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Synthesis and Evaluation of Alumina Nanocomposite Membranes for Gas Separation
, M.Sc. Thesis Sharif University of Technology ; Safekordi, Aliakbar (Supervisor) ; Rashidzadeh, Mehdi (Supervisor) ; Khanbabaei, Ghader (Co-Advisor) ; Rahimpour, Mohammad Reza (Co-Advisor)
Abstract
Membrane processes are accounted as the newest technology for gas separation and nowadays are more applicable in different petroleum, gas and petrochemical industries because of abundant advantages. One of important application of membrane gas separation technology is syngas adjustment and hydrogen enrichment. In this research, the appropriate alumina nanocomposite membranes for this purpose are prepared and their gas separation performance is investigated. Therefore the mixed matrix membranes, containing the continues polymeric phase polyethersulfone and dispersed phase alumina nanoparticles is synthesized by using methods of experimental design. As the best of our knowledge, there is no...
Simulation of Residual Oil Displacement at the Pore-scale
, M.Sc. Thesis Sharif University of Technology ; Moosavi, Ali (Supervisor) ; Shafii, Mohammad Behshad (Supervisor)
Abstract
EOR (oil enhanced recovery) is very important as oil is a nonrenewable resource. Depending on the characteristics of the rock formation, primary production can result in the recovery of up to 20% of the oil originally in the rock. This means that at least 80% of the oil may remain in the rock unless additional technology is used to increase the recovery. Before finding best way to do for EOR, scientists must study properties of different porous media that oil is trapped between its grains. Most of research and studies investigate networks of porous media but this work focused on oil movement through a pore space in porous media lonely not in network by waterflooding. Studying a pore space is...
A misbehavior‐tolerant multipath routing protocol for wireless Ad hoc networks [electronic resource]
, Article International Journal of Research in Wireless Systems (IJRWS) ; Vol. 2, Issue 9, pp. , Sep. 2013 ; Pakravan, Mohammad Reza ; Aref, Mohammad Reza ; Sharif University of Technology
Abstract
Secure routing is a major key to service maintenance in ad hoc networks. Ad hoc nature exposes the network to several types of node misbehavior or attacks. As a result of the resource limitations in such networks nodes may have a tendency to behave selfishly. Selfish behavior can have drastic impacts on network performance. We have proposed a Misbehavior-Tolerant Multipath Routing protocol (MTMR) which detects and punishes all types of misbehavior such as selfish behavior, wormhole, sinkhole and grey-hole attacks. The protocol utilizes a proactive approach to enforce cooperation. In addition, it uses a novel data redirection method to mitigate the impact of node misbehavior on network...
Fabrication and evaluation of nanocomposite membranes of polyethersulfone/α-alumina for hydrogen separation
, Article Iranian Polymer Journal (English Edition) ; Volume 24, Issue 3 , 2015 , Pages 171-183 ; 10261265 (ISSN) ; Rashidzadeh, M ; Safekordi, A ; Khanbabaei, G ; Sharif University of Technology
Springer-Verlag London Ltd
2015
Abstract
In this study, polyethersulfone (PES)-based nanocomposite membranes with the incorporation of inorganic filler of α-alumina were prepared via thermal phase inversion method. The fabricated flat sheet-mixed matrix membranes were characterized using X-ray diffraction, thermal gravimetric analysis, differential scanning calorimetry, scanning electron microscopy, and atomic force microscope analysis, and the permeation tests were performed for hydrogen, nitrogen and carbon dioxide. Also prepared α-alumina particles were identified by X-ray diffraction and the surface area, total pore volume and average pore diameter of particles were measured with a high-speed gas-sorption analyzer. The...
Analysis and Improvement of Intrusion Detection Methods in Data Network Routers
, M.Sc. Thesis Sharif University of Technology ; Aref, Mohammad Reza (Supervisor) ; Pakravan, Mohammad Reza (Co-Advisor)
Abstract
High-quality online services demand reliable and fast packet delivery at the network layer. However, clear evidence documents the existence of compromised routers in the ISP and enterprise networks, threatening network availability and reliability. A compromised router can stealthily drop, modify, inject, or delay packets in the forwarding path to launch Denial-of-Service, surveillance, man-in-the-middle attacks, etc. So researches tried to create intrusion detection methods to identify adversarial routers and switches. To this end, data-plane fault localization (FL) aims to identify faulty links and is an effective means of achieving high network availability. FL protocols use...
