Sharif Digital Repository

Nuclear energy is one of the most important sources of energy from the economical point of view and also in terms of cleanliness and safety. Hence, strategically, uranium is one of the most basic elements of the earth and nowadays, the importance of this element is more marked due to the nuclear industry developement. Therefore, uranium recovery from the wastes generated during nuclear fuel production in Isfahan’s uranium conversion plant- in which yellow cake is converted to uranium hexafluoride- is quite pivotal. In this experimental research, we have to remove Fluoride from waste after dissolution by several methods like precipitation. After that uranium is extracted from the sludge of... 

Process Planning is the link between CAD and CAM and is one of the most complex issues in product development chain. In addition, this process is time-consuming, costly and requires expert man power. In recent decades, many Computer Aided Process Planning (CAPP) systems are developed to reduce the duration of Process Planning and many feature based process planning systems have been reported. Feature recognition and determining the precedence of machining features are the most critical issues in feature-based process planning. It gets more complicated where geometric interaction occurs between machining features. This work, focuses on feature recognition and their geometric interactions and... 

Fused pyrimidines have attracted considerable attention recently in synthetic organic chemistry because of their wide range of biological activities pharmaceutical, therapeutic properties, antibacterial, antiviral, antitumor, and anti-inflammatory activities. We have reported a new and efficient synthesis of dihydro and tetrahydro pyrimidines fused to 2H-chromen-2-oneand cyclohex-2-enone and pyrimidine fused to uracil via two component reaction of 4-amino-2H-chromen-2-one, 3-aminocyclohex-2-enone and6-aminouracilto 1-aryl-N,N'-bis(arylmethylene)methanediaminein the present of iodine as catalyst.Molecular iodine has received considerable attention in the last few years due to inexpensive,... 

The problem of Origination of The Universe is one of the most important issues in the history of philosophy whether in western edition or in Islamic thought. The most problematic aspect of the Origination is Temporal Origination. From about 30 years ago as a result of the works of a famous American philosopher William Lane Craig, the debate between temporality and Eternity of the Universe became a fresh topic in western philosophy. In this research we want to survey the philosophical arguments for and against the temporality of the Universe based on the views of: W.L.Craig, Q.Smith and Allamah S.M.H Al-Tabatabaie.
 

This thesisconsiders new fundamental approaches to yield heterogeneous catalysts in to three sections. The first section described the immobilization of the molybdenum-Schiff base complexes in pores of SBA-15 in two different methodologies depending on the actual structure of the complexes., (i) stepwise formation of the complex by initial covalent anchoring of one of the components and consecutive solid phase synthesis consisting of the condensation of the other components of the salen complex (iii) one-step complex immobilization by covalent binding through the ligand.Based on the first methodology, we report the preparation of ordered mesoporous silica SBA-15 containing a molybdenum... 

The subgradient method is one of the most favoriate methods to solve discrete optimization problems. The Easy Implementation and flexibility enbles us to solve a vast types of complicated combinatorial optimization problems. However, the algorithm can be improved by adjusting its parameters and steps.In present research, we present a heuristic structure to modify and improve the algorithm. Then, the proposed algorithm has tested on special classes of discrete optimization problems such as Generealized Assignment and Uncapacitated Warehouse location problems. The results show that the proposed algorithm can improve the efficiency of the classic form of subgradient method.The three main... 

A complete 6DOF flight dynamic model of an elastic flapping wing (EFW), integrated with unsteady aerodynamic theory is developed. In this respect, initially efficient high fidelity modules for EFW structural dynamics (SD) as well as unsteady aerodynamics loadings (UAL) to be coupled with its flight dynamics are prepared. A modal approach is followed to model structural dynamics of plain and 3D EFWs. This is in contrast with the Euler-Bernoulli beam theory that is mostly utilized for SD in the existing literature. In addition, due to the possibility of large wing deformations as well as the existence of non-linear displacement regime for realistic EFW flights, non-linear modal approaches such... 

With the development of electrical engineering and the electrical industry, the use of copper and its alloys has grown tremendously. On the other hand, with development and modern industry, it will be difficult to meet the requirements such as high performance, cost reduction and weight reduction of the structure if only one metal material is used in the production of the desired component or structure. Aluminum can be used in combination with copper because of its properties such as high thermal and electrical conductivity. Al/Cu bonding is used in industries such as microelectronics, automobiles and batteries. This study has investigated parametrically the feasibility of uneven bonding of... 

We have reported a new and efficient synthesis of a broad spectrum of heterotetracyclic benzoxazocines via unique tandem 1,3-dinucleophilic addition of different bifunctional nucleophiles to quinolinium and isoquinolinium salts. The reaction generally involves the initial addition of nucleophiles to quinolinium salts to form enamine intermediate which can be trapped by intramolecular O/S-alkylation of nucleophiles. This protocol is a very mild and simple method for construction of eight-membered ring in fused heterocycles in a one-step process. We have also developed an efficient asymmetric synthesis of α,β-disubstituted γ-bisalkoxycarbonyl and α, β- disubstituted γ- phosphono sulfonates via... 

The one pot, three component 1,3-dipolar cycloaddition reaction of azomethine ylides with a series of new dipolarophiles (E)-3 -benzylidene- indolin-2 -ones in methanol under the reflux condition yields ,3′-dispiropyrrolidine oxindole library. The product is produced with high regioselectivity. Catalyst free, excellent yield , easy workup process, short reaction time, and convenient operation are the characteristics of this procedure. NMR and X-ray are used to determine the structure and stereochemistry of cycloadduct products.