Sharif Digital Repository

The effect of CoSALEN on anti-oxidative properties of fullerene C60 in the presence of O2 in cumene was investigated. A comparison was made between the role of the CoSALEN as a catalyst in the C60 oxidation and oxidation in the presence of an initiator, i.e., AIBN. A mechanism is proposed for the catalytic role of CoSALEN in oxidation of C60. Oxidation of octadecylaminofullerene C60 at the same conditions reveals that oxidation could be a result of hydroperoxidation of the unreacted sites of C60. We conclude that C60 as well as its aminoderivatives enhance the efficiency of CoSALEN in the oxidation of cumene due to their radical scavenging property of their unreacted double-bond sites. ©... 

Sleep Spindle is the hallmark of the second stage of sleep in EEG signal. It had been analyzed using different methods, including Fourier transform, parametric and non-parametric models, higher order statistics and spectra, and also time-frequency methods such as wavelet transform, and matching pursuit. In this study, bump modeling has been used to analyze sleep spindle. Bump modeling is a method which represents the time-frequency map of signals with a number of elementary functions. Results of this work demonstrate that bump modeling is capable of analyzing different sleep spindle patterns in sleep EEG signals successfully  

The reaction of 15-18 membered benzodiazacrown ethers with salicylaldehyde afforded n-membered O2N2-donor macrocyclic ligands mounted with 1,3-diazacyclohexane subrings (1-4) in high yields. The products were characterized by FT-IR, 1H, 13C NMR spectroscopy, elemental analyses, and single crystal X-ray studies. The solid state structures revealed strong intramolecular hydrogen bonding between the pendant phenolic group and the tertiary nitrogen of the corresponding macroring  

A new non-enzymatic sensor for glucose is prepared by using of Ni(II)-one dimensional coordination polymer (Ni(II)-Cp) and C 60 . The Ni(II)-Cp prepared by slow diffusion and evaporation of two solution layers of NiCl 2 and diaza-macrocycle bearing two pyridine side arms (as the reported tecton) in DMF. The Ni(II)-Cp was characterized by powder x-ray diffraction (PXRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) as well as Fourier transform infrared spectroscopy (FT-IR). C 60 as modified was added to Ni(II)-Cp for improving the electrical and chemical stability of the composite. The newly assembled Ni(II)-Cp/C 60 also coated on glassy carbon electrode (GC) to... 

A new approach to Image Quality Assessment (IQA) is presented. The idea is based on the fact that two images are similar if their structural relationship within their blocks is preserved. To this end, a transition matrix is defined which exploits structural transitions between corresponding blocks of two images. The matrix contains valuable information about differences of two images, which should be transformed to a quality index. Eigen-value analysis over the transition matrix leads to a new distance measure called Eigen-gap. According to simulation results, the Eigen-gap is not only highly correlated to subjective scores but also, its performance is as good as the SSIM, a trustworthy... 

Two mononuclear coordination complexes of fullerene[60] with Pd(dba)2 (dba = dibenzylideneacetone), [(η2-C60)Pd(Ph2P(CH2)2PPh2C(H)C(O)R)2] (R = C10H7 (1), C6H4Cl (2)), have been prepared using a simple procedure to explore new directions in palladium catalysis and nanocarbon chemistry. The palladium(0)-[60]fullerene complexes incorporating unsymmetrical phosphorus ylides have been characterized by 1H, 13C and 31P NMR spectroscopic methods and other conventional techniques such as IR, TGA, SEM, ICP-OES, EDX and TEM analysis. Attributed to the enhanced dispersity and uniform size of the Pd nanoparticles with phosphine-functionalized fullerenes, the prepared catalysts exhibited comparable... 

Feature vector extraction, based on local image texture, is a primitive algorithm for many other applications, like segmentation, clustering and identification. If these feature vectors are a good match to the human visual system (HVS), we can expect to get the appropriate results by using them. Gabor filters has been used for this purpose successfully. In this paper we introduce a novel refinement, with the use of Matching Pursuit (MP) to improve the Gabor based texture feature extractor. With this improvement, we show that the separability of different textures will increase. Another consideration in this work is computation complexity. Therefore, we limit the basis function set to reduce... 

Abstract In this work, two [60] fullerene derivatives were employed as flow improvers for waxy crude oil to reduce problems caused by the crystallization of paraffin during the production and/or transportation of the crude oil. These amine-based derivatives of [60] fullerene have been applied as wax inhibitor for improvement of rheological performance as well as pour point depressant in a waxy crude oil. Moreover, the influence of these [60] fullerene derivatives on the viscosity and pour point was also investigated in an Iranian waxy crude oil sample. The [60] fullerene derivatives were simply prepared by stirring a solution of [60] fullerene and two lipophilic amines. The results similarly... 

Two unique heteronuclear Schiff base complexes of Cu(II), [{Cu(L)Na(ClO4)}2(μ-H2L)] (1) and Ni(II), [{Ni(L)Na(BF4)}2(μ-H2L)] (2) were synthesized and characterized by different spectroscopic methods as well as X-ray crystallography. The Schiff base ligand (H2L) was synthesized from the condensation meso-1,2-diphenyl-1,2-ethylenediamine with 3-methoxysalicylaldehyde. The 3d metal ions in these complexes have been accommodated by the inner N2O2 compartment of the Schiff base ligand, while the O2O′2 outer compartment has accommodated the Na(I) ion (O and O′ denote the phenolic and methoxy oxygen atoms, respectively). Besides, a Schiff base ligand has doubly bridged the M(II)/Na(I) moieties via... 