Topological Defects in Confined Nematics by Planar Anchoring
, M.Sc. Thesis Sharif University of Technology ; Ejtehadi, Mohammad Reza (Supervisor) ; Mozaffari, Mohammad Reza (Supervisor)
Abstract
Confining nematic liquid crystal between two curved boundary conditions while the nematic molecules have a degenerate planar anchoring leads to complex and beautiful textures of molecular disparagement(defect) in the bulk and on the surfaces. Such the liquid crystal shells are made with double-emulsion techniques in microfluidic devices have provided applications for micro-scale colloidal linkers.In this work, we have numerically minimized the elastic energy in one-constant approximation in present of Fournier’s degenerate surface potential with finite element method. The nematic shell is confined between two spherical surfaces that we have studied the final energies and their related...
Solving Symmetric Nonlinear Equations System Using BFGS Trust Region Quadratic Method
, M.Sc. Thesis Sharif University of Technology ; Razvan, Mohammad Reza (Supervisor) ; Peyghami, Mohammad Reza (Supervisor)Effect of the Geometry of Colloidal Particles on Nematic Liquid Crystals
, Ph.D. Dissertation Sharif University of Technology ; Ejtehadi, Mohammad Reza (Supervisor) ; Mozaffari, Mohammad Reza (Co-Advisor)
Abstract
A liquid crystal is a state of matter composed of highly anisotropic building blocks. When liquid crystals are exposed to surfaces with given shapes and anchoring conditions, the orientation of their molecules gets spatially disordered and topological defects may form in the system. The interplay between liquid crystals and the geometry and topology of the colloidal particles has motivated extensive recent studies.In this thesis, we present the numerical modeling results for two faceted colloidal particles in a thermotropic nematic liquid crystal. To obtain the equilibrium nematic field with a finiteelement method, we numerically minimize the free energy of the system that based on the...
Design and Implementation of 2.5 Gbps Circuit Switching Fabric
, M.Sc. Thesis Sharif University of Technology ; Pakravan, Mohammad Reza (Supervisor) ; Movahhedy, Mohammad Reza (Supervisor)
Abstract
Providing high bandwidth network infrastructures for ever increasing need of data transport is of great importance. The underling infrastructure for many communication services such as GSM/3G/4G mobile networks and Internet services is Synchronous Digital Hierarchy (SDH) optical transport systems. SDH are standardized protocols that multiplex multiple lower rate digital bit streams, such as E1 and Ethernet, and transfer them synchronously over optical fiber using lasers or LEDs. In addition to high data transfer rates, flexible network management and protection mechanisms have great importance, hence are part of SDH standards. In order to obtain flexible network architecture and protected...
Preserving Privacy in Smart Grid
, M.Sc. Thesis Sharif University of Technology ; Aref, Mohammad Reza (Supervisor) ; Pakravan, Mohammad Reza (Co-Advisor)
Abstract
Development of Smart Grid and deployment of smart meters in large scale has raised a lot of concerns regarding customers’ privacy. Consequently, several schemes have been proposed to overcome the above mentioned issue. These schemes mainly rely on data aggregation as a method of protecting users’ privacy from the grid operators. However, the main problem with most of these schemes is the fact that they require a large amount of processing power at the meter side. This, together with the fact that smart meters don’t usually have a powerful processor, can cause the unavailability of smart meter data at the required time for operators of the grid, and at the same time disables smart meters from...
