Sharif Digital Repository

The purpose of this study is to investigate the effect of halids on electrooxidation of silver in alkalie medium. For this case, electrochemical teqniques such as Chronoamperometery (CA) and Cyclic Voltammetry (CV) were applied. Characterization of the electrodeposition process is based on quantitative analysis of the potentiostatic current versus time curves. Rate constants of nucleation and growth obtained from the fit of the recorded transients to the generalized equations derived based on Abyaneh and Flischmann model. The conditions that justify the use of the limiting forms of the transient equations for the so-called “ instantaneous” and “ progressive” nucleation processes were... 

In this study a systematic effort was made to study and compare electrochemical oxidation behavior of iodide on Pt, carbon and carbon supported polyorthoaminophenol film electrodes. All of the electrochemical experiments were performed in acidic, basic and nuteral aqueous solutions and the applied electrochemical techniques included Chronoamperometry (CA) and Cyclic voltammetry (CV). Effects of concentration and scan rate of potential on the cyclic voltammetry of KI was studied at the previously mentioned electrodes. Current-time and log current-potential curves were analyezed quantitavely in order to determine kinetic parameters. Carbon supported polyorthoaminophenol electrode was prepared...