Sharif Digital Repository

Aromatic aldehydes and ketones are readily acetalized or ketalized under microwave irradiation in the presence of water as a solvent  

A four-step synthetic strategy was applied to achieve novel methacrylic monomers. 5-Norbornene-2,2-dimethanol was prepared from a Diels–Alder reaction of cyclopentadiene and acrolein, followed by the treatment of the adduct with an HCHO/KOH/MeOH solution. The resulting 1,3-diol (1) was then acetalized with different aromatic aldehydes having OH groups on the ring to produce four spiroacetal derivatives. The reaction of methacryloyl chloride with the phenolic derivatives led to four new methacrylic monomers that were identified spectrochemically (mass, FTIR, 1H-NMR, and 13C-NMR spectroscopy). Free radical solution polymerization was used to prepare novel spiroacetal–norbornene containing... 

We study the problem of finding a target t from a start point s in street environments with the cooperation of two robots which have a minimal sensing capability; that is, robots do not know any information about the workspace including information on distances, edges, coordinates, angles etc. They just can detect the discontinuities in the visibility region of their location. The robots can detect target point t as soon as it enters their visibility region and have communication peripherals to send messages to each other. Our aim is to minimize the length of the path passed by the robots. We propose an online algorithm for robots such that they move in the workspace and find the target.... 

A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition  

We consider the problem of walking a robot in an unknown polygon called “street”, starting from a point (Formula presented.) to reach a target (Formula presented.). The robot is assumed to have minimal sensing capability in a way that cannot infer any geometric properties of the environment, such as its coordinates, angles or distances; but it is equipped with a sensor that can only detect the discontinuities in the depth information (or gaps). Our robot can also locate the target point (Formula presented.) as soon as it enters in robot’s visibility region. In addition, one pebble is assumed to be available to the robot to be used as an identifiable point and to mark any position of the... 

We consider the problem of walking a simple robot in an unknown street. The robot that cannot infer any geometric properties of the street traverses the environment to reach a target t, starting from a point s. The robot has a minimal sensing capability that can only report the discontinuities in the depth information (gaps), and location of the target point once it enters in its visibility region. Also, the robot can only move towards the gaps while moving along straight lines is cheap, but rotation is expensive for the robot. We maintain the location of some gaps in a tree data structure of constant size. The tree is dynamically updated during the movement. Using the data structure, we... 

We consider the problem of walking in an unknown street, starting from a point s, to reach a target t by a robot which has a minimal sensing capability. The goal is to decrease the traversed path as short as possible. The robot cannot infer any geometric properties of the environment such as coordinates, angles or distances. The robot is equipped with a sensor that can only detect the discontinuities in the depth information (gaps) and can locate the target point as soon as it enters in its visibility region. In addition, a pebble as an identifiable point is available to the robot to mark some position of the street. We offer a data structure similar to Gap Navigation Tree to maintain the... 

In this paper the characteristic ratio assignment (CRA) method is employed to control transient response of a class of non-minimum phase fractional order systems. Since fractional order all-pass filter could not be realized, the fractional unstable zeros are converted to integer unstable zeros by multiplying complementary polynomials to numerator and denominator polynomials of system's transfer function. Doing so, the closed loop system would be an integer order all-pass filter multiple an all-pole fractional transfer function determined from CRA method. Computer simulation results are presented to illustrate the performance of the proposed method. m  

This paper focuses on robust performance analysis of a closed loop fractional order system through a sensitivity approach. The characteristic ratio assignment method is selected to attain a desired closed loop transient response. Then, we compute the sensitivity of such a desired transfer function with respect to its characteristic ratio and we explore its specifications. The relation between the coefficient diagram shape and the relative stability of the closed loop system is discussed. Also, the closed loop poles variations due to the changes in the characteristic ratios are investigated. Finally, we study a pseudo second order process to verify the robust performance of the characteristic... 

An approach is proposed to control transient response of fractional order systems with maximum permissible control signal. This goal is achieved using a newly suggested characteristic ratio assignment method. Based on the proposed method, the generalized time constant τ and the characteristic ratios including their pattern, an adjustable parameter β, and the product of two successive characteristic ratios ρ are determined such that predefined level of overshoot and time specification of closed loop step response are obtained while the control signal is confined to a pre assigned maximum magnitude. The raised issue is solved by defining an optimization problem in which the design parameters... 

This paper presents a new analytical method to design fractional-order proportional- integral-derivative (PID) controllers. The control parameters are calculated so that the closedloop system approximates a desired transfer function with transient response requirements. This function is determined based on the characteristic ratio assignment method. The control parameters are calculated by matching the first three moments of the closed-loop transfer function with the corresponding values of the desired system. Furthermore, to ensure closed-loop stability the proposed method is improved by using the shifted moments around the crossover frequency. Illustrative examples are given to show the... 

Five different approaches are presented to assign characteristic ratios for commensurate fractional order systems having order in (0,0.5]. Through the indirect methods, a closed-loop or plant transfer function is converted to a commensurate order one with an order greater than 0.5 so that the previously designed CRA method by the authors is applicable. The first method among the proposed direct ones is based on increasing the order of the desired closed-loop transfer function that allows the employment of positive characteristic ratios. In the second method the closed-loop response is sped up by augmenting an appropriate zero. The final method uses negative characteristic ratios to reach the... 

In this paper the characteristic ratios and generalized time constant are defined for all-pole commensurate fractional order systems. The sufficient condition for stability of these systems in terms of their characteristic ratios is obtained. Also an analytical approach for characteristic ratio assignment (CRA) to have a non-overshooting fast closed loop step response is introduced. The proposed CRA method is then employed to design a fractional order controller. Computer simulation results are presented to illustrate the performance of the CRA based designed fractional order controllers  

The lab on a chip is utilized as a background and a substrate for creating a proper flow for cellular processes in medicine. In this study, the concepts of cell isolation and cell transfer methods have been discussed. After that, the device of separation and transfer systems has been designed, simulated, and verified by placing the frequency of particle separation and droplet formation, which is tried to introduce a new device that can be used in cellular studies. The optimal operation conditions for the problem have also been investigated. High separation efficiency (99%) could be achieved when the velocity of the sample inlet in the microchannel separator is 180 μm/s. Also, a microfluidic...