Sharif Digital Repository

Briefly in this thesis, these subjects have been investigated: In recent years, water is used as a solvent instead of an organic solvents have become more and more important due to cheap and environmental consideration. In this context, preparation of quinoxaline, pyrrole, new 1,4-dihydropyridine and reduction of imine to amine with 1,4-dihydropyridine derivatives as the reducing agents with the use of one-pot multicomponent reaction have been reported. The existence of several hydrogen bonding groups (NH) in the new dihydropyridines they acts as biologically active compounds in the forthcoming years. In continuation, oxidation of thiols to disulfides in the presence of NBS and NCS and... 

Since the classical continuum theory fails to deal with the problems associated with defects, stress concentrators, and relevant deformation phenomena in solids, alternative approaches that can detect the atomistic nature of materials' fracture are required. The deficiency of the capture the size effect which yields delusively high values for some components of the stress field right on the edge of the stress concentrators, and its weakness in describing the complex interaction between small inhomogeneities, cracks and the like when they are only a few nanometers apart, are among some of the disadvantages of the classical approach. In recent years, however, atomistic methods are emerging to... 

Aluminum Bronzes have many applications in marine environments. These alloys suffer from both hot cracking and cold cracking. In order to overcome the hot cracking and cold cracking, Semisolid Stir Joining method and a proper thermal cycle was used respectively. Effects of temperature, stirring rate, and tool type were investigated in Semisolid Stir joining method. In this method, butt joint design was used in order to place specimens, and the specimens were heated up to specific temperatures (920, 925, 930°C). A stirrer (Cylindrical and Grooved tool) with three rotational speeds (800, 1200, 1600 RPM) was introduced into the stir weld seam. Welded specimens were cooled to the 900°C... 

The low female labor force participation rate in the Iranian labor market relative to the global average and even to countries that do not differ significantly from the socio-economic characteristics of our country is one of the important questions of the Iranian labor market. In this study, we seek to answer the question of whether the economic participation rate of married women will increase if the gender gaps in wages, job findings and job losses among women and men are eliminated in the Iranian labor market. To answer this question using household expenditure and income data and labor force data, we show that between the two categories of occupations, in terms of the share of women's... 

Shot peening is a cold-working process commonly used in industry to improve the fatigue performance, stress corrosion resistance and surface nano-crystallization of metallic parts. This process extends fatigue life via two mechanisms: Preventing the crack growth due to compressive residual stresses and, preventing the crack initiation because of increased material hardness. These mechanisms are the results of the bombardment of the component's surface with small spherical particles. In this research, an analytical model is developed for estimating the residual stress distribution induced by shot peening process. The modifications of the developed analytical model are related to... 

Solid-State Drives (SSDs) provide high performance, low power consumption, and hence are widely used in the I/O cache of enterprise storage systems and high performance servers. Although employing high performance SSDs in the I/O cache of storage systems significantly improves system performance, it comes with significant reliability threats for write operations upon power failures. In order to provide high level of reliability, storage architectures employ SSDs in I/O cache with RAID-1 configuration, however, such configuration only partially mitigates the reliability issues of the SSDs. In this thesis, we analyze the reliability of SSD-based I/O caches against power outage and high...