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    The role of powder preparation route on physical and mechanical properties of Cu-rGO bulk nanocomposites

    , Article Materials Today Communications ; Volume 28 , 2021 ; 23524928 (ISSN) Fahimi, N ; Abachi, P ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    To study the effect of the production method on physical and mechanical properties of Cu-rGO nanocomposites, nanocomposite powder samples with rGO content of 0.25–1 wt.% were prepared via combined routes of molecular-level mixing (MLM) and powder metallurgy (PM). Spark plasma sintering (SPS) was applied to consolidate nanocomposite powders with better control on the grain size. According to the specific electrical resistivity measurements, microhardness, and pin-on-disk wear tests, the sample with 0.5 wt.% rGO comprised the best overall properties. For assessment, samples containing 0.5 wt.% rGO were also produced via PM and MLM routes, separately. The physical and mechanical properties of... 

    Production of Copper-Graphene Nanocomposites Via Molecular Level Mixing, Evaluation of the Effect of Some Processing Parameters on Micro-Structure and Physical-Mechanical Properties

    , M.Sc. Thesis Sharif University of Technology Fahimi, Negar (Author) ; Abachi, Parvin (Supervisor)
    Abstract
    This research aimed at production of Cu-rGO via the combination of Molecular-Level-Mixing (MLM) method and powder metallurgy route (PM). First, Cu-GO composite powder was produced via MLM method. Subsequently, the resultant powder was mixed with electrolytic copper powder.Synthesis process included adjustment of the solution containing copper sulfate and 2Na.EDTA using NaOH solution. In the next step, GO suspension was added to the aforementioned solution. Finally, reduction of copper powder and formation of nanocomposite powder completed via the addition of Sodium Borohydrate. Nanocomposite powder was washed and dried in vacuum oven in 70˚C. GO reduction process took place using a tube... 

    Development and Simulation of Metallic Mesostructures Manufacturing Process by Integrated Vat Polymerization and Electroforming

    , M.Sc. Thesis Sharif University of Technology Fahimi Hanzaei, Amir (Author) ; Akbari, Javad (Supervisor)
    Abstract
    Nowadays, metallic microsystems such as miniature and meso-scale gears, microgrippers, and comb structures constitute a significant portion of key components in various microelectromechanical systems (MEMS). Due to their extremely lightweight nature, small size, high dimensional accuracy, superior performance, and extended lifetime, the manufacturing process of these microsystems has always been a subject of discussion and research. The goal is to enhance the strength and precision of the products while reducing production costs.LIGA and wire-cut electrical discharge machining (WEDM) are two well-known methods for fabricating microstructurs. Despite their advantages, such as high dimensional... 

    Gold-nanoparticle-based colorimetric sensor array for discrimination of organophosphate pesticides

    , Article Analytical Chemistry ; Volume 88, Issue 16 , 2016 , Pages 8099-8106 ; 00032700 (ISSN) Fahimi Kashani, N ; Hormozi Nezhad, M. R ; Sharif University of Technology
    American Chemical Society  2016
    Abstract
    There is a growing interest in developing high-performance sensors monitoring organophosphate pesticides, primarily due to their broad usage and harmful effects on mammals. In the present study, a colorimetric sensor array consisting of citrate-capped 13 nm gold nanoparticles (AuNPs) has been proposed for the detection and discrimination of several organophosphate pesticides (OPs). The aggregation-induced spectral changes of AuNPs upon OP addition has been analyzed with pattern recognition techniques, including hierarchical cluster analysis (HCA) and linear discriminant analysis (LDA). In addition, the proposed sensor array has the capability to identify individual OPs or mixtures of them in... 

    Gold nanorod-based chrono-colorimetric sensor arrays: a promising platform for chemical discrimination applications

    , Article ACS Omega ; Volume 3, Issue 2 , 2018 , Pages 1386-1394 ; 24701343 (ISSN) Fahimi Kashani, N ; Hormozi Nezhad, M. R ; Sharif University of Technology
    American Chemical Society  2018
    Abstract
    Most array-based sensing platforms, to date, utilize static response patterns for discrimination of a wide variety of analytes, but only a few studies have focused on the important task of quantitatively resolving structural isomers, which are nowadays important because of their broad usage in medicines and industries. A possible way of accomplishing this feat is to combine kinetic (rather than static) sensor response profiles with the chemical tongue strategy to allow the development of array-based sensors for isomeric discrimination. Here, by adding the time dimension, a simple and novel gold nanorod (AuNR)-based chrono-colorimetric sensor array is proposed for chemical discrimination... 

