Sharif Digital Repository

Photocatalytic degradation is one of the developing modern and effective methods for decontamination of hazardous pollutants of chemical industrial wastewater. In spite of great developments in this field of research and its various advantages, finding a process with high efficiency and optimization of the operating parameters are still required to be investigated. In this study, the photocatalytic degradation of 2-Nitrophenol under natural sunlight irradiation using industrial photocatalysts such as TiO2 (Hombikat), ZnO, WO3 and TiO2 (P25) was investigated. The photocatalysts were characterized by the XRD, BET, SEM and DRS tests and the effects of significant operating parameters (the... 

In this study, we investigate the effect of adding potassium persulfate (PDS) (K2S2O8) and hydrogen peroxide (H2O2) to E.coli (as a model microorganism) photocatalytic removal system in the presence of the TiO2-P25 as photocatalyst and UV irradiation. In this regard, the PDS and H2O2 oxidants were added separately in the different levels of pH and photocatalyst loading under UV irradiation. The experimental points were determined based on the central composite design (CCD) and in order to study the main and the interactive effects of the photocatalyst concentration (mg/L), oxidant concentration (mg/L) and the pH on the final concentration of E.coli (cfu/mL), a response surface model (RSM)... 

Photocatalytic degradation is one of the developing modern and effective methods for decontamination of hazardous pollutants of chemical industrial wastewater. For this purpose, in this research, the efficiency of the photocatalytic process in degradation of Cortisone Acetate is investigated under solar light irradiation, and the effect of two useful oxidants, potassium persulfate (PDS) and potassium proxy mono sulfate (PMS), on the degradation efficiency is examined. At first, the single effect of these two oxidants, and then their interaction effects with the photocatalyst (TiO2-P25) and solution pH by analytical analysis and with the help of Response Surface Methodology (RSM) and... 

Control of many mechanical systems such as satellites lies on the control of space robots. Control of space robots has many theoric complexities because of the presence of non-holonomic constraints due to angular momentum conservation. Unlike fixed-base robots, any movement of space robots manipulator has a reaction on the robot base and moves it. Thus manipulator’s movement toward desired configuration rotates the robot base and as a result appropriate attitude may not be attained. Therefore an appropriate path is required to achieve the desired configuration and the base attitude reaches its desired value. In this thesis, first the dynamic of space robots and the interaction between the... 

A motion tracking control design of an n-DOF rigid robot by taking into account its actuator dynamics is proposed in this paper using backstepping technique. neglecting actuator dynamics in control of rigid robot manipulators can degrade the performance and loss of stability. However,consideration of actuator dynamics entails joint torque or armature currents measurement. In this study, torque measurement has been avoided using an torque estimator.. Finally, Semi-global convergence for motion tracking error are proven. In addition, A simulation example of a two-link robotic manipulator is also given to clarify the effectiveness of proposed design method. Considering actuator dynamics entails... 

Wheeled mobile robots form a subcategory of mobile robots and are usually accompanied with geometric constraints on their velocities. These constraints do not allow the robots to move in any path that only does not collide with obstacles, in order to move from one point to another. On the other hand, the nonlinear nature of these systems make their control difficult. A general approach in motion planning and control for mobile robots is using standard forms equivalent to their state equations; Usually, solving motion planning and control problems for these forms is easier than that of the original system. Also,the mentioned problems are more prospective to have a systematic solution for... 

Satellite attitude determination means specifying its rotation relative to a known reference. To determine satellite attitude, gyroscope is used to measure angular velocity and attitude sensors such as sun sensor, magnetometer, star tracker and earth horizon scanner are used in order to obtain vector measurements. In kinematic control, satellite angular velocity is determined in a way that its attitude converges to desired attitude. Usually, gyroscope and attitude sensors measurements are contaminated by noise which leads to errors in satellite attitude estimation and control. In the literature, gyroscope and at least two vector meaurements are used to estimate and control the... 

The demand for safety operating systems is growing with the new developments in technology. One of the important and critical issues in system monitoring is the capability of the system to detect probable faults and hazards. In model-based fault detection one specific diagnostic signal called residual should be generated for each fault that is only sensitive to a particular fault and independent of other faults and disturbances. In this thesis we try to investigate the nonlinear geometric approach in fault detection of a class of mechanical systems. After a brief introduction to geometric tool for nonlinear inputaffine systems and conditions in which output is decoupled from input, we... 

