Sharif Digital Repository

The present work describes sensing application of modified TiO 2 nanotubes having carbon-Pt nanoparticles for simultaneous detection of dopamine and uric acid. The TiO 2 nanotubes electrode was prepared using anodizing method, followed by electrodeposition of Pt nanoparticles onto the tubes. Carbon was deposited by decomposition of polyethylene glycol in a tube furnace to improve the conductivity. The C-Pt-TiO 2 nanotubes modified electrode was characterized by cyclic voltam-metry and differential pulse voltammetry methods. The modified electrode displayed high sensitivity towards the oxidation of dopamine and uric acid in a phosphate buffer solution (pH 7.00). The electro-oxidation currents... 

In this study a novel Pt/Ni nanostructure consisting of nano-bushes and nanocubes was fabricated onto TiO 2 nanotubes. The scanning electron microscopy images showed that a large amount of well-dispersed nano-architectures had uniformly covered all over the surface which made an electrode with high surface area. It was obviously seen that the nanocube structures mainly consists of Ni had been grown on top of each other while the Pt colonies represented bush-like structures. As a non-enzymatic glucose biosensor, the Pt/Ni TiO 2 nanotubes modified electrode exhibited an excellent performance. The proposed biosensor had two linear ranges for detection of glucose from 0 to 0.12 mM (correlation... 

Co/Cu multilayers were deposited in a sulfate solution by controlling the current and potential for the deposition of cobalt and copper layer respectively. The electrochemical behavior of these multilayers was studied by cyclic voltammetry and current transients. In addition, a mathematical analysis was used to characterize the electrodeposition system. Simultaneously, the nucleation and growth mechanisms were monitored by these techniques. In this case, the results clearly showed that electrodeposition of cobalt layers was a kinetically controlled process while the reduction of copper ions was a diffusion-control process. Although nucleation mechanism of the single Co deposit was found as a... 

The cobalt-nickel/copper multilayer films were prepared by electrodeposition process in sulfate solution using a three electrode cell. Cyclic voltammetry and double chronoampermetry techniques were utilized to characterize the multilayer system and to obtain the nucleation and growth mechanism. The cyclic voltammograms determined the reduction potential range of the three components and also clearly emphasized that electrodeposition of cobalt-nickel alloy was controlled by a kinetic process, while copper ions were reduced with diffusion-controlled mechanism. These results were confirmed with those which were extracted from the chronoampermetry curves. In addition, the current transients... 

A simple modified TiO2 nanotubes electrode was fabricated by electrodeposition of Pd, Pt and Au nanoparticles. The TiO2 nanotubes electrode was prepared using the anodizing method, followed by modifying Pd nanoparticles onto the tubes surface, offering a uniform conductive surface for electrodeposition of Pt and Au. The performance of the modified electrode was characterized by cyclic voltammetry and differential pulse voltammetry methods. The Au/Pt/Pd/TiO2 NTs modified electrode represented a high sensitivity towards individual detection of dopamine as well as simultaneous detection of dopamine and uric acid using 0.1 M phosphate buffer solution (pH 7.00) as the base solution. In both case,... 

A modified weakly compressible smoothed particle hydrodynamics (WCSPH) is presented, which utilizes consistent discretization schemes for spatial derivatives in the flow equations. Here, each SPH particle is considered as a computational point that represents a specific part of the fluid. To overcome non-physical oscillations that usually arise in standard WCSPH, we modified the mass conservation equation by using a numerical filter. This modification is based on the difference between two discretization schemes used for the term ∇{dot operator}∇Pρ. Furthermore, a new implementation of wall boundary condition in SPH is introduced. This condition is imposed on the pressure of wall boundary... 

Several schemes for discretization of first and second derivatives are available in Smoothed Particle Hydrodynamics (SPH). Here, four schemes for approximation of the first derivative and three schemes for the second derivative are examined using a theoretical analysis based on Taylor series expansion both for regular and irregular particle distributions. Estimation of terms in the truncation errors shows that only the renormalized (the first-order consistent) scheme has acceptable convergence properties to approximate the first derivative. None of the second derivative schemes has the first-order consistency. Therefore, they converge only when the particle spacing decreases much faster than... 

