Sharif Digital Repository

Our previously reported mathematical model for a mixed oxide nanoparticulate-based supercapacitor containing RuO2·xH2O and MO2·yH2O (M being another suitable transition metal) was analyzed. Both double-layer and faradaic processes responsible for charge/discharge were considered. The effects of the intrinsic factors, unit cell length, state of charge, and the exchange current densities of the electrochemical processes of the constituents on the performance of the model supercapacitor were clarified. Compensation effects where each constituent compensates the shortcomings of the other at specific conditions of discharge are analyzed in the light of the model  

A mathematical model was developed to describe the performance of nanoparticulate mixed oxide pseudocapacitors based on RuO 2-MO 2 (M being another suitable transition metal) under galvanostatic charge/discharge regime. Both double layer and faradaic processes were taken into account. The effects of the active material's particle size and composition were examined. Furthermore, the influence of discharge current on the extents of double layer and faradaic contributions was analyzed. The model analysis showed that the energy density declined upon increasing the volume fraction of larger particles. © 2008 Springer-Verlag  

The factors influencing the electrochemical behaviour of a supercapacitor have been partly examined in this work. The effects of so-called intrinsic parameters, i.e. exchange current density, unit cell length and double layer (DL) capacitance; as well as the so-called application parameters, i.e. cell current, on the cell potential discharge time have been considered. The contributions of each type of capacitors, DL capacitor and faradaic supercapacitor under various states of operation and material have been analyzed, and the competing (compensating) effects of the two types of capacitors as regards to the discharge and power characteristics manifested by current-potential and energy-power... 

Artificial neural network was used to calculate the performance of a model supercapacitor as signified by the power density, energy density and utilization to the synthetic, intrinsic and operating characteristics. A four-layer neural net having two hidden layers having 6 and 15 nodes was found to be well capable of simulating the capacitor performance with the convergence achieved often a relatively small number of epochs. As for the input parameters, crystal size, surface lattice length, exchange current density of the capacitor active material and the cell current employed while utilization, energy density and power density were the outputs. © 2006 Elsevier B.V. All rights reserved  

Agglomerates of tungsten trioxide in the range of 90 nm to 1 μm are prepared by the acid precipitation method and characterized by XRD as well as scanning electron microscopy. The product when coated with platinum showed pseudocapacitance when in contact with acidic electrolyte in the potential range of 0. 1 to -0. 25 V/SCE. Capacitance in the range of 0. 014 to 0. 039 F cm-2 exhibiting moderate potential dependencies measured through both chronopotentiometry and impedance spectroscopy is presumed to be due to the insertion/de-insertion of protons into the lattice of tungsten trioxide. Equivalent circuit consisting of parallel simulators of mass transfer and capacitor charging... 

In this paper, the Nonlinear Normal Modes (NNMs) analysis for the case of three-to-one (3:1) internal resonance of a slender simply supported beam in presence of compressive axial load resting on a nonlinear elastic foundation is studied. Using the Euler- Bernoulli beam model, the governing nonlinear PDE of the beam's transverse vibration and also its associated boundary conditions are extracted. These nonlinear motion equation and boundary condition relations are solved simultaneously using four different approximate-analytical solution techniques, namely the method of Multiple Time Scales, the method of Normal Forms, the method of Shaw and Pierre, and the method of King and Vakakis. The... 

In this paper, the nonlinear dynamic response of an inclined Timoshenko beam with different boundary conditions subjected to a traveling mass with variable velocity is investigated. The nonlinear coupled partial differential equations of motion for the bending rotation of cross-section, longitudinal and transverse displacements are derived using Hamilton's principle. These nonlinear coupled PDEs are solved by applying Galerkin's method to obtain dynamic response of the beam under the act of a moving mass. The appropriate parametric studies by taking into account the effects of the magnitude of the traveling mass, the velocity of the traveling mass with a constant acceleration/ deceleration... 

In this article, smoothed particle hydrodynamics method is applied in order to study the free surface flow generated by two-dimensional planing flat plate. For this purpose, a two-dimensional smoothed particle hydrodynamics code is developed and validated by the well-known dam breaking problem. Four trim angles and three different velocities are considered to perform a parametric study to examine their physical effects. The obtained results from smoothed particle hydrodynamics are compared against the corresponding Reynolds-averaged Navier Stokes solutions. It is observed that at lower velocities, there exists a good agreement between the smoothed particle hydrodynamics and Reynolds-averaged... 

Nanostructured molybdenum oxide was potentiodynamically deposited onto a stainless steel surface from an aqueous bath by cycling the potential between 0 and -0.75 V vs. Ag/AgCl. The deposit consisted of particulates in the range of 30 to 80 nm. Electrochemical studies under galvanostatic charge/discharge and also impedance spectroscopy revealed capacitive behavior in the potential range of -0.3 to -0.55 V vs. Ag/AgCl with the value of 477 F g-1 at 0.1 mA/cm2. An equivalent circuit comprising of three parallel branches consisting of double-layer capacitance, Warburg impedance, and a constant phase element signifying pseudo-capacitance each coupled with their corresponding resistances was... 