    A smart-phone based ratiometric nanoprobe for label-free detection of methyl parathion

    , Article Sensors and Actuators, B: Chemical ; Volume 322 , 2020 Fahimi Kashani, N ; Hormozi Nezhad, M. R ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    The widespread use of pesticides in pest management has boosted the demands for developing highly sensitive probes for on-site monitoring. Herein we presented a sensitive enzyme-free ratiometric probe for determination of methyl parathion (MP), as an organophosphate pesticide using TGA-capped CdTe QDs and carbon dots (CDs). Unlike previous methods in which hydrolysis product of MP is instrumental in the response of the sensors, here, self-assembly of cetyltrimethylammonium bromide (CTAB) on the surface of non-modified yellow-emissive CdTe QDs facilitates the quenching of CTAB-QDs upon addition of MP while the fluorescence intensity of CDs remains constant. Using a smartphone, the ratiometric... 

    A Comprehensive Machine Learning-Based Approach to Seismic Loss and Repair Time Assessment of Special Steel Moment-Resisting Frame Structures

    , M.Sc. Thesis Sharif University of Technology Fahimi, Alireza (Author) ; Rahimzadeh Rofooei, Fayaz (Supervisor)
    Abstract
    Assessing the seismic loss incurred by structures post-earthquake, or to evaluate structural performance vis-à-vis potential seismic events, constitutes an imperative and pivotal measure for informed decision-making geared towards enhancing community resilience. However, large-scale assessments targeting risk analysis at citywide levels necessitate significant temporal and computational resources. To expedite this process and mitigate associated costs, this study introduces a machine learning-based methodology for estimating seismic loss and repair time of special steel moment-resisting frames. Six distinct machine learning models were trained based on results derived from nonlinear time... 

    Performance Assesment of Ordinary Structures with Concrete Bearing Wall by Endurance Time Method

    , M.Sc. Thesis Sharif University of Technology Fahimi Farzam, Maziar (Author) ; Esmaeil Pourestekanchi, Homayoon (Supervisor)
    Abstract
    In high seismically active regions, such as Iran, shear walls are one of the preferred seismic force resisting system.The efficiency of reinforced concrete bearing walls for resisting lateral forces and controlling lateral drift in high-rise buildings has long been recognized. But in recent decades shear wall dominant buildings or so called tunnel form buildings have been increasingly constructed as the multi-story reinforced concrete buildings. The purpose of this thesis is to assess the seismic performance of concrete shear walls that provide gravity as well as sesmic resistance for this kind of buildings. The studied walls were assumed to be part of 5- 10- 20- and 40- story residential... 

    A colorimetric assay for d-Penicillamine in urine and plasma samples based on the aggregation of gold nanoparticles

    , Article Journal of the Iranian Chemical Society ; Vol. 11, issue. 5 , Dec , 2014 , p. 1249-1255 Hormozi-Nezhad, M. R ; Azargun, M ; Fahimi-Kashani, N ; Sharif University of Technology
    2014
    Abstract
    We report herein the development of a highly sensitive colorimetric method for detection of d-Penicillamine using citrate-capped gold nanoparticles (AuNPs). This assay relies upon the distance-dependent of gold nanoparticles surface plasmon resonance band of gold nanoparticles. By replacing the thiol-containing chelator drug, d-Penicillamine, with citrate on the gold nanoparticles surface, a new peak appearing at a longer wavelength intensifies and shifts further to the red from the original peak position due to aggregation of gold nanoparticles which depends on ionic strength, gold nanoparticles and d-Penicillamine concentration. During this process, the plasmon band at 521 nm decreases... 

    Colorimetric detection of glutathione based on transverse overgrowth of high aspect ratio gold nanorods investigated by MCR-ALS

    , Article RSC Advances ; Volume 5, Issue 101 , 2015 , Pages 82906-82915 ; 20462069 (ISSN) Fahimi Kashani, N ; Shadabipour, P ; Hormozi-Nezhad, M. R ; Sharif University of Technology
    Royal Society of Chemistry  2015
    Abstract
    In this paper, we present a simple platform for colorimetric detection of glutathione using gold nanorods (AR ∼ 6.5 ± 0.2) as a plasmonic sensor. The functional mechanism of the sensor is based on shifts of longitudinal plasmon resonance during selective transverse overgrowth induced by preferential binding of glutathione at the nanorod tips. Under the optimum conditions, a calibration curve showed two linear regimes at the range of 50 nM to 20 μM of glutathione with a detection limit as low as 40 nM. The nanosensor maintains relatively high selectivity for determination of glutathione in the presence of several other amino acids. However, cysteine at similar concentration levels strongly... 

    Colorimetric Sensing of Nitrite and Glutathione Based on Morphological Changes of High Aspect Ratio of Gold Nanorods

    , M.Sc. Thesis Sharif University of Technology Fahimi - Kashani, Nafiseh (Author) ; Hormozi Nezhad, Mohammad Reza (Supervisor)
    Abstract
    The fascinating size-dependent properties of noble metal nanop articles have created a great promise for their use in a different applications specially chemical sensing. Gold nanorods (GNRs), specifically, have received a great deal of attention due to their unusual optical properties. The nanoscale confinement of electrons on the surface of gold nanorods grants them aspect ratio-dependent properties not seen in larger particles. Due to the intriguing properties of GNRs, significant work has gone into the application of nanorods for sensing and detection of various an alytes in biological and other systems. The major modalities which have been developed for... 