Weakly Compressible Smoothed Particle Hydrodynamics (WCSPH) can lead to non-physical oscillations in the pressure and density fields when simulating incompressible flow problems. This in turn may result in tensile instability and sometimes divergence. In this paper, it is shown that this difficulty originates from the specific form of spatial discretization used for the pressure term when solving the mass conservation equation. After describing the pressure-velocity decoupling problem associated with the so-called colocated grid methods, a modified approach is presented that overcomes this problem using a different discretization scheme for the second derivative of pressure. The modified... 

Purpose - The purpose of this paper is to present a novel approach in aeroservoelastic analysis and robust control of a wing section with two control surfaces in leading-edge and trailing-edge. The method demonstrates how the number of model uncertainties can affect the flutter margin. Design/methodology/approach - The proposed method effectively incorporates the structural model of a wing section with two degrees of freedom of pitch and plunge with two control surfaces on trailing and leading edges. A quasi-steady aerodynamics assumption is made for the aerodynamic modeling. Basically, perturbations are considered for the dynamic pressure models and uncertainty parameters are associated... 

Various methods are devised to capture renewable energy or waste heat from different sectors, where among all, waste heat capturing from the generator of a wind turbine through the cooling process for freshwater and cooling production is paid less attention in Iran, in spite of the fact that many wind farms in Iran are in hot and humid regions and the residents nearby the farms desperately need freshwater and cooling load. To surmount this problem, waste heat extraction from a wind turbine (Enercon 70 Model) for freshwater and cooling production is proposed in this study. Instead of dissipating this thermal energy of the wind turbine into the environment, it can be used for freshwater and... 

Progressive conversion/shrinking core (PC-SC) models of constant-size cylinders were exploited to interpret the decarburization reactions of MgO-C-Si bricks heated up under blown air. Chemical adsorption/solid (or pore) diffusion mechanisms governed the reaction rate. With 5% silicon, chemical adsorption vanished at 1000 and 1100°C. The oxidation rate lowered then with temperature. This was due apparently to the blocking of the pore-end gorges by the voluminous compounds (like Forstrite). Arrhenius plots of the specific rates yielded the activation energies of the prevailing steps. Without Si antioxidant, three steps were appreciated having activation energies of 51.65 (for chemical... 

TiO2nanocrystals were prepared by hydrolysis and peptisation of titanium isopropoxide under different pH values. The as-prepared powder of very fine anatase crystallites ranges from 8 nm in acidic solution of pH 3 to 10 nm in basic solution of pH 8. Heat treatment of the powders leads to grain growth and anatase - rutile transformation. Experimental results have shown that the anatase to rutile phase transformation in the heat-treated powders depend not only on primary crystallite size but also the presence of brookite phase. It is observed that in the powders with the same size the presence brookite phase would accelerate the anatase to rutile transformation. Furthermore it has been found... 

Occurrence of drought, as an inevitable natural climate feature, cannot be ceased while happening. However, costs of the consequences could be alleviated using mature scientific integrated approaches. To reduce the amount of damage, it is required to provide “Contingency” and “Mitigation” action plans. For this reason, development of efficient operating instructions for various regions based on weather conditions and field studies is needed as well as having a sophisticated understanding of socioeconomic situations. This paper describes an approach to provide the first national agricultural drought risk management plan for a river basin in Iran country as a pilot. The study lasted for... 

In this paper we use tunability of FBG to introduce a novel device for optically reading, writing or modifying the low-speed label(s). We utilize tunable FBG arrays as concurrent label modulating (multiplexing) elements. This second-level intensity modulation is used to send signaling messages between nodes of WDM networks. The fiber optic small-signal modulator is formulated, and its behavior is compared with the published reports  

Tunability of fiber Bragg grating (FBG) in transition region is used to implement wavelength-selective optical intensity modulator, which superimposes a secondary low-speed data on the transit high-speed payload optical signal. Theoretical model of the device is developed and verified by measurements in the linear and nonlinear slopes of the FBG. Experiments with strong and relatively weak gratings confirm the wavelength-selectivity and stability of modulation. The fiber-based modulator is employed for optically tagging or labeling individual wavelength channels using baseband and amplitude-shift keying (ASK) modulated signals. The wavelength-selective channel labeling scheme is useful for...