Sharif Digital Repository

A one-pot Cu-catalyzed synthesis of functionalized alkynyl imidamide by terminal alkynes, trichloroacetonitrile and aniline or benzyl amine is reported. The compounds were produced via coupling reaction of terminal alkynes with trichloroacetamidine. This method was performed under mild, ligand-free conditions and easy work-up method. © 2020, Bentham Science Publishers. All rights reserved  

GAC has been modified by loading of potassium nickel hexacyanoferrate (KNiCF) as a new adsorbent for cesium adsorption. The potassium nickel hexacyanoferrate-loaded granular activated carbon (KNiCF-GAC) was characterized using powder x-ray diffraction (XRD) and nitrogen adsorption-desorption isotherm data, infrared spectroscopy, and its cesium adsorption performance in aqueous solution was investigated. The effect of the various parameters such as initial pH value of the solution, contact time, temperature, and initial concentration of the cesium ion on the adsorption efficiencies of KNiCF-GAC have been studied systematically by batch experiments. The adsorption isotherm of KNiCF-GAC was... 

Uranium (VI) sorption using an anionic exchanger resin, namely Amberlite IRA910, in the presence of sulfate anions was the subject of current study. Batch sorption experiments were carried out to evaluate the influence of operational parameters such as pH, contact time, initial concentration and existence of various anions (including phosphate, sulfate, chloride, fluoride, and nitrate) in the solution on Amberlite IRA910 sorption behavior. Experiments revealed that uranium adsorption was fulfiled at pH>3 and 50 min to amount of 80%. Kinetics study revealed that the pseudo-second-order model showed better curve-fitting regression of the experimental data than the pseudo-first-order one.... 

In this paper, fundamental concepts of ultrasonics and characteristics of distinctive microstructures have been used to simply explain the effect of microstructure on the attenuation mechanism of ultrasonic waves in carbon steels. In addition, it has been shown that application of the second medium hardness instead of the bulk hardness is more appropriate to correlate the sound velocity and the microstructure  

The importance of the model to predict the aggregation behavior of asphaltene molecules at the molecular level was well established in different studies. Elucidation of the relationship between the interaction energy and the structural characteristics of asphaltene molecules to their aggregation behavior still needs further investigation. For this purpose, we combined the quantum mechanics and molecular dynamics approaches and analyzed the interaction energy of asphaltene to find out the effect of structural features on the aggregation behavior. The interaction energy of asphaltene is used in this study to evaluate the potential of aggregation. We found that asphaltene molecules with smaller... 

A simple and appropriate procedure for the synthesis of quinazoline-2,4(1H,3H)-dione derivatives from isocyanides, aniline and isocyanate via the Cu-catalyzed intramolecular C-H activation reaction is reported. The advantages of this method are one-pot conditions, accessible starting materials-catalyst, high yield of products, and short reaction times. The structures are confirmed spectroscopically (1H-and13C-NMR, IR and EI-MS) and by elemental analyses. © 2020 Bentham Science Publishers  

The linear behavior of fission chamber (FC) neutron detectors in Isfahan miniature neutron source reactor (MNSR) was investigated experimentally. FC neutron detectors are installed near the reactor core to measure the produced neutron flux in the core. The linearity of the response of these detectors is important because the measured neutron flux by them is one of the important methods in determining and controlling the reactor power and therefore affects the safety of the reactor. For this purpose, the measured neutron fluxes by these detectors at different reactor powers were compared with the measured neutron flux at the output of the external beam tubes by different methods. In this... 

This paper resolve the salinity-dependent interactions of polar components of crude oil at calcite-brine interface in atomic resolution. Molecular dynamics simulations carried out on the present study showed that ordered water monolayers develop immediate to a calcite substrate in contact with a saline solution. Carboxylic compounds, herein represented by benzoic acid (BA), penetrate into those hydration layers and directly linking to the calcite surface. Through a mechanism termed screening effect, development of hydrogen bonding between –COOH functional groups of BA and carbonate groups is inhibited by formation of a positively-charged Na+ layer over CaCO3 surface. Contrary to the common... 

A one-pot synthesis of functionalized benzo thiazine derivatives via a Cu-catalyzed, multicomponent reaction of isocyanides, aniline, and heterocumulenes in acetonitrile at room temperature was developed. Transition metal-catalyzed activation of C-H bonds under mild copper-catalytic reaction conditions, using simple and available starting materials, also obtaining a pure product with high yield without applying column chromatography are the major advantages of the applied method among the other ones used for this purpose. The structures are confirmed spectroscopically (1H- and 13C-NMR, IR, and EI-MS) and through elemental analyses. © 2019 The Chemical Society Located in Taipei & Wiley-VCH... 

An energy-based ordinary differential equation is derived for a plastic wave propagating through a Taylor impact test specimen. Using the definition of true strain, an analytical equation is presented to calculate the strain rate across the plastic wave front. Having considered a Johnson-Cook plasticity model for the projectile material, the derived energy equation accompanied by a governing kinematics relation and the strain rate equation is numerically integrated to obtain the final deformed profile of the specimen. The results of the energy based model are then compared with those of the commonly used momentum-based approach as well as the existing experimental data in literature for... 

This paper presents a novel approach based on pulse transit time (PTT) for the estimation of blood pressure (BP). In order to achieve this goal, a data acquisition hardware is designed for high-resolution sampling of phonocardiogram (PCG) and photoplethysmogram (PPG). These two signals can derive PTT values. Meanwhile, a force-sensing resistor (FSR) is placed under the cuff of the BP reference device to mark the moments of measurements accurately via recording instantaneous cuff pressure. For deriving the PTT-BP models, a calibration procedure including a supervised physical exercise is conducted for each individual. The proposed method is evaluated on 24 subjects. The final results prove... 

A low-power high-speed two-stage dynamic comparator is presented. In this circuit, PMOS transistors are used at the input of the first and second stages of the comparator. At the evaluation phase, the second stage is activated after the first stage with a predetermined delay to achieve a controllable pre-amplifier gain. Also, the first stage is turned off after the delay to reduce overall power consumption. Simulation results in 0.18 μτη CMOS technology, prove that the proposed circuit reduces the power consumption by a factor of two and reduces comparison time as large as 210ps in the same budget of offset voltage compared to the conventional circuit. Moreover, the offset voltage and power... 

Selective Laser Sintering (SLS) is a rapidly growing additive manufacturing process, because it has the capacity to build parts from a variety of materials. However, the dimensional accuracy of the fabricated parts in this process is dependent on the ability to control phenomena such as warpage and shrinkage. This research presents an optimization algorithm to find the best processing parameters for minimizing warpage. The finite element method was used to simulate the sintering of a layer of polymer powder, and the warpage of the layer was calculated. The numerical model was verified through comparison with experimental results. A back-propagation neural network was used to formulate the... 

Abstract: Well testing is one of the important methods to provide information about the reservoir heterogeneity and boundary limits by analyzing reservoir dynamic responses. Despite the significance of well testing data, misinterpreted data can lead us to a wrong reservoir performance prediction. In this study, we focus on cases ignoring the adjacent well’s production history, which may lead to misinterpretation. The analysis was conducted on both homogeneous and naturally fractured reservoirs in infinite-acting and finite-acting conditions. The model includes two wells: one is “tested well” and the other is “adjacent one.” By studying different scenarios and focusing on derivative plots, it...