    Optical Sensor Arrays Based on Nanostructured Materials for Quantitative Detection and Qualitative Discrimination of Pesticides and Structural Isomers

    , Ph.D. Dissertation Sharif University of Technology Fahimi-Kashani, Nafiseh (Author) ; Hormozi-Nezhad, Mohammad Reza (Supervisor)
    Abstract
    There is a growing interest in developing high-performance sensors monitoring organophosphate pesticides, primarily due to their broad usage and harmful effects on mammals. In the first part of this research, by introducing conditional sensor elements (CSE), a colorimetric sensor array has been proposed for the detection and discrimination of several organophosphate pesticides (OPs). citrate-capped 13 nm gold nanoparticles (AuNPs) at nine different pH/ionic strengths were employed as simple plasmonic sensing elements in the development of a colorimetric sensor array for the detection and discrimination of five organophosphate pesticides, including azinphos-methyl (AM), chlorpyrifos (CP),... 

    MoS2 quantum-dots as a label-free fluorescent nanoprobe for the highly selective detection of methyl parathion pesticide

    , Article Analytical Methods ; Volume 9, Issue 4 , 2017 , Pages 716-723 ; 17599660 (ISSN) Fahimi Kashani, N ; Rashti, A ; Hormozi Nezhad, M. R ; Mahdavi, V ; Sharif University of Technology
    Royal Society of Chemistry  2017
    Abstract
    A reliable, simple, and sensitive fluorescence method was developed for the determination of methyl parathion (MP) in rice using MoS2 quantum dots (QDs). Rapid hydrolysis of MP under alkaline conditions, and thus the formation of p-nitrophenol (p-NP) can be used for MP detection. The functional mechanism of the nanoprobe relies on p-nitrophenol-induced photoluminescence quenching of MoS2 QDs. The high probability of resonance energy transfer (RET) stems from the spectral overlap of MoS2 QD emission spectra and the absorption spectra of p-NP. The high value of the Stern-Volmer constant (KSV = 3.73 × 104 M-1) suggests the efficient quenching of MoS2 QDs by MP in the course of the ET process.... 

    Mining the potential of label-free biosensors for in vitro antipsychotic drug screening

    , Article Biosensors ; Volume 8, Issue 1 , 2018 ; 20796374 (ISSN) Kilic, T ; Soler, M ; Fahimi Kashani, N ; Altug, H ; Carrara, S ; Sharif University of Technology
    MDPI AG  2018
    Abstract
    The pharmaceutical industry is facing enormous challenges due to high drug attribution rates. For the past decades, novel methods have been developed for safety and efficacy testing, as well as for improving early development stages. In vitro screening methods for drug-receptor binding are considered to be good alternatives for decreasing costs in the identification of drug candidates. However, these methods require lengthy and troublesome labeling steps. Biosensors hold great promise due to the fact that label-free detection schemes can be designed in an easy and low-cost manner. In this paper, for the first time in the literature, we aimed to compare the potential of label-free optical and... 

    Visual recognition of tryptophan enantiomers using chiral self assemblies of quantum dots

    , Article ACS Applied Nano Materials ; 2021 ; 25740970 (ISSN) Fahimi Kashani, N ; Jafar Nezhad Ivrigh, Z ; Bigdeli, A ; Hormozi Nezhad, M.R ; Sharif University of Technology
    American Chemical Society  2021
    Abstract
    Discrimination of chiral targets is generally achieved with chiral nanomaterials. However, the limited number of intrinsic chiral nanostructures as well as their complex synthesis procedure has led to the production of chirality-induced nanomaterials as alternatives. Chirality can be induced in nanomaterials by either chirality transfer or the formation of chiral assemblies. Using the latter approach, in this work, we have provided chiral supramolecular assemblies of CdTe quantum dots (QDs) from achiral starting materials. CTAB-QD assemblies showed chiroptical activities, and their orange emission in combination with the blue emission of carbon dots was utilized as a ratiometric chiral... 