Improvement of Routing Security in Ad Hoc Networks Against Several Attacks
, M.Sc. Thesis Sharif University of Technology ; Aref, Mohammad Reza (Supervisor) ; Pakravan, Mohammad Reza (Supervisor)
Abstract
Secure routing is a major key to service maintenance in wireless ad hoc networks. Ad hoc nature exposes the network to several types of node misbehavior or attacks. Wormhole attack is one of the most severe active attacks to mobile ad hoc networks. Noting the resource limitations in such networks, nodes may have a tendency to behave selfishly. Selfish behavior can have drastic impacts on network performance. We have proposed a Misbehavior-Tolerant Multipath Routing protocol (MTMR) which detects and punishes all types of misbehavior such as selfish behavior, wormhole, sinkhole and grey-hole attacks. The protocol utilizes a proactive approach to enforce cooperation. In addition, it uses a...
Design and Develop of a new Multivariate Control Chart for Image based Process Control based on Principal Component Analysis for Multivariate non Normal Distribution
, M.Sc. Thesis Sharif University of Technology ; Akhavan Niaki, Taghi (Supervisor)
Abstract
Control charts have always had an undeniable role in Statistical Control of processes in many fields. The growth of quality characteristics to be monitored, has led to the vast utilization of multivariate control charts. These variables are characterized by relatively high correlation between them. The complicated structure of measured variables has lessened the reliability of conventional control charts. Projection methods have been developed to address the problem of high correlated variables by transforming the correlated variables to an uncorrelated set of variables. Among them, Principal Component Analysis based control charts have been widely used to overcome the problem of correlated...
Solving Nonlinear Systems of Mixed Iqualities and Inequalities Via Trust Region Quadratic Methods
, M.Sc. Thesis Sharif University of Technology ; Razvan, Mohammad Reza (Supervisor) ; Payghami, Mohammad Reza (Supervisor)Jamming Resilient Algorithms for Rendezvous in Cognitive Radio Networks
, M.Sc. Thesis Sharif University of Technology ; Aref, Mohammad Reza (Supervisor) ; Pakravan, Mohammad Reza (Co-Advisor)
Abstract
Dynamic spectrum access with the aid of cognitive radio (CR) technology is a viable solution to spectrum scarcity. There are many military and emergency applications that require the use of cognitive radio ad-hoc networks (CRAHNs). In these net- works, nodes must first find each other in a wide spectrum and then exchange their desired data. The process of finding each other in a multichannel environment is a challenging task and is usually known as rendezvous. Since rendezvous is the first step in communication, disrupting will disable the nodes from establishing proper communication sessions. That results in a drastic degrade in the performance of the network. Therefore, it is important to...
Numerical Study of Spray Impingement to Solid Wall
, M.Sc. Thesis Sharif University of Technology ; Morad, Mohammad Reza (Supervisor) ; Jahannama, Mohammad Reza (Co-Supervisor)
Abstract
Spray-wall impingement is one of the phenomenon that associated in different subject such as spray cooling, combustion chamber and gas turbine. With the impingement of spray to the wall, liquid film begins to form. Wall film characteristics is still an important subject to study. Due to the various stages of liquid film formation from injection of spray till spray-wall impingement, the investigation of this phenomenon is far more complicated. This paper is meant to provide detailed data on spray-wall impingement and wall film formation physics with the help of computational analysis of OpenFOAM . A Lagrangian-Eulerian method based on discrete phase model (DPM) was employed to model...
Assessing and Improving Algorithms to Control the Propagation of Light through Scattering Media
, M.Sc. Thesis Sharif University of Technology ; Rahimitabar, Mohammad Reza (Supervisor) ; Nasiriavanaki, Mohammad Reza (Supervisor)
Abstract
Light propagation through turbid media, such as biological tissues, experience scattering due to inhomogeneous distribution of refractive indices of their microscopic structure. Scattering and diffusion of light not only limit many optical imaging techniques, but are also big challenges for telecommunication, spectroscopy, and other optical techniques. Recently many new imaging methods are developed that work in strongly scattering media such as optical coherence tomography, diffusion tomography, and laser speckle velocimetry. In this thesis, we have studied how wavefront shaping techniques can tackle the problem of scattering. By spatially shaping the wavefront of the incident beam, using...
