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The present work was aimed to account a green and eco-friendly synthesis of palladium nanoparticles using Rosmarinus officinalis leaves extracts for the first time, therefore, that can be an acceptable replacement for chemical media to improve potential biological properties. The synthesized palladium nanoparticles were fully characterized using FT-IR, XRD, FESEM, TEM and UV/Vis spectroscopy techniques. Catalytic activity was investigated by Mizoroki-Heck reaction, and optimized based on solvent, temperature and time of the reaction, and the best results were found in water as a green media without any additional reagents. Biological activity of the synthesized nanoparticles were evaluated... 

The future of power systems known as smart grids is expected to involve an increasing level of intelligence and incorporation of new information and communication technologies in every aspect of the power grid. Demand response resources and gridable vehicle are two interesting programs which can be utilized in the smart grid environment. Demand response resources can be used as a demand side virtual power plant (resource) to enhance the security and reliability of utility and have the potential to offer substantial benefits in the form of improved economic efficiency in wholesale electricity markets. An economic model of incentive responsive loads is modelled based on price elasticity of... 

Due to rapid development of manufacturing process, composite materials with porosity have attracted commercially notices in advanced engineering applications. For this regard, buckling and vibrational characteristics of a porous composite cylindrical nanoshell reinforced with GPLs is investigated in this paper. The material properties of piece-wise graphene-reinforced composites (GPLRC) are assumed to be graded in the thickness direction of a cylindrical nanoshell and are estimated using a nanomechanical model. The novelty of our work is including the effects of porosity and GPLRC on natural frequency, critical axial load and critical temperature of the GPLRC cylindrical nanoshell. The... 

Doxorubicin (DOX) is a potent anti-cancer agent and there have been attempts in developing nanostructures for its delivery to tumor cells. The nanoparticles promote cytotoxicity of DOX against tumor cells and in turn, they reduce adverse impacts on normal cells. The safety profile of nanostructures is an important topic and recently, the green synthesis of nanoparticles has obtained much attention for the preparation of biocompatible carriers. In the present study, we prepared layered double hydroxide (LDH) nanostructures for doxorubicin (DOX) delivery. The Cu–Al LDH nanoparticles were synthesized by combining Cu(NO3)2·3H2O and Al(NO3)3·9H2O, and then, autoclave at 110. The green... 

Nanostructured TiO2 hollow fibers have been prepared using natural cellulose fibers as a template. This cheap and easily processed material was used to produce highly porous photoanodes incorporated in dye-sensitized solar cells and exhibited remarkably enhanced electron transport properties compared to mesoscopic films made of spherical nanoparticles. Photoinjected electron lifetime, in particular, was multiplied by 3-4 in the fiber morphology, while the electron transport rate within the fibrous photoanaode was doubled. A nearly quantitative absorbed photon-to-electrical current conversion yield exceeding 95% was achieved upon excitation at 550 nm and a photovoltaic power conversion... 

Nanoparticles and nanomaterials in cancer therapy as well as in all biomedical applications have been heavily investigated over the last decade. In this manner, green synthesized nanomaterials have been vastly considered as promising, cost effective, and environmentally friendly components. Also, green synthesis methods could reduce cytotoxicity as well as increase the biocompatibility of the final products. In this chapter, the role of nanomaterials obtained from biowaste specifically for cancer therapy is discussed. © 2023 Elsevier Ltd. All rights reserved  

In the present research, human errors existed in tasks of operators working in two control rooms (Northern and Southern control rooms) in the Tehran oil refinery are identified and evaluated. Then, corrective strategies and actions are advised to decrease errors. At first, using hierarchical task analysis (HTA) method, four positions including shift controller, head operators, control room's operators, and outside operators are analyzed. Afterwards, human errors in the considered positions are identified and assessed using technique for retrospective and predictive analysis of cognitive errors (TRACEr). Results present 670 internal errors and 738 external errors in the Northern sector while... 

In recent years, many efforts have been made in the field of computational modeling of cancerous tumors, in order to obtain a better understanding and predictions of their growth patterns. Furthermore, constraint-based modeling of metabolic networks has become increasingly popular, which is appropriate for the systems-level reconstruction of cell physiology. The goal of the current study is to integrate a multiscale agent-based modeling framework with a constraint-based metabolic network model of cancer cells in order to simulate the three dimensional early growth of avascular tumors. In order to develop the integrated model, a previously published generic metabolic network model of cancer... 

In this article, wave propagation characteristics of a size-dependent laminated composite nanostructure coupled with a piezoelectric actuator (PA) is investigated. In order to consider the effects of small scale, the governing equations of the laminated composite nanostructure coupled with PA are derived using Hamilton’s principle based on the nonlocal strain gradient theory (NSGT). The differential equations of motion are solved with the assistance of the analytical method. Afterward, a parametric study is carried out to investigate the effects of the PA thickness, wave number, angular velocity and the ply angle on the value of phase velocity. The results show that the ply angle plays an... 