Nanostructured molybdenum oxide having a particle size in the range of 30-80 nm was prepared by potentiodynamic electrodeposition method, and the effects of H2SO4 concentration on its capacitive behavior were studied by cyclic voltammetry, galvanostatic discharge, and electrochemical impedance spectroscopy. Poor to fair capacitive behaviors were witnessed depending on the electrolyte concentration and conditions of charge/discharge. Increasing acid concentration to 0.02 M had favorable effect, while beyond that, the effect was detrimental. Capacitance around 600 F g-1 was recorded in the potential range of 0 to -0.55 V vs. Ag/AgCl  

In order to enhance the post-damage repair capability of the hybrid coupled shear wall systems, a different type of replaceable steel coupling beam with end-plate connection was investigated. Different from conventional configurations, the coupling beams were not embedded into the walls to minimize the post-event repair/replacement difficulties and expenses. To assess the seismic behavior and post-damage replaceability of the coupling beam, a two-stage experimental program was performed to test the full-scale specimens, each utilizing coupling beams with different strength and stiffness. The results of the first specimen indicated a ductile failure with a concentration of inelastic... 

The purpose of this study is to define a piecewise fatigue damage model (PFDM) for the prediction of damage in composite laminates under cyclic loading based on the continuum damage mechanics (CDM) model. Assuming that damage in fiber-reinforced plastic structures accumulates nonlinearly, a piecewise degradation growth function is defined and coupled with CDM and micromechanics approaches. The model divides the damage behavior of fiber, matrix, and fiber/matrix debonding at the ply scale, into three different stages. For generality, a fully multi-stage damage formulation on a single-ply level is employed. The unknown parameters of the PFDM are estimated according to obtained experimental... 

High-temperature insulators protect structures against extreme thermal loads in various industries such as energy and space-related areas. For such insulations, radiation is the dominant mode of heat transfer. The intended multilayer high-temperature insulator utilizes reflection as the controlling mechanism for the radiative heat transfer. In the current study, the axiomatic design methodology is used to map the design process of a reflective multilayer high-temperature insulator. In addition, an analytical model is developed to simulate the combined radiation and conduction heat transfer in the reflective multilayer high-temperature insulator. The model was solved numerically and validated... 

Male infertility is mostly related to semen and spermatozoa, and any diagnosis or treatment requires the investigation of the motility patterns of spermatozoa. The movements of spermatozoa are fast and involve collision and occlusion with each other. In order to extract the motility patterns of spermatozoa, multi-target tracking (MTT) of spermatozoa is necessary. One of the most important steps of MTT is data association, in which the newly arrived observations are used to update the previous tracks. Dynamic Bayesian network (DBN) is a powerful tool for modeling and solving various types of problems such as tracking and classification. There can also be a hybrid-DBN (HDBN), in which both... 

A series of polyurethane elastomers (PUEs) based on 4,4′-cyclohexamethylene diisocyanate (H12MDI)/1,2-ethanediol as hard segment with the soft segments having different molecular weights of polycaprolactone diols, were effectively polymerized by two step technique. The structural characterization was performed by FT-IR spectroscopy. The X-ray diffraction (XRD) technique was used to study the crystallinity and hydrophilicity of the prepared polymer films. It was found that crystallinity and hydrophilicity increased with increasing the chain length of soft segments. The effect of molecular weight of polyols on the contact angle, water absorption (%) and swelling behavior of the synthesized... 

We consider the problem of interference management in wireless cellular networks with caches at both base stations and receivers, and we characterize the degrees of freedom (DoFs) per cell to within an additive gap of (1/3) and a multiplicative gap of 2 for all system parameters, under one-shot linear schemes. Our result indicates that the one-shot linear DoF per cell scales linearly with the total amount of cache available in the cell, i.e., the sum of the caches at the central base station and all the receivers within the cell, resembling a similar phenomenon previously observed for the case of fully connected wireless networks. To establish the result, we propose a decentralized and... 

How can we optimally trade extra computing power to reduce the communication load in distributed computing? We answer this question by characterizing a fundamental tradeoff between computation and communication in distributed computing, i.e., the two are inversely proportional to each other. More specifically, a general distributed computing framework, motivated by commonly used structures like MapReduce, is considered, where the overall computation is decomposed into computing a set of “Map” and “Reduce” functions distributedly across multiple computing nodes. A coded scheme, named “coded distributed computing” (CDC), is proposed to demonstrate that increasing the computation load of the...