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Production of biodiesel from waste frying oil using whole cell biocatalysts: Optimization of effective factors
, Article Waste and Biomass Valorization ; Vol. 5, issue. 6 , 2014 , pp. 947-954 ; ISSN: 18772641 ; Kariminia, H. R ; Yaghmaei, S ; Sharif University of Technology
2014
Abstract
Using whole cell as a catalyst of enzymatic transesterification is a method to produce biodiesel with fewer drawbacks and at a lower cost. In the present study, biodiesel was produced by the reaction of waste frying oil with methanol in the presence of Rhizopus oryzae PTCC 5174 in both immobilized and free forms. Effect of four influencing factors including temperature, methanol to oil molar ratio, amount of biomass, and shaking speed was investigated. Response surface methodology was used to find the optimum conditions of the transesterification reaction. Each factor was set at three levels and the yield of the biodiesel was considered as the response. A quadratic equation was well-fitted...
Fabrication and Optimization of Organic Inorganic Perovskite Solar Cells Using Vapor Phase Deposition
, Ph.D. Dissertation Sharif University of Technology ; Taghavinia, Nima (Supervisor) ; Tajabadi, Fariba (Supervisor)
Abstract
In this research, we focus on study and fabrication of organic inorganic solar cells. We use and optimize various methods such as one-step spin-coating, two-step sequential deposition and vapor-assisted solution process (VASP), to prepare high quality perovskite films. One-step deposition is simplest method for deposition of perovskite films. Although perovskite deposition by this method is very simple, the control of uniformity and surface film morphology is difficult. Chlorine inclusion, optimization of annealing conditions, and a sequential solution-based deposition method have been demonstrated to increase film coverage and uniformity. Hence, we use sequential deposition method for...
Preparation of conductive polyaniline/graphene nanocomposites via in situ emulsion polymerization and product characterization
, Article Synthetic Metals ; Vol. 196 , 2014 , pp. 199-205 ; Ramazani, S. A ; Mashayekhan, S ; Ghaderinezhad, F ; Sharif University of Technology
2014
Abstract
This work, which is a part of our ongoing studies on developing conductive scaffolds for nerve tissue engineering, reports synthesis of highly conductive binary-doped polyaniline nanoparticles and polyaniline/graphene nanocomposites. The samples were synthesized through chemical oxidation of aniline via in situ emulsion polymerization method in presence of hydrochloric acid and sodium dodecyl sulfate. Graphene nanosheets were also prepared via modified Hummer's method followed by chemical reduction using hydrazine monohydrate. Electrical conductivity measurements using a standard four-point probe technique with FTIR and UV-vis studies revealed that conductive binary-doped emeraldine salt...
Investigation of Quantum States of Light (Generation and Utilization Their Special Properties) in Quantum Information Science and Precision Measurements
, M.Sc. Thesis Sharif University of Technology ; Karimipour, Vahid (Supervisor)
Abstract
Quantum entanglement and superposition are wonderful and mysterious phenomena of quantum mechanics. By means of quantum entanglement, two or more systems become partner in state of each other . As a result, measurements on each of these systems affect the status of other systems. Quantum superposition allows a system inhabits several of its possible quantum states simultaneously. These two features are applicable in many technologies in present age. Photons, as an quantum unit of light, are appropriate candidate for utilization these properties. Because they are robust to decoherence and for their preparation exist various methods. Hence, we interested to generation of quantum states of...
A Study on Action Selection Deficits in Schizophrenic Patients Using Computational Modeling in Reniforcement Learning Framework
, M.Sc. Thesis Sharif University of Technology ; Vosoughi Vahdat, Bijan (Supervisor) ; Bahrami, Fariba (Supervisor)
Abstract
Schizophrenia is a devastating disorder that steals the opportunity of having a normal life from the sufferers. Drugs used in treating this disorder usually target psychotic symptoms and do not affect negative symptoms effectively. One of the deficits falling into this category is the impaired reversal learning. These patients usually learn the rules but do not renounce them after the contingencies of reward have been reversed. To investigate the reasons of this impairment, first a hypothesis of how different parts of the brain communicate during reversal learning is proposed using the physiological evidence. Then considering the known relation between the actor-critic model of the...
