Sharif Digital Repository

Since, presence of sulfur compounds in fuels leads to environmental pollution and deacrese of fuel quality, fuel desulfurization should be considered for enhancing the fuel charachteristics. Electrochemical desulfurization was recogonized as one of desulfurization techniques that uses anode and cathode in an electrolytic environment under mild temperature and pressure. In this research, electrochemical desulfurization of crude gas-oil has been studied over electrodes of copper and stainless steel in the presence of NaOH and sulfuric acid. In this research, the effects of operational prameters like stirring rate, temperature, applied potential, sodium hydroxide/sulfuric acid addition as... 

In recent years, the biodegradation of micro-contaminants using enzymes has attracted the attention of many researchers in the field of environment and health. Micro- and nano-scale environments play an important role in enzymatic catalysis that directly affects the activity and stability of enzymes. Therefore, setting a nanoscale environment for enzymes is very important, especially in liquids with undesirable properties (such as pH, temperature, toxicity, etc.) in this work, a method proposed in which the pH and the substrate concentration are regulated for enzymatic catalysis using a metal-organic framework, consisting of Glucose Oxidase (GOx) and Horseradish Peroxidase (HRP) immobilized... 

The appearance of water in pipe lines of the natural gas transportation would cause several problems. In this regard, disparate methods have been developed to produce and refine of the natural gas, and one of the most common method is adsorption process. In this study, modeling and simulation of the adsorption process in the packed bed of zeolite 4A has been done. This research includes four steps, first, adsorption process and all types of adsorbent were investigated. Second, using rigorous solution method, equations of mass and energy balance derived. Third, using the collocation method and MATLAB programing, system equations of mass and energy was solved. Finally, accuracy of simulation... 

While intrusion detection systems (IDSs) are widely used, large number of alerts as well as high rate of false positive events make such a security mechanism insufficient. Accordingly, a track of recent security research, focused on alert correlation. This thesis proposes a Hidden Markov Model (HMM) based correlation method of intrusion alerts which have been fired from different IDS sensors across an enterprise. We used HMM to predict the next attack class of the intruder that is also known as plan recognition. Our method has two advantages. Firstly, it does not require any usage or modeling of network topology, system vulnerabilities, and system configurations. Secondly, as we perform high... 

In this thesis, we propose two new network coding-based packet relaying schemes suitable for multiple unicast scenarios in a random access network. In such networks the channels may have memory dependent upon the random access scheme. Thus, the optimal scheme for memoryless channels reported recently in the literature is not necessarily optimal in random access networks. In our proposed schemes, we convert a multiple unicast scenario to a combination of multiple anycast and a few multicast scenarios. By such an approach, we exploit the channels between relay node and the other nodes, instead of using only one channel at each packet transmission, for as many as possible. By simple analytical... 

Liquid ammonia atmospheric tank (20000 ton) attached to Pardis Petrochemical Complex was ruptured on 8th August 2011 due to overpressure blast injury so that ammonia gas was spread throughout the complex. The current study was aimed to evaluate ammonia leakage and emission from the tank. For this purpose, in addition to evaluate ammonia emission into the air, pressure changes were investigated to simulate the rupture. First of all, ammonia tanks and urea stocks were simulated and then considering two aerial classes (D and B), the incident was stimulated. According to this model, up to 1000 m, was contaminated with 1000 ppm of ammonia. Since there was no experimental data for validating the... 

The aim of this project is Industrial Solvents (White Spirit) producing in Tehran Refinery. For this manner “Wild Naphtha” from Gasoil Hydrotreater and Kerosene Hydrotreater Units was chosen as feed stock for solvents preparation. In addition, Pentane Recovery Column is selected for Simulation and Optimization based on Wild Naphtha. As a Result, Abadan White Spirit 402 and 410 has been produced and a side stream which is full of Aromatic is obtained. Simultaneously, Tray Hydraulics and Solvents production in different cases (Various Pressure and different Split Ratio of Feed Stock) are evaluated, so optimum Tower process conditions such as pressure, Temperature and Split Ratio of Feed Stock... 

Many industrial systems have on/off actuators. Traditionally, these systems are controlled using traditional control methods, like PID controller. The performance of this controller is not ideal for these systems, especially in term of transient response and power consumption. Due to the large number of constraints for these systems, to improve the performance of them, it is necessary to use the model predictive control technic. The decision variables of these systems are integer, hence it is necessary to develop the model predictive control method based on integer programming, which is the subject of this thesis. The main challenge in the development of this model predictive control method,... 

Injecting several droplets with a known size distribution function in the hot gas environment makes droplets smaller because of evaporation or reaction. Droplets lifetime specification is important in vapor-liquid interactive processes such as chemical or process industries. In previous works, different approximate semi-empirical methods are developed to specify droplets lifetime without considering their size distribution. In this work, governing equations is studiedconsidering a size distribution function for droplets. There is not any analytical method for solving this set of equations, so numerical methods using CFD packages such as Fluent, are applicable in these cases. In this study,... 

This thesis is concerned with an optimal trade-off between communication overhead and the number and size of neighborhoods in a distributed optimal control technique for large-scale systems that is based on the Jacobi iteration and two-layer architecture for communication. Although this method efficiently reduces computational overhead, continuous and proper data transfer between subsystems that are very often far from each other, is required to achieve an acceptable performance. However, limited transmission bandwidth and short communication range result in significant communication overhead. This causes significant time latency between measurement and applied calculated control actions,... 

The present thesis is concerned with design and development of automated irrigation system pilot. This system is obtained by equipping each regulating gate of irrigation network with a controlling hardware. This hardware is designed and developed in this project for Iran’s regulating gate, which are either slide gate or radial gate. This hardware consists of a) Ultrasonic sensor for measure gate upstream water level, b) Wireless modem for exchanging measurements between automated gates, c) controller, d) Electric motor and driver, e) shaft encoder and f) adaptor. The satisfactory performance of this hardware is shown via several experiments on the pilot  

Abstract: In this dissertation, the problem of tracking and stabilization of nonlinear dynamic systems over the packet erasure channel is addressed. Using the idea of linearization of nonlinear system around current working point, and by the design of an encoder, decoder, and controller for the linearized system, state tracking and reference tracking of the nonlinear system are addressed. To prove the traking and stability of the system, the strong law of large numbers and the dwell time approach are used. By computer simulations, the theoretical development is applied on the nonlinear dynamic of the unicycle model, which is a suitable model for autonomous vehicles, such as drones, unmanned...