Evaluation of the effect of different parameters for designing a non-viral vector in gene delivery systems has great importance. In this manner, 2D crystals, precisely layered double hydroxides, have attracted the attention of scientists due to their significant adjustability and low-toxicity and low-cost preparation procedure. In this work, the relationship between different physicochemical properties of LDH, including pH, size, zeta potential, and synthesis procedure, was investigated and optimized for CRISPR/Cas9 delivery and reverse fluorescence response to the EGFP. In this manner, ZnAl LDH and ZnAl HMTA LDH were synthesized and characterized and applied in the HEK-293 cell line to... 

Introduction: In recent years, the use of cost-effective, multifunctional, environmentally friendly and simple prepared nanomaterials/nanoparticles have been emerged considerably. In this manner, different synthesizing methods were reported and optimized, but there is still lack of a comprehensive method with multifunctional properties. Materials and Methods: In this study, we aim to synthesis the copper oxide nanoparticles using Achillea millefolium leaf extracts for the first time. Catalytic activity was investigated by in situ azide alkyne cycloaddition click and also A3 coupling reaction, and optimized in terms of temperature, solvent, and time of the reaction. Furthermore, the... 

In the present work, an amperometric inhibition biosensor for the determination of sulfide has been fabricated by immobilizing Coprinus cinereus peroxidase (CIP) on the surface of screen printed electrode (SPE). Chitosan/acrylamide was applied for immobilization of peroxidase on the working electrode. The amperometric measurement was performed at an applied potential of -150. mV versus Ag/AgCl with a scan rate of 100. mV in the presence of hydroquinone as electron mediator and 0.1. M phosphate buffer solution of pH 6.5. The variables influencing the performance of sensor including the amount of substrate, mediator concentration and electrolyte pH were optimized. The determination of sulfide... 

In this article, the vibration frequency of an orthotropic nanoplate under the effect of temperature change is investigated. Using nonlocal elasticity theory, governing equations are derived. Based on the generalized differential quadrature method for cantilever and propped cantilever boundary conditions, the frequencies of orthotropic nanoplates are considered and the obtained results are compared with valid reported results in the literature. The effects of temperature variation, small scale, different boundary conditions, aspect ratio, and length on natural nondimensional frequencies are studied. The present analysis is applicable for the design of rotating and nonrotating nano-devices... 

Herein, in a one-pot method, the reduced graphene oxide layers with the assistance of multiwalled carbon nanotubes were decorated to provide a suitable space for the in situ growth of CoNi2S4, and the porphyrins were incorporated into the layers as well to increase the sensitivity of the prepared nanostructure. The prepared nanocomposite can establish π–π interactions between the genetic material and on the surface of porphyrin rings. Also, hydrogen bonds between genetic domains and the porphyrin’ nitrogen and the surface hydroxyl groups are probable. Furthermore, the potential donor–acceptor relationship between the d7 transition metal, cobalt, and the genetic material provides a suitable... 

Correction to: Scientific Reports, published online 23 March 2021 The original version of this Article contained errors in the Results section resulting from an incomplete revision of the text to reflect changes in the figures during review. Figure legends and the Results section were corrected accordingly. As a result, in the Results section, under the subheading ‘In situ and real-time monitoring of hydrogen peroxide from the living cell’, the original legend of Figure 4 “Fluorescent image of the cells seeded on the nanocomposite after 16 h, for HEK-293 cell line (a,b) and PC12 cell line (c,d). (b,d) represents the fluorescence image after + 1 s after (a,c) captures. Fluorescence emission... 

This study investigated the synthesis of Pd nanoparticles (NPs) using a high-gravity technique mediated by Salvia hispanica leaf extracts. Biological assays confirmed their antibacterial activity against gram positive (S. aureus) and gram negative (E. coli) bacteria with significant antioxidant activity in comparison with the standards as well as low cellular toxicity on PC12 and HEK293 cell lines. To the best of our knowledge, this study can be considered as the first investigation of Pd-NPs synthesized by Salvia hispanica leaf extracts assisted by a high-gravity technique. In addition, the mentioned green synthesis procedure led to the formation of nanoparticles with considerable... 

The nanostructures under rotation have high promising future to be used in nanomachines, nano-motors and nano-turbines. They are also one of the topics of interests and it is new in designing of rotating nano-systems. In this paper, the scaledependent vibration analysis of a nanoplate with consideration of the axial force due to the rotation has been investigated. The governing equation and boundary conditions are derived using the Hamilton's principle based on nonlocal elasticity theory. The boundary conditions of the nanoplate are considered as free-free in y direction and two clamped-free (cantilever plate) and clamped-simply (propped cantilever) in x direction. The equations have been... 

Pure and Pd-doped WO3 Nanocrystalline tungsten oxide films on alumina substrates were prepared via sol-gel method from peroxopolytungstic acid. AFM, XRD, SEM, XPS methods were used to determine the surface morphology, grain size and layer composition. XRD analysis showed WO3 nanocrystalline particles in monoclinic phase and with average size of about 333nm, which was consistent with SEM analysis results. Sensing properties of samples toward H2 gas was studied. The sensitivity of WO3 nanocrystalline films was about 4 at 2300ppm (0.2%) H2 gas. Introducing Pd to the system led to an increase in the sensitivity about 2 orders of magnitude. The sensitivity of Pd: WO3 was about 400 at 2300ppmH2