Photocatalytic mechanism of action of apatite-coated Ag=AgBr=TiO 2 on phenol and Escherichia coli and Bacillus subtilis bacteria under various conditions
, Article Progress in Reaction Kinetics and Mechanism ; Vol. 1 , Vol.36 (1) , 2011 , pp.38-52 ; Gholami, M. R. (Mohammad Reza) ; Rahimnejad, S. (Sara) ; Pourbaba, R. (Reza) ; Haghighi, S.(Saeed) ; Sharif University Of Technology
2011
Abstract
Multi-component photocatalysts based on apatite-coated Ag/AgBr/TiO(2) were prepared by the deposition method. The effects of various kinds of apatites, with hydroxyl and fluoro substituents, on photocatalytic activity were investigated. The antibacterial processes in the dark, and under visible light, on two types of bacteria indicate that the multi-composites can inhibit the growth of bacteria by two different mechanisms. TEM images and optical microscopic data demonstrate that by attaching the nanosize catalyst to the outer membrane of the cell, the bacteria could not derive nourishment from surrounding media, i.e. this component acts as bacteria-static. The mechanism for deactivation of...
Solvatochromic Probes Absorbance Behavior in Mixtures of 2-Hydroxy ethyl ammonium formate with methanol, ethylene glycol and glycerol
, Article Journal of Solution Chemistry ; Volume 39, Issue 10 , October , 2010 , pp 1509-1519 ; Harifi-Mood, A. R. (Ali Reza) ; Elahifard, M. R. (Mohammad Reza) ; Gholami, M. R. (Mohammad Reza) ; Sharif University of Technology
2010
Abstract
Solute-solvent and solvent-solvent interactions were investigated for binary mixtures of an ionic liquid (IL) 2-hydroxy ethylammonium formate as with methanol, ethylene glycol and glycerol. The physicochemical properties of the solvent mixtures at 25 °C, over the whole range of mole fractions, were determined using solvatochromic probes. High normal polarity ( ENT ) in the alcohol-rich region confirms solute-solvent interactions in this medium. Dipolarity/polarizability (π ∗) show a different trend to ENT with a positive deviation from ideal behavior in IL-glycerol mixtures. However, these deviations for other solvent mixtures are insignificant. Contrary to what is observed for ENT and π ∗,...
Investigations on the Effect of Biosurfactants on the Wettability of Carbonate Rocks via Interactions with Rock and Fluid in Ex-Sito MEOR
, Ph.D. Dissertation Sharif University of Technology ; Roosta Azad, Reza (Supervisor) ; Kamali, Mohammad Reza (Supervisor) ; Shadizadeh, Reza (Co-Advisor)
Abstract
The effects of biosurfactants on sandstone rocks are known in the literature. However, there are few examples of experimental works in Iranian carbonate reservoirs dealing with the effects of biosurfactants under reservoir conditions. This thesis discusses the effect of an efficient biosurfactant produced from Pseudomonas aeroginosa MRo1, a bacterial strain isolated from oil excavation areas in southern Iran, on the recovery of residual oil trapped within carbonate rocks was investigated. The MRO1 could reduce surface tension from 72 to 28 dyne/cm. It also could reduce Interfacial tension from 18.382 to 5.646 dyne/cm.
In a core holder set-up bearing four limestone- and...
In a core holder set-up bearing four limestone- and...
Study of Electronic Structure of 3d Transition Matals-Doped TiO2 Based on Band Calculations:a DFT Study
, M.Sc. Thesis Sharif University of Technology ; Gholami, Mohammad Reza (Supervisor) ; Elahifard, Mohammad Reza (Co-Advisor)
Abstract
We present a systematic study of the composition, electronic structure, and the band gap energy in pure, Cu-doped and O-vacancy@Cu-doped TiO2 using periodic density functional theory (DFT) calculations by several techniques implemented by Abinit code. Herein, the effect of Cu impurity and O-vacancy in three famous crystalline structures of TiO2 i.e. rutile, anatase and brookite, with 6.25% and 12.5% of Cu impurity were investigated. Bulk titania was modeled using 2×2×1, 2×1×1 and 1×1×1 super cells (24 atoms with formula of Ti8O16) and 2×2×2, 2 2×1 and 1×2×1 super cells (48 atoms with formula of Ti16O32) for rutile, anatase and brookite phases, respectively. One Ti atom replaces with Cu atom...