We investigate various types of fuzzy linear programming problems based on models and solution methods. First, we review fuzzy linear programming problems with fuzzy decision variables and fuzzy linear programming problems with fuzzy parameters (fuzzy numbers in the definition of the objective function or constraints) along with the associated duality results. Then, we review the fully fuzzy linear programming problems with all variables and parameters being allowed to be fuzzy. Most methods used for solving such problems are based on ranking functions, α-cuts, using duality results or penalty functions. In these methods, authors deal with crisp formulations of the fuzzy problems. Recently,... 

Introduction: Diabetic neuropathy is a common complication of diabetes mellitus. It is associated with nerve damage due to oxidative stress and high levels of pro-inflammatory mediators. In the present study, we examined the anti-nociceptive effects of Fullerene nanoparticle, as a potent anti-oxidant, during diabetic neuropathy. Methods: Diabetes mellitus induced through injection of streptozotocin (STZ) (40 mg/kg). Four groups were used in the study as follows: the control, control+fullerene, diabetes, and diabetes +fullerene groups. All four groups received sesame oil. Treatment rats received fullerene C60 (1mg/kg/day) for 9 weeks by intra-gastric gavage. Then, cold allodynia, histology,... 

Background & Objective: The potent antioxidant property of fullerene C60 nanoparticles and their derivatives has been demonstrated in a wide range of in vitro and in vivo studies. Hence, we examined the effects of fullerene C60 on the oxidative stress parameters in brain and liver of the rats in normal situation. Materials & Methods: The study was performed in two groups of Wistar rats (each group, n = 6); normal and fullerene-treated normal animals. Treated rats received fullerene via oral gavage at dose of 1 mg/kg/day for 60 days. At termination of the study, the oxidative stress parameters were determined in brain and liver tissues, including the contents of glutathione (GSH) and... 

In the present research, the efficiency of the methanol to aromatics process was improved by metal doping of alkali leached ZSM-5 catalyst in the presence of ultrasound radiation. The influence of different ultrasound powers together with metal impregnation (conventional and/or by ultrasound-assisted) methods on the physicochemical properties and catalytic performance were investigated. The samples were characterized by employing various techniques, namely XRD, FESEM, adsorption–desorption of ammonia, FTIR and NH3-TPD. The experimental results disclosed the presence of a mesoporous morphology on ZSM-5 by employing alkali treatment by NaOH. Meanwhile, XRD patterns of the metal-doped samples... 

Two new heteronuclear Nickel(II)/Sodium(I) complexes of a side-off compartmental Schiff base ligand were synthesized and characterized by spectroscopic methods. Crystal structures of both of the complexes were also obtained. The Schiff base ligand was synthesized from the condensation of meso-1,2-diphenyl-1,2-ethylenediamine with 2-hydroxy-3-methoxybenzaldehyde. In both of the complexes the Ni(II) ion is coordinated to the inner N2O2 coordination sphere with square-planar geometry and the Na(I) ion is coordinated to the outer O2O2′ coordination sphere. In Complex (1) with general formula [Ni(L)Na(CH3OH)(ClO4)] the sodium ion is seven coordinated while in (2) with general formula... 

The interaction of [60]fullerene with a newly synthesized series of 17-to 21-membered macrocyclic ligands containing an O2N3-donor set has been investigated. The formation constants (K) arising from their complexation with [60]fullerene macrocycles, having various ring size, were measured in CHCl3 media by UV-visible spectroscopy applying Benesi-Hildebrand (BH) equation and their stoichiometries were also determined by the Job method. The best K value was measured for 20-membered ring macrocycle in which a 1:1 complexation stoichiometry with [60]fullerene was dominant. Furthermore, 1H NMR spectroscopy data reveled that the macrocylic ligand coordinates [60]fullerene via the nitrogen-donor... 

The voluminous of the e-mails are spam. Several algorithms are represented for spam detection based on batch learning. In this paper, a new algorithm based on incremental learning is introduced. The algorithm composes new knowledge from new training data with previous knowledge by combining classifiers based on weighted majority voting. The experiment results show that the proposed algorithm outperforms other related incremental algorithms and non-incremental algorithms  

This paper deals with estimation of fractional order and pole locator in fractional order systems. The estimation is based on Bode diagram of the system that is obtained using input and output measurements. Here the magnitude diagram is approximated with number of straight lines depending on the level of complexity and in consequence a very good estimation of fractional order and acceptable approximations of pole locators are determined. Relying on the proposed method, complexity of fractional order system identification which is mostly due to the estimation of fractional order is substantially resolved. Some example simulation results are provided to explain the work and show its... 

The present paper reports the spectroscopic investigations on the complexation of Cu(II) with two macrocyclic ligands bonded to [60]Fullerene (L1 and L2) measured in N-methylpyrrolidone (NMP) as solvent. On the basis of UV–vis-NIR spectroscopy applying Jobs method of continuous variation, typical 1:1 stoichiometries were established for the complexes of Cu(II) with L1, and L2. DFT calculations suggested that superior HOMO distributions spread over the nitrogen-donor (as well as somehow oxygen- donor in L2) groups of L1 and L2 macrocycles were the key factor for the observed Kb value enhancement. Thermodynamic stabilities for these complexes have also been determined employing... 

Incremental learning is a learning algorithm that can get new information from new training sets without forgetting the acquired knowledge from the previously used training sets. In this paper, an incremental learning algorithm based on ensemble learning is proposed. Then, an application of the proposed algorithm for spam filtering is discussed. The proposed algorithm called incremental RotBoost, assumes the environment is stationary. It trains new weak classifiers for newly arriving data, which are added to the ensemble of classifiers. To evaluate the performance of the proposed algorithm, several computer experiments are conducted. The results of computer experiments show the ability of...