparticles, this phenomenon is known as surface plasmons. Surface plasmons are surprisingly coupled with light and cause the significant increase in the intensity of optical fields induced in nanoparticles. Therefore, with the presence of localized surface plasmons or plasmon...
Theoretical Investigation of Ab-initio MD Approach to Increase the Efficiency and Accuracy of VCD Spectrum Calculation
, M.Sc. Thesis Sharif University of Technology ; Jamshidi, Zahra (Supervisor)
Abstract
Understanding of the Molecules is the main purpose of the chemistry. Ab-initio molecular dynamics (AIMD) as a branch of the computational chemistry, tries to give us a deep comprehension of the molecule, and its chemical, physical and optical activities. This comprehension, relies on the accuracy of quantum mechanics, in addition to the speed of the classical mechanics. The mixing of the quantum mechanics and the classical mechanics could simulate activities of the atoms in the time-domain, provided the mixing is done with precaution. This, in turn, helps us to forecast the response of a molecule in different situations, and also translating the macroscopic phenomena in a nanoscopic...
Investigation of Plasmonic Excitation in Carbonic Nanostructures Within Near-IR
, M.Sc. Thesis Sharif University of Technology ; Jamshidi, Zahra (Supervisor)
Abstract
To date, the plasmonic properties of many metallic and semi-conducting materials have been investigated and used in various industries. One of the plasmonic material categories that have always been considered is polycyclic aromatic hydrocarbon or PAH, whose plasmonic resonance energy depends on the charge state of the molecule. In this regard, it is easy to change the plasmonic resonance energy via changing the induced charge, which is a unique feature of the mentioned materials. In addition, plasmonic structures with excitations in the infrared region are able to enhance the vibration intensity of absorbed molecules by increasing the electric field around themselves. Therefore, they have...