Sharif Digital Repository

The fascinating size-dependent properties of noble metal nanop articles have created a great promise for their use in a different applications specially chemical sensing. Gold nanorods (GNRs), specifically, have received a great deal of attention due to their unusual optical properties. The nanoscale confinement of electrons on the surface of gold nanorods grants them aspect ratio-dependent properties not seen in larger particles. Due to the intriguing properties of GNRs, significant work has gone into the application of nanorods for sensing and detection of various an alytes in biological and other systems. The major modalities which have been developed for... 

There is a growing interest in developing high-performance sensors monitoring organophosphate pesticides, primarily due to their broad usage and harmful effects on mammals. In the first part of this research, by introducing conditional sensor elements (CSE), a colorimetric sensor array has been proposed for the detection and discrimination of several organophosphate pesticides (OPs). citrate-capped 13 nm gold nanoparticles (AuNPs) at nine different pH/ionic strengths were employed as simple plasmonic sensing elements in the development of a colorimetric sensor array for the detection and discrimination of five organophosphate pesticides, including azinphos-methyl (AM), chlorpyrifos (CP),... 

In the nuclear industry, gas centrifuges are considered of high importance for the purpose of uranium enrichment. Today, with advances in science and technology, the use of gas centrifuges for separating isotopes other than uranium, is so common. With respect to the use of conventional methods such as Pancake equation in calculating the velocity profile in centrifuges, it is needed that A^2=(MV^2)/2RT≫1 (M: Feed molecular weight; V: Peripheral speed of centrifuge; T: Mean temperature of feed; R: The universal constant of gases). While the molecular weight of the feed mixture gets lower, the A2 parameter gets closer to one. So, other methods for modeling the behavior of the gas in the... 

The Vehicle Routing Problem with Simultaneous Pick-up and Delivery (VRPSPD) and maximum time for traversing of each tour is a variant of the classical vehicle routing problem (VRP) where clients require simultaneous delivery and pick-up. Deliveries are supplied from a single depot at the beginning of the vehicle’s service, while pick-up loads are taken to the same depot at the conclusion of the service. Also the required time for traversing each route should not encroach the specified limit.
In this research, the aforesaid problem was introduced and a mixed integer programming model developed for it. Because of being NP-Hard and impossibility of solving it in the large instances, two... 

The purpose of this study is to provide a framework to demonstrate the organizational capabilities of chemical knowledge-based firms and analyze the relationship between these capabilities and exports. For this purpose, by combining 18 different output-based indicators, a model that includes six technological, manufacturing, research and development, marketing, organization and finance capabilities, was designed. Finally, in addition to analyzing the relationship between exports and the level of capabilities of knowledge-based firms, a comparison between the two groups of export and non-export firms and the analysis of these firms' current export situation was made in the period 2015-2018.... 

The purpose of this study is to present a suitable model for calculating the costs imposed on society due to deaths and injuries due to infrastructure failure due to earthquakes, which is used in the analysis of community resilience. Much research has been done to date to calculate the economic costs of infrastructure failure. However, no suitable analytical framework has been provided to quantify the costs of deaths and injuries to people due to earthquake failure. Previous research has provided methods such as the value of statistical life to quantify the social costs caused by accidents and environmental pollution. However, the literature review results in the field of seismic resilience... 

Fault occurrence is an inevitable problem in industrial plants. These faults have numerous types. Some common kinds of faults are faults in actuators, faults in system dynamics, and faults in sensors. In many cases it is not possible to change or repair the broken part immediately. On the other hand, it is not reasonable to shut-down the whole system due to a minor failure. Therefore we should take a measure to have the best output possible in a faulty plant. In this thesis we have proposed a new static compensator by which we distribute the contribution of the faulty actuator among the other ones. At the end we evaluate the method by means of simulations  

Given a set of obstacles as an arrangement of geometric shapes in the plane, we would like to find a path from the initial point s to the target point t that crosses the minimum number of obstacles. In other words, the goal is to determine the minimum number of obstacles that need to be removed to exist a collision-free path between s and t.On one hand, this problem can be used for measuring the strength of barrier coverage which is a fundamental concept in wireless sensor networks (WSNs), and on the other hand, it has been considered as a robot motion-planning problem. The objective of barrier coverage is to guarantee that any path from the start point to the target point, will intersect at... 

Electrodeposition is an old, well known and conventional science surface modification method to improve the surface characteristics, decorative and functional, of a wide variety of materials. This science is considered in nanotechnology as a bottom-up method for fabrication of one, two and three-dimensional nanomaterials. A great variety of secondary components can be added to plating baths resulting in metallic matrix composite and nanocomposite coatings production. Low amounts of iron addition for alloying zinc coatings, significantly increases the corrosion resistance of this generally used metal economically. Superhydrophobic coatings on metallic substrates have shown, during the past... 

