Sharif Digital Repository

Nowadays, the use of gas turbines with low capacity have acceptance in large quantity. This type of gas turbines with a capacity of approximately 5-200kW are known as microturbines. This type of turbines due to the existence of limitations on increasing of turbine inlet temperature and compressor pressure ratio has low efficiency compared to the turbine with high capacity. Therefore the use of a recuperator in the cycle is necessary. Optimum design of heat recuperator has important effect on improving of gas turbine cycle efficiency. In this project for optimum design of heat recuperator, the effect of recuperator on gas turbine cycle efficiency is studied. By determining geometric... 

Electroless coating is a chemical reduction process which depends on the catalytic reduction. In this study, the influences of different concentrations, stirring rate, pH and heat treatment of Al2O3 and SiO2 Nano sized particles in the bath on deposition rate, hardness, wear resistant, surface morphology and corrosion behavior of the Ni-P-Al2O3-SiO2 composite coatings have been investigated. The microstructure was investigated by field emission scanning electron microscopy (FESEM) and among the nanoparticles SiO2 and Al2O3 have drawn attention due to their high hardness, availability, particles distribution and reduced cost. The amount of Al2O3 and SiO2 was examined by Energy Dispersive... 

In the present study, the coordination chemistry of an amino acid azacrown macrocycle ligand bearing one carboxylic acid arm (MA1) was investigated by employing NMR spectroscopy, crystallography and computational chemistry. MA1 was synthetized by the reaction of chloroacetic acid with the parent azacrown macrocycle and its purity was confirmed with 13C and 1H NMR for the first time. A new MA1 homologue, MA3 was also successfully prepared and characterized with NMR, mass spectrometry, and elemental analysis. NMR studies showed that MA1 binds to cadmium via the carboxylate arm in solution. Crystallographic studies showed that MA1 formed a one-dimensional polymer with cadmium, wherein the... 

Nowadays with development of applications that stream video over internet, compression efficiency of video has become very important. On the other hand, Watermarking and video coding are two conflicting technologies. One adds redundancy and other tries to remove it. We have proposed a H.264 watermarking method that does not increases the bit rate. Unlike most of watermarking schemes, this methods embeds the watermark in inter coded frames. Abundance of these frames in video is impressively more than intra frames, so a lot of capacityis eventuated. But these frames are highly compressed using motion compensation, and are very sparse. To avoid from bit rate increment, this method only embeds... 

Nanostructured graphene based membranes demonstrated excellent capabilities in various applications in nanofiltration and energy conversion due to unique atomically smooth surfaces and adjustable pore size or interlayers spacing at Angstrom scales.In addition to graphitic surface and physical confinement on ions in Graphene-oxide (GO) laminates, surface charges on such 2D-slits provide an attractive aspects to have more channels walls interactions with ions. There are some reports on the osmotic power generation using physical confinements and electrostatic interactions between ions and GO membranes. However, the results indicated insufficient power densities (1 W=m2 ) can be achieved... 

The main objective of this study is to identify the contribution of different damping mechanisms in equivalent damping of inelastic soil- structure systems which can be used to reach a better estimation of inelastic soil- structure systems response using some simplified methods. This mechanisms include the material damping of soil and structure, radiation damping of soil and also the structure’s nonlinear behavior. Despite the studies have been done, even in the fixed base systems, there is not an exact prediction for the contribution rate of inherent damping and energy absorption related to nonlinear behavior in equivalent damping of system. Considering the flexibility of soil under the... 

Cryptocurrencies are not only regarded as a trustworthy method of financial transaction validated by a decentralized cryptographic system as opposed to a centralized authority, but also as one of the most popular and lucrative forms of trade and investing. Predicting the price of a cryptocurrency is a challenging topic in time-series research. Its intricacy is due to the volatility and large swings of cryptocurrencies' price. The emergence of brand-new cryptocurrencies, which might present a profitable trading opportunity but lack sufficient historical data for technical analysis, prompted us to develop a trading strategy that could be applied universally. The forecast of the next timestep's... 

Today, energy has a great impact on the economy, political relations, prosperity, and lifestyle of human societies. Energy sustainable development has become inevitable because of factors such as increasing population growth and as a result, increasing the energy consumption, consuming more energy from fossil fuels, decreasing in reserves of fossil fuel resources, environmental damage caused by the burning down of fossil fuels and greenhouse gas emissions,high cost of energy from burning fossil fuels.Generally, the sustainable development isall steps in order to comply with economic development and protecting the environment, resources and living standards. Considering that a large part of... 

Evaporation and condensation of thin films can rupture or stabilize thin film .We show that evaporation hastens dewetting of a thin film. Dewetting over nanometric downward step causes pinning of the contact line near the step. This phenomena is not permanent and after certain time that contact angle reaches to its critical value depinnnig happens. We also study the effect of the step size, contact angle, film thickness, slip and evaporation on the depinning time of the contact line. We show that depinnig time has a reverse relation with the rate of evaporation  

Silica nanoparticles is one of the most important mineral particles. In this study, Sodium silicate, Sulfuric acid and Sodium aluminate is used in order to synthesis of the modified Silica nanoparticles. The effects of temperature, reaction time and the molar ratio of regents were tested and optimized. Synthesized nanoparticles were characterized by use of XRD, FT-IR and SEM techniques. The results show that by controlling the reaction conditions, nanoparticles with an average size of 26.2 nm is obtained. The increase of temperature and reaction time alters the structure of the particles of amorphous state to a crystalline needles. The particle surface modification process was performed by... 