Attitude determination and control system (ADCS) design is usually based on using measurements provided by rate gyros or attitude sensors such as Sun, Earth-magnetic, Earthhorizon and star trackers. In many practical scenarios, vector measurements provided by attitude sensors and the corresponding reference vectors are available with time delay while the angular velocity is measured by Gyro without significant delay. Time delay can cause ADCS performance degradation and even instability of the closed-loop system. Due to the nonlinearity of satellite dynamics and kinematics, controller and observer design in presence of measurement delays has its own complexity. Hence, despite its... 

In recent years, autonomous unmanned aerial vehicles (UAVs) have attracted considerable amount of interest because of a wide area of applications and a lot of advantages. UAVs have been extensively used for military operations that include tracking, surveillance, active engagement with weapons and airborne data acquisition. UAVs are also in demand commercially due to their advantages in comparison to manned vehicles. These advantages include lower manufacturing and operating costs, flexibility in configuration depending on customer request and not risking the pilot on demanding missions. Quadrotor, which is a kind of rotary wing UAVs, has many advantages such as the vertical take-off and... 

This thesis is devoted to deriving a port Hamiltonian control approach for different scenarios of brachiation movement by a two-link underactuated planar robot called brachiation robot. The port Hamiltonian modeling and control of this type of robot is introduced for the first time and shows promising results in the analysis and simulation as will be showed here. Animals have long inspired roboticists. Their dexterity, versatility, flexibility of motion and great variety of behaviors has made them benchmarks for robot performance. Recently things have begun to change and robots are now capable, to a limited degree, of mimicking the behavior of animals. This paper studies a type of... 

In robotic, Underactuated systems are interesting subject to study. Underactuated system, is a system that have fewer actuator than degrees of freedom. Underactuated systems are composed of active and passive joints. passive joints are existed, in order to decrease the weight, cost, and energy consumption. Usually, control of these systems are difficult. Underactuated systems have acceleration constraint. This property make the control method have fundamental constraint. So that controller dynamic could not be a smooth function of states of system. So most of standard method in control, such as feedback linearization, are not applicable. Local linearizing methods, because of... 

The purpose of determining orientation and position of a rigid-body is specifying its attitude and position with respect to a specified reference frame in order to using in controller. Since there is no sensor that can directly measures the attitude and position, we have to estimate those variables by observers. In this thesis we derive a new and explicit neccesary and sufficient condition for observability of the rigid-body kinematic equation. Also we propose a new observer for estimating the attitude and position of the rigid-body. The special feature of the proposed estimator is that it use only a single landmark and is globally and exponentially stable. In the next step we study the... 

Time-delay in measurement of the outputs is usually one of the important factors creating complexity in design of a robot controller such that ignoring the delay in controller design can cause instability or significant performance degradation in a robotic system. In this thesis, set-point regulation problem as well as the trajectory tracking problem for a rigid robotic manipulator in presence of constant and known delay in measurements have been investigated and in particular, three dynamically smooth controllers have been proposed:
1-A controller based on the “minimal” dynamic model of a robot manipulator that satisfies sufficient conditions in the form of Linear Matrix inequalities... 

Inverters are the main utility in transmitting power from distributed generation (DG) systems toward grid and their safe and immune performance has become a major concern among the system designers. In addition to poor power transmittance, faults in inverter can harm other equipment such as DG and local load. Consequently different protections has been considered to increase the reliability of these systems. Some of these protections like fuses and varistors are implemented in the hardware while others are considered in the processor. In the later class of protections, fault detection and isolation (FDI) system has been the subject of intense investigation in inverters over the past two... 

The goal of the attitude determination is to determine the orientation of a satellite with respect to a reference frame. For this purpose, gyroscopes are used to measure the satellite’s angular velocity. Also, the attitude sensors such as magnetometers, Sun sensors, Earth sensors or star trackers are employed to collect vector measurements. The aim of the attitude control is to calculate the torque which is needed to be applied to the satellite such that its orientation and angular velocity converge to their desired values. It is usual to determine the attitude of satellite first and then use it in the attitude control algorithms. When multiple independent vector measurements are available,...