Producing Biodiesel from Waste Frying Oil Using Whole Cell Biocatalysts
, M.Sc. Thesis Sharif University of Technology ; Yaghmaei, Soheyla (Supervisor) ; Kariminia, Hamid Reza (Supervisor)
Abstract
Nowadays, due to depletion of fossil fuels and the emission of green house gases, biodiesel has attracted lots of attention as a renewable, non-toxic, and biodegradable fuel. Biodiesel can be produced from different resources such as vegetable oil, animal fat and algae oil. In this study, waste frying oil was used as a raw material that can reduce the probable hazardous effects of its disposal and produce a clean fuel at the same. Biofuel was produced through an enzymatic method using the whole cell of Rizopu oryzae (a filamentous fungus) in both immobilized and free forms. In order to find the optimum conditions for biodiesel production, four variables including temperature, methanol to oil...
Improvment of Perovskite Layer and Perovskite/Hole Transport Layer Interface to Inhance Perovskite Solar Cell Performance
, Ph.D. Dissertation Sharif University of Technology ; Taghavinia, Nima (Supervisor) ; Tajabadi, Fariba (Supervisor)
Abstract
The use of renewable energy sources has received much attention due to the increasing need for energy, limited energy resources and the pollution of fossil fuels. Among all types of solar energy conversion technology, photovoltaics has the highest technical potential and Iran’s geographical location is very suitable for benefiting from this energy. So, in this thesis, the fabrication and characterization of nanostructured solar cells based on organic-inorganic perovskites have been investigated. Many research goups have tried to increase the efficiency of perovskite solar cells. The efficiency of this kind of solar cells depends mainly on the light-absorbing layer (perovskite) and its...
Printable Carbon Electrode for Perovskite & Thin Film Solar Cells
, Ph.D. Dissertation Sharif University of Technology ; Taghavinia, Nima (Supervisor) ; Tajabadi, Fariba (Supervisor) ; Mohammadpour, Raheleh (Supervisor)
Abstract
Solar cells, as a part of photovoltaics (PV) industry, have a significant share in the renewable energy market. Perovskite solar cells (PSCs) and thin film solar cells (TFSCs) achieved 23% and 22% power conversion efficiencies (PCEs) respectively. However, the PV industry still faces challenges like “high manufacturing costs” and “stability”. Among the strategies to overcome these challenges are substitution of the costly materials with cheaper, more abundant ingredients along with utilizing inexpensive deposition methods like printing rather than vacuum-based methods such as evaporation and sputtering. Carbon materials attract more attention in the solar cell research community for their...
Design, fabrication, and characterization of novel porous conductive scaffolds for nerve tissue engineering
, Article International Journal of Polymeric Materials and Polymeric Biomaterials ; Volume 64, Issue 18 , 2015 , Pages 969-977 ; 00914037 (ISSN) ; Ahmad Ramazani, S. A ; Mashayekhan, S ; Farani, M. R ; Ghaderinezhad, F ; Dabaghi, M ; Sharif University of Technology
Taylor and Francis Inc
2015
Abstract
Highly conductive polypyrrole/graphene (PYG) nanocomposite was synthesized with chemical oxidation process via emulsion polymerization and used for the preparation of novel porous conductive gelatin/chitosan-based scaffolds. The effect of PYG loading on various properties of scaffolds was investigated. The obtained results indicated that by introducing PYG into the polymeric matrix, the porosity and swelling capacity decreased while electrical conductivity and Young's modulus demonstrated increasing trend. The in vitro biodegradation test revealed that pure gelatin/chitosan matrix lost 80% of its weight after six weeks in the presence of lysozyme whilst the biodegradation rate was...