    Visual recognition of tryptophan enantiomers using chiral self assemblies of quantum DOTS

    , Article ACS Applied Nano Materials ; Volume 5, Issue 1 , 2022 , Pages 1460-1471 ; 25740970 (ISSN) Fahimi-Kashani, N ; Jafar Nezhad Ivrigh, Z ; Bigdeli, A ; Hormozi Nezhad, M. R ; Sharif University of Technology
    American Chemical Society  2022
    Abstract
    Discrimination of chiral targets is generally achieved with chiral nanomaterials. However, the limited number of intrinsic chiral nanostructures as well as their complex synthesis procedure has led to the production of chirality-induced nanomaterials as alternatives. Chirality can be induced in nanomaterials by either chirality transfer or the formation of chiral assemblies. Using the latter approach, in this work, we have provided chiral supramolecular assemblies of CdTe quantum dots (QDs) from achiral starting materials. CTAB-QD assemblies showed chiroptical activities, and their orange emission in combination with the blue emission of carbon dots was utilized as a ratiometric chiral... 

    Plasmonic noble metal (Ag and Au) nanoparticles: from basics to colorimetric sensing applications

    , Article Gold and Silver Nanoparticles: Synthesis and Applications ; 2023 , Pages 1-58 ; 978-032399454-5 (ISBN) Fahimi Kashani, N ; Orouji, A ; Ghamsari, M ; Sahoo, S. K ; Hormozi Nezhad, M. R ; Sharif University of Technology
    Elsevier  2023
    Abstract
    The unique optical properties of plasmonic gold (Au) and silver Ag) nanoparticles (NPs) due to localized surface plasmon resonance (LSPR), surface modifications of Au and Ag NPs through non-covalent/covalent conjugations, and their applications in colorimetric detection of various ionic and neutral analytes are discussed in this chapter. The chapter begin with the basics of LSPR phenomenon, and then the effects like surrounding medium, composition, size, shape, structural configuration and interparticle coupling that influenced the LSPR of Au and Ag NPs are discussed. The different design principles for colorimetric assays using plasmonic Au and Ag NPs, such as analyte-induced aggregation... 

    Ratiometric fluorescent nanoprobes for visual detection: Design principles and recent advances - A review

    , Article Analytica Chimica Acta ; Volume 1079 , 2019 , Pages 30-58 ; 00032670 (ISSN) Bigdeli, A ; Ghasemi, F ; Abbasi Moayed, S ; Shahrajabian, M ; Fahimi Kashani, N ; Jafarinejad, S ; Farahmand Nejad, M. A ; Hormozi Nezhad, M. R ; Sharif University of Technology
    Elsevier B.V  2019
    Abstract
    Signal generation techniques for visual detection of analytes have received a great deal of attention in various sensing fields. These approaches are considered to be advantageous when instrumentation cannot be employed, such as for on-site assays, point-of-care tests, and he althcare diagnostics in resource-constrained areas. Amongst various visual detection approaches explored for non-invasive quantitative measurements, ratiometric fluorescence sensing has received particular attention as a potential method to overcome the limitations of intensity-based probes. This technique relies on changes in the intensity of two or more emission bands (induced by an analyte), resulting in an effective... 

    Optical nanoprobes for chiral discrimination

    , Article Analyst ; Volume 145, Issue 20 , 2020 , Pages 6416-6434 Bigdeli, A ; Ghasemi, F ; Fahimi Kashani, N ; Abbasi Moayed, S ; Orouji, A ; Jafar Nezhad Ivrigh, Z ; Shahdost Fard, F ; Hormozi Nezhad, M. R ; Sharif University of Technology
    Royal Society of Chemistry  2020
    Abstract
    Chiral discrimination has always been a hot topic in chemical, food and pharmaceutical industries, especially when dealing with chiral drugs. Enantiomeric recognition not only leads to better understanding of the mechanism of molecular recognition in biological systems, but may further assist in developing useful molecular devices in biochemical and pharmaceutical studies. By emerging nanotechnology and exploiting nanomaterials in sensing applications, a great deal of attention has been given to the design of optical nanoprobes that are able to discriminate enantiomers of chiral analytes. This review explains how engineering nanoparticles (NPs) with desired physicochemical properties allows... 

    Nanoparticle-based optical sensor arrays

    , Article Nanoscale ; v. 9 , 2017 , pages 16546 – 16563 ; 2040-3364 Hormozi-Nezhad, M. R ; Bigdeli, Arafeh ; Ghasemi, Forough ; Golmohammadi, Hamed ; Abbasi-Moayed, Samira ; Farahmand Nejad, M. Amin ; Fahimi-Kashani, Nafiseh ; Jafarinejad, Somayeh ; Shahrajabian, Maryam ; Sharif University of Technology
    Royal Society of Chemistry  2017
    Abstract
    As in many other methods that have integrated nanoparticles (NPs), the chemical nose/tongue strategy has also progressed greatly since the entrance of NPs into this field. The fascinating tunable physicochemical properties of NPs have made them powerful candidates for array-based sensing platforms and have enabled the development of real-time, sensitive and portable systems that are able to target complex mixtures of analytes. In particular, the unique optical properties of NPs have a key role in providing promising array-based sensing approaches. This review will describe the main aspects and processes of most common NP-based optical sensor arrays. The fundamental steps in the design of a...