High-quality online services demand reliable and fast packet delivery at the network layer. However, clear evidence documents the existence of compromised routers in the ISP and enterprise networks, threatening network availability and reliability. A compromised router can stealthily drop, modify, inject, or delay packets in the forwarding path to launch Denial-of-Service, surveillance, man-in-the-middle attacks, etc. So researches tried to create intrusion detection methods to identify adversarial routers and switches. To this end, data-plane fault localization (FL) aims to identify faulty links and is an effective means of achieving high network availability. FL protocols use... 

Confining nematic liquid crystal between two curved boundary conditions while the nematic molecules have a degenerate planar anchoring leads to complex and beautiful textures of molecular disparagement(defect) in the bulk and on the surfaces. Such the liquid crystal shells are made with double-emulsion techniques in microfluidic devices have provided applications for micro-scale colloidal linkers.In this work, we have numerically minimized the elastic energy in one-constant approximation in present of Fournier’s degenerate surface potential with finite element method. The nematic shell is confined between two spherical surfaces that we have studied the final energies and their related... 

Today, by emerging wearable technologies and digital health, it is possible to constantly monitor vital signals of people without time-consuming and costly referrals to medical centers. Applications of wearable sensors for health monitoring include electrocardiograms (ECG), blood pressure measurement, and blood sugar measurement, etc. One of the important fields of health monitoring is cardiac arrhythmia detection. Cardiac arrhythmia is any kind of anomalies in heart beat rhythm that can lead to serious damage to vital organs of the body. It is estimated that between 750 thousand to 1.5 million people are facing cardiac arrhythmia in Iran. Therefore, early detection of cardiac arrhythmia is... 

Secure routing is a major key to service maintenance in wireless ad hoc networks. Ad hoc nature exposes the network to several types of node misbehavior or attacks. Wormhole attack is one of the most severe active attacks to mobile ad hoc networks. Noting the resource limitations in such networks, nodes may have a tendency to behave selfishly. Selfish behavior can have drastic impacts on network performance. We have proposed a Misbehavior-Tolerant Multipath Routing protocol (MTMR) which detects and punishes all types of misbehavior such as selfish behavior, wormhole, sinkhole and grey-hole attacks. The protocol utilizes a proactive approach to enforce cooperation. In addition, it uses a... 

Providing high bandwidth network infrastructures for ever increasing need of data transport is of great importance. The underling infrastructure for many communication services such as GSM/3G/4G mobile networks and Internet services is Synchronous Digital Hierarchy (SDH) optical transport systems. SDH are standardized protocols that multiplex multiple lower rate digital bit streams, such as E1 and Ethernet, and transfer them synchronously over optical fiber using lasers or LEDs. In addition to high data transfer rates, flexible network management and protection mechanisms have great importance, hence are part of SDH standards. In order to obtain flexible network architecture and protected... 

Development of Smart Grid and deployment of smart meters in large scale has raised a lot of concerns regarding customers’ privacy. Consequently, several schemes have been proposed to overcome the above mentioned issue. These schemes mainly rely on data aggregation as a method of protecting users’ privacy from the grid operators. However, the main problem with most of these schemes is the fact that they require a large amount of processing power at the meter side. This, together with the fact that smart meters don’t usually have a powerful processor, can cause the unavailability of smart meter data at the required time for operators of the grid, and at the same time disables smart meters from... 

A liquid crystal is a state of matter composed of highly anisotropic building blocks. When liquid crystals are exposed to surfaces with given shapes and anchoring conditions, the orientation of their molecules gets spatially disordered and topological defects may form in the system. The interplay between liquid crystals and the geometry and topology of the colloidal particles has motivated extensive recent studies.In this thesis, we present the numerical modeling results for two faceted colloidal particles in a thermotropic nematic liquid crystal. To obtain the equilibrium nematic field with a finiteelement method, we numerically minimize the free energy of the system that based on the... 

Spine column is the most important musculoskeletal structures. One of the serious health problems in societies, especially among aged population is osteoporosis. Loss of bone density in bone structures is called osteoporosis which increases the risk of fracture due to a decrease of bone stiffness and bone strength. Spine is the most common sites for osteoporosis-related fractures. Current assessment of osteoporosis status is based on bone densitometry tools like QCT (Quantitative Computed Tomography) or DEXA (Dual Energy X-ray absorptiometry). With these methods it is only possible to estimate density without any consideration the morphology of trabecular making parts like rods and plates....