Wideband mm-wave radars are gaining popularity in automotive applications due to their superiority in harsh weather conditions, high distance resolution, precise velocity measurement, and superior spatial resolution. The primary purpose of this thesis is to design and implement a voltage-controlled oscillator for 77GHz automotive radar applications.Phase noise -as one of the most crucial specifications in VCO design- Phase noise improvement techniques as well as harmonic engineering methods are delineated. Also, an Ocean-based code for ISF simulation is introduced and developed to obviate the need for additional signal processing software so that simulation speed increases... 

The development of innovation ecosystems has become a global trend. These ecosystems have proven their importance to governments by having a significant impact on the creation of technology companies and the economic growth of the country. In Iran, too, for many years, efforts have been made under various headings to develop the innovation ecosystems. In this dissertation, based on the narrative policy framework, the existing policy narratives of innovation ecosystems development policy in iran between 2013-20 years in the case of startup ecosystem have been analyzed. After analyzing these data, it was found that the three main narratives of catch-up, wealth creation and infiltration, have... 

Modern broadband microwave and millimeter-wave systems often struggle with excessive pass band ripple and negative gain slopes due to the loss of transmission lines such as coaxial cables, or ripples in the gain characteristic of broadband amplifiers. The common solution for this problem is using a gain equalizer to compensate for the intrinsic pass band variation with some extra loss in the band of interest in return.Designed equalizers often have a constant slope in their bandwidth. However, having ripples in pass band or in other words slope changing in some parts of the band is one of the issues that designers should deal with. In this thesis, after reviewing the previous works on the... 

For decades Crystal Oscillators (XO) have been the unequaled references for stable and low noise frequency sources. This leadership is due to their high Q-factor. The resonant frequency of such crystal resonator is inversely proportional to the thickness of the quartz disk (the resonant cavity) and is today limited , by physical manufacturing constraints , to about 150 MHz . in order to avoid such limitation , the solution is to start with an oscillator at higher fundamental frequency. SAW technology on quartz offers this opportunity . with SAW the resonant cavity size is not linked to the thickness of the substrate and resonant frequencies up to the GHz range are achievable. In this thesis... 

Power amplifiers (PAs) are one of the key components in radio-frequency (RF) and microwave systems. In these systems, PAs must be highly efficient to simplify the thermal management and to enhance dc power requirements. Future systems, including WiMax, 4G, 5G, and beyond, will likely require larger bandwidths due to their wider spectral allocations caused by the extended bandwidth of baseband signals. Therefore, highly-efficient and broadband PAs are needed to be employed in these systems. To realize high-efficiencies over wide frequency ranges, class-J mode of operation was introduced by Cripps in 2009. Class-J mode of operation is capable of maintaining a high efficiency (78% in theory)... 

Evaluation of the seismic-induced settlement of an unsaturated soil layer depends on several variables, among which the small strain shear modulus, Gmax, and soil’s state of stress have been demonstrated to be of particular significance. Recent interpretation of trends in Gmax revealed considerable effects of the degree of saturation and hydraulic hysteresis on the shear stiffness of soils in unsaturated states. Accordingly, the soil layer is expected to experience different settlement behaviors depending on the soil saturation and seasonal weathering conditions. In this study, a semi-empirical formulation was adapted to extend an existing Gmax model to infer hysteretic effects along... 

A drug can be defined as a substance made to prevent disease, cure a specific symptom, relieve pain, and reduce anomalies in the body. The process of drug designing is so laborious, complex, costly, and time-consuming that chance of failure during the lab experiment stages is high. These challenges have persuaded researchers to find new usage for existing drugs, referred to as drug repurposing, with the main advantage of reducing cost, risk, and time. To this aim, computational methods have been applied to discover hidden pharmaceutical capabilities of drugs in terms of predicting whether a particular drug can interact with a particular protein.Graph Neural Networks (GNNs) have recently... 

Wettability is the cause of many interactions today and is definitely effective in almost all processes where liquid and solid phases are in contact. Wetting controls by surface engineering can accelerate the process in the industry or improve the quality of daily life. Therefore, the fabrication of complex surfaces with a specific purpose and different wettability has attracted the attention of researchers. In this thesis, silica nanoparticles were synthesized to create roughness and reduce contact between surfaces and liquids at first. Then, using chemical compounds to reduce the surface energy, a transparent (94.20%) superhydrophobic and oleophobic coating was created on the glass. The... 

Due to the global crisis of water and energy scarcity, the design and optimization of water treatment systems with the aim of reducing energy consumption and increasing efficiency have gained significant importance. An electrodialysis system was simulated and validated using advanced lumped model, considering all critical effects in the process, such as Donnan resistance, boundary layer resistance, and osmotic and electroosmotic flows, across salinity ranges from 0.35 to 200 parts per thousand. Additionally, a reverse osmosis desalination system was simulated and validated using the solution-diffusion model, with the concentration polarization coefficient calculated via the thin-film theory.... 

In this thesis first of all we investigate phase noise and it's generation factors. Then we design and implement an ultra low phase noise oscillator. To do this, an ultra low phase noise oscillator which is tunable in 1-2GHz with 100MHz steps will be designed. The outline of the circuit is as follows: at the first we design a VCO which is ultra low phase noise and mechanically tunable in 1-2GHz by means of rotation of a handle. Then a phase locked loop will be built with the help of an ultra low phase noise OCXO at 100MHz and one SPD1 which generates harmonics of OCXO's output frequency. For the next, design and implementation of a 1.6GHz oscillator with fixed output frequency has been done....